Supercapacitors with Carbon Nanostructure Electrodes
US-2015380174-A1 · Dec 31, 2015 · US
US2020122129A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2020122129-A1 |
| Application number | US-201716473335-A |
| Country | US |
| Kind code | A1 |
| Filing date | Dec 22, 2017 |
| Priority date | Dec 27, 2016 |
| Publication date | Apr 23, 2020 |
| Grant date | — |
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In relation to a Cu-based delafossite-type oxide that is effective as an exhaust gas purification catalyst, Cu is placed in a high catalytic activity low-valence state, whereby a novel Cu-based delafossite-type oxide having higher activity than in the past is provided. Proposed is a delafossite-type oxide for an exhaust gas purification catalyst that is represented by a general formula ABO2, wherein Cu and Ag are contained in the A site of the general formula, one or two or more elements selected from the group consisting of Mn, Al, Cr, Ga, Fe, Co, Ni, In, La, Nd, Sm, Eu, Y, V, and Ti are contained in the B site of the general formula, and Ag is contained at a ratio of 0.001 at. % or more and less than 20 at. % in the A site of the general formula.
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1 . A delafossite-type oxide for an exhaust gas purification catalyst, represented by a general formula ABO 2 , wherein Cu and Ag are comprised in the A site of the general formula, one or two or more elements selected from the group consisting of Mn, Al, Cr, Ga, Fe, Co, Ni, In, La, Nd, Sm, Eu, Y, V, and Ti are comprised in the B site of the general formula, and Ag is comprised at a ratio of 0.001 at. % or more and less than 20 at. % in the A site of the general formula. 2 . The delafossite-type oxide for an exhaust gas purification catalyst according to claim 1 , wherein one or two or more elements selected from the group consisting of Mn, Al, Cr, and Ga are comprised in the B site of the general formula. 3 . The delafossite-type oxide for an exhaust gas purification catalyst according to claim 1 , wherein only Mn is comprised in the B site of the general formula, or Mn and one or two or more elements selected from the group consisting of Al, Cr, and Ga are comprised in the B site of the general formula. 4 . The delafossite-type oxide for an exhaust gas purification catalyst according to claim 1 , wherein Mn and one or two or more elements selected from the group consisting of Al, Cr, and Ga are comprised in the B site of general formula, and the atomic ratio of the content of Mn to the total content of Al, Cr, and Ga in the B site of the general formula is 10:90 to 90:10. 5 . An exhaust gas purification catalyst, comprising the delafossite-type oxide according to claim 1 and an inorganic porous material. 6 . An exhaust gas purification catalyst, having a configuration in which the exhaust gas purification catalyst according to claim 5 is supported on a substrate made of metal or ceramics.
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