Retroreflective Colored Articles
US-2017293056-A1 · Oct 12, 2017 · US
US2020299529A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2020299529-A1 |
| Application number | US-201816607246-A |
| Country | US |
| Kind code | A1 |
| Filing date | Apr 25, 2018 |
| Priority date | Apr 28, 2017 |
| Publication date | Sep 24, 2020 |
| Grant date | — |
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Described herein are opaque water-based inks that include water and an opacity-providing polymer component. In one aspect, the opacity providing polymer component is a hollow sphere polymer material. The opacity-providing polymer material may replace all or part of white opacifying pigment material, such as titanium dioxide. Also described herein is a method of opacifying a printing ink by adding hollow sphere resin particles and a colorant to a printing ink that comprises water as a volatile component.
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1 - 29 . (canceled) 30 . A method of opacifying a printing ink comprising adding hollow sphere resin particles and a colorant to a printing ink that comprises water as a volatile component. 31 . The method of claim 30 , wherein the colorant comprises a white pigment that, as a result of the inclusion of the hollow sphere resin particles, the amount of white pigment is reduced by 10 wt % to 30 wt % based on a printing ink that comprises a colorant comprising a white pigment material that does not include hollow sphere resin particles, wherein wear of parts of a printing press contacting the ink is reduced. 32 . The method of claim 31 , wherein the white pigment is selected from titanium dioxide, zinc sulfide, and mixtures thereof. 33 . The method of claim 30 , wherein the colorant comprises pigments and dyes that emit color in the visible, infrared, and ultraviolet spectrum, white pigments and dyes, and mixtures thereof. 34 . The method of claim 33 , wherein the colorant comprises a white pigment selected from titanium dioxide, zinc sulfide, and mixtures thereof. 35 . The method of claim 30 , wherein the colorant comprises pigments and dyes that emit color in the visible, infrared, and ultraviolet spectrum and does not include white pigments and dyes. 36 . The method of claim 30 , wherein the colorant comprises pigments and dyes that emit color in the visible spectrum. 37 . The method of claim 30 , wherein the colorant comprises pigments and dyes that emit color in the visible spectrum and does not include white pigments and dyes. 38 . The method of claim 30 , wherein the hollow sphere resin particles are voided latex particles. 39 . The method of claim 31 , wherein the hollow sphere resin particles are voided latex particles. 40 . The method of claim 30 , wherein the hollow sphere resin particles are present in an amount from about 1.0 wt % to about 50 wt %, preferably 10 wt % to about 50 wt %, more preferably 20 wt % to about 50 wt %, and more preferably 30 wt % to about 50 wt %, based on the total weight of the composition. 41 . The method of claim 30 , wherein a hollow sphere resin component is present in an amount from 10-90%, based on the total weight of the composition. 42 . The method of claim 41 , wherein the hollow sphere resin component comprises the hollow sphere resin particles and water. 43 . The method of claim 30 , wherein about 10 wt % to about 100 wt % of the volatile component is water. 44 . The method of claim 30 , further comprising a volatile component selected from alcohols, esters, aliphatic hydrocarbons, cyclic hydrocarbons, aromatic hydrocarbons, ketones, aldehydes, ethers, and mixtures thereof. 45 . The method of claim 30 , wherein the colorant comprises a pigment dispersion. 46 . The method of claim 30 , further comprising one or more waxes. 47 . The method of claim 30 , further comprising a crosslinker. 48 . A method of improving die cutting blade durability comprising the steps of printing on a substrate a printing ink comprising hollow sphere resin particles and a colorant in a printing ink that comprises water as a volatile component to provide a printed substrate, and cutting the printed substrate with a die-cutting blade, wherein the printing ink improves the durability of the die-cutting blade relative to printing inks that include large amounts of abrasive white pigment materials. 49 . The method of claim 48 , wherein the abrasive white pigment materials are selected from titanium dioxide, zinc sulfide, and mixtures thereof. 50 . The method of claim 48 , wherein the printing is performed by a printing method selected from flexographic and gravure printing.
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