Catalysts and methods for alcohol dehydration
US-2015375214-A1 · Dec 31, 2015 · US
US2020070139A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2020070139-A1 |
| Application number | US-201716346997-A |
| Country | US |
| Kind code | A1 |
| Filing date | Nov 3, 2017 |
| Priority date | Nov 3, 2016 |
| Publication date | Mar 5, 2020 |
| Grant date | — |
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The invention relates to a catalyst useful in the steam reforming of hydrocarbons and oxygenated hydrocarbons. The invention provides a method for preparing a catalyst comprising heating a spinel of formula ANixFe(1-X)CrO4 where A is Mn or Mg and x is from 0 to 0.75 under reducing conditions at a temperature of from 800 to 1500° C., and catalysts obtainable by said method.
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1 - 8 . (canceled) 9 . A method for preparing a catalyst comprising heating a spinel of formula ANi x Fe (1-x) CrO 4 where A is Mn or Mg and x is from >0 to 0.75 under reducing conditions at a temperature of from 800 to 1500° C. so as to cause a restructuring of the spinel to form a catalyst comprising a porous spinel phase supporting metal particles of Ni, Fe, mixtures thereof and/or alloys thereof. 10 . The method according to claim 1 , wherein the spinel of formula ANi x Fe (1-x) CrO 4 is single phase. 11 . The method according to claim 1 , wherein when A is Mn, x is less than or equal to 0.55. 12 . The method according to claim 1 , wherein the metal particles have a particle size of 10 nm to 5 μm. 13 . A catalyst obtainable by the method of claim 1 . 14 . A method of steam reforming a hydrocarbon or an oxygenated hydrocarbon comprising contacting said hydrocarbon or oxygenated hydrocarbon with steam and the catalyst according to claim 13 . 15 . A method according to claim 14 , wherein said oxygenated hydrocarbon is steam reformed. 16 . A method according to claim 14 , wherein said oxygenated hydrocarbon is glycerol.
Reducing · CPC title
Hydrocarbons · CPC title
Alcohols · CPC title
Spinels · CPC title
Manganese · CPC title
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