Process for production of elastomer agglomerate composition, elastomer agglomerate composition and its use

Patent metadata

Field	Value
Publication number	US-2020238232-A1
Application number	US-201816652266-A
Country	US
Kind code	A1
Filing date	Oct 12, 2018
Priority date	Oct 13, 2017
Publication date	Jul 30, 2020
Grant date	—

Abstract

The invention relates to a process for the production of an elastomer agglomerate composition, comprising: forcing a slurry through an aperture in a valve assembly ( 1 ) to obtain the elastomer agglomerate composition; wherein the valve assembly ( 1 ) comprises the valve ( 2 ) and a seat ( 3 ) that are arranged opposite each other to provide a flow channel for the slurry to be homogenized with an emulsifying channel section ( 5 ) that is provided with the aperture; wherein the emulsifying flow channel section is arranged at an angle (a) with respect to an axial center line of the valve in a cross sectional view of the valve assembly; and wherein the slurry comprises elastomeric particles in water.

First claim

1 . A process for the production of an elastomer agglomerate composition, comprising:
forcing a slurry through an aperture in a valve assembly to obtain the elastomer agglomerate composition; wherein the valve assembly comprises the valve and a seat that are arranged opposite each other to provide a flow channel for the slurry to be homogenized with an emulsifying channel section that is provided with the aperture; wherein the emulsifying flow channel section is arranged at a sharp angle with respect to an axial center line of the valve in a cross sectional view of the valve assembly; and wherein the slurry comprises elastomeric particles in water.

2 . The process according to claim 1 , wherein the elastomeric particles are selected from the group consisting of polybutadiene particles, poly(styrene butadiene) particles, poly(acrylonitrile butadiene) particles and polybutylacrylate particles and combinations thereof.

3 . The process according to claim 1 , wherein the elastomeric particles are selected from the group consisting of polybutadiene particles, poly(styrene butadiene) particles comprising at least 50 wt % of units derived from butadiene, poly(acrylonitrile butadiene) particles and polybutylacrylate particles and combinations thereof.

4 . The process according to claim 1 , wherein the elastomeric particles are polybutadiene particles.

5 . The process according to claim 1 , wherein the slurry is substantially free of chemical agglomerants, preferably the amount of the chemical agglomerants being less than 0.01 wt % with respect to the total of the solids content in the slurry and any chemical agglomerants.

6 . The process according to claim 1 , wherein the slurry has a temperature of 40 to 80° C., preferably 45 to 80° C.

7 . The process according to claim 1 , wherein the flow channel has a Y-shaped cross section, and wherein the valve has a cone-shaped surface that is directed towards the seat.

8 . The process according to claim 1 , wherein the emulsifying channel section has a first width, as seen in a direction perpendicular to a flow of the fluid to be homogenized, that is adjustable by moving the valve and the seat with respect to each other, and preferably wherein the flow channel has an inlet flow channel section having a second width, as seen in the direction perpendicular to the flow of the fluid to be homogenized, that is larger than the first width.

9 . The process according to claim 1 , wherein the elastomeric particles in the slurry have an average particle size D 50 , as is determined in accordance with ISO 9276-2:2014; and wherein the elastomer agglomerate composition has at most 40 vol %, preferably at most 30 vol %, underhomogenized portion, and at most 10 vol %, preferably at most 8 vol %, overhomogenized portion, based upon a total volume of the elastomer agglomerate composition.

10 . (canceled)

11 . (canceled)

12 . (canceled)

13 . The process according to claim 1 , wherein:
the elastomeric particles are selected from the group consisting of polybutadiene particles, poly(styrene butadiene) particles comprising at least 50 wt % of units derived from butadiene, poly(acrylonitrile butadiene) particles and polybutylacrylate particles and combinations thereof; the slurry is substantially free of chemical agglomerants, preferably the amount of the chemical agglomerants being less than 0.01 wt % with respect to the total of the solids content in the slurry and any chemical agglomerants; the slurry has a temperature of 40 to 80° C., preferably 45 to 80° C.; the flow channel has a Y-shaped cross section, and wherein the valve has a cone-shaped surface that is directed towards the seat; the emulsifying channel section has a first width, as seen in a direction perpendicular to a flow of the fluid to be homogenized, that is adjustable by moving the valve and the seat with respect to each other, and preferably wherein the flow channel has an inlet flow channel section having a second width, as seen in the direction perpendicular to the flow of the fluid to be homogenized, that is larger than the first width; and the elastomeric particles in the slurry have an average particle size D 50 , as is determined in accordance with ISO 9276-2:2014; and wherein the elastomer agglomerate composition has at most 40 vol %, preferably at most 30 vol %, underhomogenized portion, and at most 10 vol %, preferably at most 8 vol %, overhomogenized portion, based upon a total volume of the elastomer agglomerate composition.

14 . The process according to claim 1 ,
wherein the elastomeric particles are selected from the group consisting of polybutadiene particles, poly(styrene butadiene) particles comprising at least 50 wt % of units derived from butadiene, poly(acrylonitrile butadiene) particles and polybutylacrylate particles and combinations thereof; wherein the slurry is substantially free of chemical agglomerants, and wherein the amount of the chemical agglomerants being less than 0.01 wt % with respect to the total of the solids content in the slurry and any chemical agglomerants; wherein the slurry has a temperature of 45 to 80° C.; wherein the emulsifying channel section has a first width, as seen in a direction perpendicular to a flow of the fluid to be homogenized, that is adjustable by moving the valve and the seat with respect to each other, and wherein the flow channel has an inlet flow channel section having a second width, as seen in the direction perpendicular to the flow of the fluid to be homogenized, that is larger than the first width; wherein the elastomeric particles in the slurry have an average particle size D 50 , as is determined in accordance with ISO 9276-2:2014; and wherein the elastomer agglomerate composition has at most 30 vol %, underhomogenized portion, and at most 8 vol %, overhomogenized portion, based upon a total volume of the elastomer agglomerate composition.

15 . The process according to claim 14 , wherein the elastomeric particles are polybutadiene particles.

16 . The process according to claim 1 , wherein the slurry is substantially free of chemical agglomerants, and the amount of the chemical agglomerants is less than 0.01 wt % with respect to the total of the solids content in the slurry and any chemical agglomerants.

17 . The process according to claim 1 , wherein the slurry has a temperature of 45 to 80° C.

18 . The process according to claim 1 , wherein the emulsifying channel section has a first width, as seen in a direction perpendicular to a flow of the fluid to be homogenized, that is adjustable by moving the valve and the seat with respect to each other, and wherein the flow channel has an inlet flow channel section having a second width, as seen in the direction perpendicular to the flow of the fluid to be homogenized, that is larger than the first width.

19 . The process according to claim 1 , wherein the elastomeric particles in the slurry have an average particle size D 50 , as is determined in accordance with ISO 9276-2:2014; and wherein the elastomer agglomerate composition has at most 30 vol %, underhomogenized portion, and at most 8 vol %, overhomogenized portion, based upon a total volume of the elastomer agglomerate composition.

Assignees

• Sabic Global Technologies Bv

Inventors

• Li Dejin
• Nelson Mark Erik
• Ferraris Dane
• Lowry Vern

Classifications

• B01F25/4413

  the slits being formed between opposed conical or cylindrical surfaces · CPC title

• B01F25/4422 Primary

  the surfaces being maintained in a fixed but adjustable position, spaced from each other, therefore allowing the slit spacing to be varied (B01F25/4423 takes precedence) · CPC title

• C08C1/065 Primary

  Increasing the size of dispersed rubber particles · CPC title

• B01F2101/2805

  Mixing plastics, polymer material ingredients, monomers or oligomers · CPC title

• B01F25/4412

  the slits being formed between opposed planar surfaces, e.g. pushed again each other by springs · CPC title