Sulfur-carbon composite and lithium-sulfur battery including same

Patent metadata

Field	Value
Publication number	US-2020280052-A1
Application number	US-201816646484-A
Country	US
Kind code	A1
Filing date	Oct 5, 2018
Priority date	Nov 3, 2017
Publication date	Sep 3, 2020
Grant date	—

Abstract

A sulfur-carbon composite and a lithium-sulfur battery including the same, and in particular, to a sulfur-carbon composite including a porous carbon material; a polymer having electrolyte liquid loading capacity; and sulfur. The porous carbon material may be coated with the polymer having electrolyte liquid loading capacity and the coated porous carbon material then mixed with the sulfur. By introducing a coating layer including the polymer having electrolyte liquid loading capacity to a surface of the porous carbon material, it is possible to improve reactivity of the sulfur and an electrolyte liquid and thereby enhance performance and lifetime properties of the lithium-sulfur battery.

First claim

1 . A sulfur-carbon composite comprising:
a porous carbon material; a polymer having electrolyte liquid loading capacity; and sulfur.

2 . The sulfur-carbon composite of claim 1 , wherein a coating layer is present on at least one selected from the group consisting of an inner surface of the porous carbon material and an outer surface of the porous carbon material, wherein the coating layer comprises the polymer having electrolyte liquid loading capacity.

3 . The sulfur-carbon composite of claim 2 , wherein the the coating layer-formed porous carbon material is mixed with the sulfur.

4 . The sulfur-carbon composite of claim 1 , wherein the polymer has an electrolyte liquid loading capacity of 50% or greater.

5 . The sulfur-carbon composite of claim 1 , wherein the polymer having electrolyte liquid loading capacity comprises at least one selected from the group consisting of polyurethane, polyethylene oxide, polypropylene oxide, polyvinylidene fluoride, polyvinylidene fluoride-hexafluoropropylene, polyolefin, poly(meth)acrylate, polymethyl methacrylate, polycarbonate, polymethyl carbonate, polyethyl oxazoline, polyvinyl acetate, polyvinyl chloride, polyvinyl ether and polyvinyl pyrrolidone.

6 . The sulfur-carbon composite of claim 1 , wherein the polymer having electrolyte liquid loading capacity is present in an amount of from 0.1 parts by weight to 50 parts by weight, based on 100 parts by weight of the porous carbon material.

7 . The sulfur-carbon composite of claim 1 , wherein the porous carbon material comprises at least one selected from the group consisting of graphite, graphene, carbon black, carbon nanotubes, carbon fibers, natural graphite, artificial graphite, expanded graphite and activated carbon.

8 . The sulfur-carbon composite of claim 1 , wherein the sulfur comprises at least one selected from the group consisting of inorganic sulfur of formula S 8 , Li 2 S n , wherein n≥1, disulfide compounds, organosulfur compounds and carbon-sulfur polymers of formula (C 2 S x ) n , wherein x=2.5 to 50, and n≥2.

9 . A method for preparing a sulfur-carbon composite comprising the steps of:
(a) coating a porous carbon material with a polymer having electrolyte liquid loading capacity and (b) mixing the porous carbon material coated with the polymer having electrolyte liquid loading capacity prepared in (a) with sulfur, and molding the result.

10 . The method for preparing a sulfur-carbon composite of claim 9 , wherein the step (b) includes mixing the porous carbon material coated with the polymer having electrolyte liquid loading capacity with sulfur and heating and molding the result.

11 . A positive electrode for a lithium-sulfur battery comprising the sulfur-carbon composite of claim 1 .

12 . A lithium-sulfur battery comprising the positive electrode of claim 11 .

Assignees

• Lg Chemical Ltd

Inventors

• Cho Eunkyung
• Koh Dongwook
• Sohn Kwonnam
• Yang Doo Kyung

Classifications

• H01M10/052

  Li-accumulators · CPC title

• H01M4/38

  of elements or alloys · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/362 Primary

  Composites · CPC title

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title