Mechanochemical recovery of Co, Li and other constituents from spent lithium-ion batteries

Patent metadata

Field	Value
Publication number	US-2020318219-A1
Application number	US-202016873071-A
Country	US
Kind code	A1
Filing date	Jan 28, 2020
Priority date	Apr 4, 2019
Publication date	Oct 8, 2020
Grant date	—

Abstract

Method embodiments useful for recycling spent lithium-ion battery (LIB) electrodes to extract critical and/or valuable elements from LIBs are provided and involve mechanochemical processing of spent LIB electrodes in the presence of certain chemical agents to recover products that can include, but are not limited to, metallic solids such as elemental metals or metal alloys, and/or inorganic compounds, metal salts, or organometallic derivatives. The desired products can be separated from by-products and contaminants and further processed into LIB electrode materials or/and other substances.

First claim

We claim:

1 . A method for recycling spent LIB material, comprising subjecting the spent LIB material to mechanochemical processing by mechanical processing the spent LIB material in the presence of a metallic reducing agent to produce a recovered metal or metal alloy product.

2 . The method of claim 1 wherein the spent LIB material comprises spent cathode material.

3 . The method of claim 1 wherein the spent LIB material also includes spent anode material and/or metallic separator material.

4 . The method of claim 1 wherein the recovered product comprises a magnetic metal or metal alloy.

5 . The method of claim 4 wherein the magnetic metal or alloy comprises Co metal or Co alloy.

6 . The method of claim 5 further including magnetically separating the Co metal or Co alloy from non-magnetic by-products.

7 . The method of claim 5 wherein the recovered product includes Li oxide.

8 . The method of claim 7 including further treating the Li oxide to recover a water insoluble Li-containing product.

9 . The method of claim 1 wherein the reducing agent comprises at least one of Li, Na, K, Mg, Ca, Sr, Ba, Al, Zn, rare earth metal, and mischmetal.

10 . The method of claim 1 wherein the mechanical processing includes at least one of milling, grinding, shredding, or extruding of the spent LIB material under inert gas atmosphere or in air without or with liquid assistant agent.

11 . The method of claim 1 wherein mechanochemical processing is conducted in the absence of a solvent.

12 . The method of claim 1 wherein mechanochemical processing is conducted in the presence of a liquid assistant agent.

13 . A method for recycling spent LIB material, comprising subjecting the spent LIB material to mechanochemical processing by mechanical processing the spent LIB material in the presence of an organic chemical compound or a polymer having a functional moiety that reacts with at least one constituent of the LIB material to produce a water-soluble metal salt.

14 . The method of claim 13 wherein the functional moiety comprises a halogen.

15 . The method of claim 14 wherein the polymer comprises at least one of a polyvinylidene halide, a halogenated polyethylene, a halogenated polystyrene, and halogenated co-polymer.

16 . The method of claim 14 wherein the organic chemical compound comprises a halogenated carboxylic acid.

17 . The method of claim 13 wherein the metal salt comprises at least one of Co halide and Li halide.

18 . The method of claim 17 including further treating the metal salt by aqueous acidic or basic reaction.

19 . The method of claim 13 wherein the mechanical processing includes at least one of milling, grinding, shredding, or extruding of the spent LIB material under inert gas atmosphere or in air without or with liquid assistant agent.

20 . The method of claim 13 wherein mechanochemical processing is conducted in the absence of a solvent.

Assignees

• Univ Iowa State Res Found Inc

Inventors

• Dolotko Oleksandr
• Balema Viktor
• Hlova Ihor
• Gupta Shalabh
• Mudryk Yaroslav
• Pecharsky Vitalij K

Classifications

• H01M6/52

  Reclaiming serviceable parts of waste cells or batteries {, e.g. recycling} · CPC title

• C22B26/12

  Obtaining lithium · CPC title

• C22B7/006

  Wet processes · CPC title

• B09B3/35

  Shredding, crushing or cutting · CPC title

• B09B3/70

  Chemical treatment, e.g. pH adjustment or oxidation (involving an extraction step B09B3/80) · CPC title