Solid electrolyte material and battery

Patent metadata

Field	Value
Publication number	US-2020328460-A1
Application number	US-202016911707-A
Country	US
Kind code	A1
Filing date	Jun 25, 2020
Priority date	Jan 5, 2018
Publication date	Oct 15, 2020
Grant date	—

Abstract

A solid electrolyte material contains Li, Y, at least one selected from the group consisting of Mg, Ca, Sr, Ba, Zn, Sc, La, Sm, Bi, Zr, Hf, Nb, and Ta, and at least one selected from the group consisting of Cl, Br, and I. An X-ray diffraction pattern of the solid electrolyte material obtained by using Cu-Kα radiation as the X-ray source includes peaks within the range in which the diffraction angle 2θ is 25° or more and 35° or less, and also includes at least one peak within the range in which the diffraction angle 2θ is 43° or more and 51° or less.

First claim

What is claimed is:

1 . A solid electrolyte material comprising:
Li; Y; at least one selected from the group consisting of Mg, Ca, Sr, Ba, Zn, Sc, La, Sm, Bi, Zr, Hf, Nb, and Ta; and at least one selected from the group consisting of Cl, Br, and I, wherein: an X-ray diffraction pattern of the solid electrolyte material obtained by using Cu-Kα radiation as an X-ray source includes a plurality of peaks within a range in which a diffraction angle 2θ is 25° or more and 35° or less, and includes at least one peak within a range in which the diffraction angle 2θ is 43° or more and 51° or less.

2 . The solid electrolyte material according to claim 1 , wherein
the X-ray diffraction pattern further includes two peaks within a range in which the diffraction angle 2θ is 50° or more and 63° or less.

3 . The solid electrolyte material according to claim 1 , wherein
the X-ray diffraction pattern further includes a peak within a range in which the diffraction angle 2θ is 13° or more and 18° or less.

4 . The solid electrolyte material according to claim 1 , wherein:
the solid electrolyte material contains a sublattice of the at least one selected from the group consisting of Cl, Br, and I; and the sublattice has a cubic close-packed or distorted cubic close-packed structure.

5 . A battery comprising:
a solid electrolyte material according to claim 1 ; a positive electrode; a negative electrode; and an electrolyte layer between the positive electrode and the negative electrode, wherein at least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer contains the solid electrolyte material.

6 . A solid electrolyte material comprising:
Li; Y; at least one selected from the group consisting of Mg, Ca, Sr, Ba, Zn, Sc, La, Sm, Bi, Zr, Hf, Nb, and Ta; and at least one selected from the group consisting of Cl, Br, and I, wherein: a first converted pattern, which is obtained by measuring an X-ray diffraction pattern of the solid electrolyte material by using Cu-Kα radiation as an X-ray source and converting the X-ray diffraction pattern to change a horizontal axis of the X-ray diffraction pattern from a diffraction angle 2θ to q,
where q=4π sin θ/λ, where λ is a wavelength of the Cu-Kα radiation,
includes a base peak within a range in which q is 1.76 Å −1 or more and 2.18 Å −1 or less;
a second converted pattern, which is obtained by converting the X-ray diffraction pattern to change the horizontal axis of the X-ray diffraction pattern from the diffraction angle 2θ to q/q 0 ,

where q 0 is a q corresponding to the base peak in the first converted pattern,
includes a peak within each of a range in which q/q 0 is 1.14 or more and 1.17 or less and a range in which q/q 0 is 1.62 or more and 1.65 or less.

7 . The solid electrolyte material according to claim 6 , wherein
the second converted pattern includes a peak within each of a range in which q/q 0 is 1.88 or more and 1.94 or less and a range in which q/q 0 is 1.9 or more and 2.1 or less.

8 . The solid electrolyte material according to claim 6 , wherein
the second converted pattern includes a peak within a range in which q/q 0 is 0.49 or more and 0.56 or less.

9 . The solid electrolyte material according to claim 6 , wherein:
the solid electrolyte material contains a sublattice of the at least one selected from the group consisting of Cl, Br, and I; and the sublattice has a cubic close-packed or distorted cubic close-packed structure.

10 . A battery comprising:
a solid electrolyte material according to claim 6 ; a positive electrode; a negative electrode; and an electrolyte layer between the positive electrode and the negative electrode, wherein at least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer contains the solid electrolyte material.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Asano Tetsuya
• Sakai Akihiro
• Nishio Yusuke
• SAKAIDA Masashi
• Miyazaki Akinobu
• Hasegawa Shinya

Classifications

• C01F17/36 Primary

  halogen being the only anion, e.g. NaYF4 · CPC title

• H01M10/0562 Primary

  Solid materials · CPC title

• H01M2300/008

  Halides · CPC title

• H01M2300/0068

  inorganic · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title