Nanoporous membranes for fast diffusion of ions and small molecules

Patent metadata

Field	Value
Publication number	US-2020338505-A1
Application number	US-202016921443-A
Country	US
Kind code	A1
Filing date	Jul 6, 2020
Priority date	Feb 23, 2017
Publication date	Oct 29, 2020
Grant date	—

Abstract

A product includes a nanoporous membrane having a plurality of carbon nanotubes and a fill material in interstitial spaces between the carbon nanotubes for limiting or preventing fluidic transfer between opposite sides of the nanoporous membrane except through interiors of the carbon nanotubes. The longitudinal axes of the carbon nanotubes are substantially parallel, an average inner diameter of the carbon nanotubes is about 20 nanometers or less, and both ends of at least some of the carbon nanotubes are open. Moreover, the fill material is impermeable or having an average porosity that is less than the average inner diameter of the carbon nanotubes.

First claim

1 . A product, comprising:
a nanoporous membrane, comprising:
a plurality of carbon nanotubes; and
a fill material in interstitial spaces between the carbon nanotubes for limiting or preventing fluidic transfer between opposite sides of the nanoporous membrane except through interiors of the carbon nanotubes,
wherein longitudinal axes of the carbon nanotubes are substantially parallel,
wherein an average inner diameter of the carbon nanotubes is about 20 nanometers or less,
wherein both ends of at least some of the carbon nanotubes are open,
wherein the fill material is impermeable or having an average porosity that is less than the average inner diameter of the carbon nanotubes.

2 . The product as recited in claim 1 , wherein less than 95% the carbon nanotubes have both ends open.

3 . The product as recited in claim 1 , wherein the average inner diameter of the carbon nanotubes is about 10 nanometers or less.

4 . The product as recited in claim 1 , wherein the fill material is impermeable.

5 . The product as recited in claim 1 , wherein the nanoporous membrane is characterized by exhibiting a rate of diffusion of a component of a feed fluid through the nanoporous membrane, under a concentration gradient in the absence of a pressure gradient and a voltage gradient, that is greater than one times a bulk diffusivity of the component, wherein the component is selected from the group consisting of: ions having an average diameter smaller than an average inner diameter of the carbon nanotubes, and molecules having an average diameter smaller than the average inner diameter of the carbon nanotubes.

6 . The product as recited in claim 5 , wherein the rate of diffusion of the component through the nanoporous membrane is at least one order of magnitude greater than the bulk diffusivity of the component.

7 . A product, comprising:
a first chamber configured to receive a feed fluid; a second chamber configured to receive a permeate fluid; and a nanoporous membrane between the first and second chambers for transporting a component from the feed fluid under a concentration gradient, wherein the nanoporous membrane comprises:
a plurality of carbon nanotubes having substantially parallel longitudinal axes; and
a fill material in interstitial spaces between the carbon nanotubes for preventing fluidic transfer between opposite sides of the nanoporous membrane except through interiors of the carbon nanotubes,
wherein an average inner diameter of the carbon nanotubes is about 10 nanometers or less, wherein both ends of at least some of the carbon nanotubes are open, wherein the fill material is impermeable, wherein the component is selected from the group consisting of: ions having an average diameter smaller than an average inner diameter of the carbon nanotubes, and molecules having an average diameter smaller than the average inner diameter of the carbon nanotubes.

8 . The product as recited in claim 7 , wherein the average inner diameter of the carbon nanotubes is about 6 nanometers or less.

9 . The product as recited in claim 7 , wherein less than 95% the carbon nanotubes have both ends open.

10 . The product as recited in claim 7 , wherein the feed fluid is blood.

11 . The product as recited in claim 7 , wherein the product is configured to perform kidney dialysis.

12 . The product as recited in claim 7 , with a proviso that the product is configured to not apply a pressure gradient to the chambers and to not apply a voltage gradient to the chambers.

13 . The product as recited in claim 7 , wherein the nanoporous membrane is characterized by exhibiting a rate of diffusion of the component from the feed fluid through the nanoporous membrane, under a concentration gradient in the absence of a pressure gradient and a voltage gradient, that is greater than one times a bulk diffusivity of the component in the feed fluid, wherein the component is selected from the group consisting of: ions having an average diameter smaller than an average inner diameter of the carbon nanotubes, and molecules having an average diameter smaller than the average inner diameter of the carbon nanotubes.

14 . The product as recited in claim 7 , wherein a rate of diffusion of the component through the nanoporous membrane is maintainable at or above at least one order of magnitude greater than a bulk diffusivity of the component in the feed fluid.

15 . A method, comprising:
adding a feed fluid to a first chamber; and adding a permeate fluid to a second chamber, wherein the first and second chambers are separated by a nanoporous membrane configured for transporting a component from the feed fluid to the permeate fluid under a concentration gradient, wherein the nanoporous membrane comprises:
a plurality of carbon nanotubes having substantially parallel longitudinal axes; and
a fill material in interstitial spaces between the carbon nanotubes for preventing fluidic transfer between opposite sides of the nanoporous membrane except through interiors of the carbon nanotubes,
wherein an average inner diameter of the carbon nanotubes is about 10 nanometers or less, wherein both ends of at least some of the carbon nanotubes are open, wherein the fill material is impermeable, wherein the component is selected from the group consisting of: ions having an average diameter smaller than an average inner diameter of the carbon nanotubes, and molecules having an average diameter smaller than the average inner diameter of the carbon nanotubes.

16 . The method as recited in claim 15 , wherein less than 95% the carbon nanotubes have both ends open.

17 . The method as recited in claim 15 , wherein the feed fluid is blood.

18 . The method as recited in claim 15 , wherein the method is kidney dialysis.

19 . The method as recited in claim 15 , wherein no pressure gradient is applied to the chambers and no voltage gradient is applied to the chambers.

20 . The method as recited in claim 15 , wherein a rate of diffusion of the component from the feed fluid through the nanoporous membrane, under a concentration gradient in the absence of a pressure gradient and a voltage gradient, that is greater than one times a bulk diffusivity of the component in the feed fluid.

Assignees

• L Livermore Nat Security Llc

Inventors

• Buchsbaum Steven F
• Fornasiero Francesco
• Jue Melinda L
• Meshot Eric R
• Park Sei Jin
• Bui Ngoc T N
• Chen Chiatai

Classifications

• B01D71/0212 Primary

  Carbon nanotubes · CPC title

• B01D2325/0283

  Pore size · CPC title

• B01D67/0049

  by evaporation · CPC title

• B01D61/243

  Dialysis · CPC title

• B01D67/0037

  by deposition from the gaseous phase, e.g. CVD, PVD · CPC title