Systems and methods for producing metal clusters; functionalized surfaces; and droplets including solvated metal ions

Patent metadata

Field	Value
Publication number	US-2020024762-A1
Application number	US-201916415531-A
Country	US
Kind code	A1
Filing date	May 17, 2019
Priority date	Sep 13, 2013
Publication date	Jan 23, 2020
Grant date	—

Abstract

The invention generally relates to systems and methods for producing metal clusters; functionalized surfaces; and droplets including solvated metal ions. In certain aspects, the invention provides methods that involve providing a metal and a solvent. The methods additionally involve applying voltage to the solvated metal to thereby produce solvent droplets including ions of the metal containing compound, and directing the solvent droplets including the metal ions to a target. In certain embodiments, once at the target, the metal ions can react directly or catalyze reactions.

First claim

1 - 20 . (canceled)

21 . A method for producing a functionalized substrate, the method comprising:
providing a substrate; providing a focusing mask; and spraying, under ambient conditions, metal ions from a droplet emitter toward the focusing mask such that the ions interact with the focusing mask and are focused to a discrete location on the substrate, thereby producing an aggregate of metal nanoparticles at the discrete location on the substrate.

22 . The method according to claim 21 , further comprising:
moving to at least one other discrete location on the substrate; and spraying, under ambient conditions, metal ions from a droplet emitter toward another location on the focusing mask such that the ions interact with the other location on the focusing mask and are focused to another discrete location on the substrate, thereby producing an aggregate of uncapped metal nanoparticles at the other discrete location on the substrate.

23 . The method according to claim 21 , wherein the method is repeated a plurality of times to produce an array of discrete spots.

24 . The method according to claim 22 , further comprising depositing a sample on the substrate.

25 . The method according to claim 24 , wherein the sample is deposited prior to the spraying step.

26 . The method according to claim 24 , wherein the sample is deposited after to the spraying step.

27 . The method according to claim 21 , wherein the substrate comprises a metal.

28 . The method according to claim 21 , wherein the uncapped metal nanoparticles are uniform in size.

29 . The method according to claim 21 , wherein the focusing mask is a non-conductive focusing mask.

30 . The method according to claim 21 , wherein the focusing mask is a conductive focusing mask.

31 . A method for producing a functionalized substrate, the method comprising:
providing a substrate; providing a focusing mask; and spraying, under ambient conditions, metal ions from a droplet emitter toward the focusing mask such that the ions interact with the focusing mask and are focused to a discrete location on the substrate, wherein the focusing mask may selectively block a portion of the metal ions, thereby producing an aggregate of metal nanoparticles at the discrete location on the substrate.

32 . The method according to claim 31 , further comprising:
moving to at least one other discrete location on the substrate; and spraying, under ambient conditions, metal ions from a droplet emitter toward another location on the focusing mask such that the ions interact with the other location on the focusing mask and are focused to another discrete location on the substrate, thereby producing an aggregate of uncapped metal nanoparticles at the other discrete location on the substrate.

33 . The method according to claim 31 , wherein the method is repeated a plurality of times to produce an array of discrete spots.

34 . The method according to claim 32 , further comprising depositing a sample on the substrate.

35 . The method according to claim 34 , wherein the sample is deposited prior to the spraying step.

36 . The method according to claim 34 , wherein the sample is deposited after to the spraying step.

37 . The method according to claim 31 , wherein the substrate comprises a metal.

38 . The method according to claim 31 , wherein the uncapped metal nanoparticles are uniform in size.

39 . The method according to claim 31 , wherein the focusing mask is a non-conductive focusing mask.

40 . The method according to claim 31 , wherein the focusing mask is a conductive focusing mask.

Assignees

• Purdue Research Foundation

Inventors

• Cooks Robert Graham
• Li Anyin
• Pradeep Thalappil
• Baird Zane

Classifications

• C25C1/20

  of noble metals · CPC title

• C25C7/06 Primary

  Operating or servicing · CPC title

• C25C7/00

  Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells (for the production of aluminium C25C3/06 - C25C3/22) · CPC title

• C25C1/22

  of metals not provided for in groups C25C1/02 - C25C1/20 · CPC title

• Y02P10/234

  Cross-Sectional Technologies · mapped topic