Mixing system for producing aqueous repair coating products, method for the production thereof, and aqueous repair coating products produced from the mixing system

Patent metadata

Field	Value
Publication number	US-2020010721-A1
Application number	US-201716319096-A
Country	US
Kind code	A1
Filing date	Jul 20, 2017
Priority date	Jul 20, 2016
Publication date	Jan 9, 2020
Grant date	—

Abstract

Provided herein is a mixer system for producing refinish compositions, more particularly for the sector of automotive finishing, including at least mutually different components (1), (2), and (3), namely component (1) as base varnish, component (2) as tinting base, and component (3) as rheology module, with at least one of components (1) to (3) including at least one aqueous dispersion including at least one polymer prepared by multistage emulsion polymerization, and at least one of components (1) to (3) including at least one aliphatic monoalcohol having 5 carbon atoms and/or at least one aliphatic monoalcohol having 6 carbon atoms. Further provided herein is an aqueous refinish composition that is produced by the mixing of components (1) to (3), and a method for producing aqueous refinish compositions. Further provided herein is a use of the mixer system for producing aqueous refinish compositions for automotive refinishing.

First claim

1 . A mixer system for producing aqueous refinish compositions, the mixer system comprising:
at least one component (1) as pigment-free base varnish, comprising at least one physically curing polyurethane or a self-crosslinking polyurethane or an externally crosslinking polyurethane; at least one component (2) as tinting base, comprising at least one physically drying polyurethane or a self-crosslinking polyurethane or an externally crosslinking polyurethane and at least one color-imparting and/or optical-effect-imparting pigment; and at least one component (3) as rheology module, comprising at least one inorganic and/or organic thickener, wherein at least one of the components, (1), (2), or (3), comprises an aqueous dispersion comprising at least one polymer SCS, and wherein at least one of the components, (1), (2), or (3), comprises at least one aliphatic monoalcohol having 5 carbon atoms and/or at least one aliphatic monoalcohol having 6 carbon atoms, the aqueous dispersion being prepared by the successive radical emulsion polymerization of three mutually different monomer mixtures (A), (B), and (C) of olefinically unsaturated monomers, wherein optionally at least one of the monomer mixtures, (A), (B) or (C), comprises at least one polyurethane (P) containing at least one olefinically unsaturated group, and wherein, before the optional polyurethane (P) is admixed to at least one of the monomer mixtures (A), (B) or (C), the monomer mixture (A) comprises at least 50 wt % of monomers having a solubility in water of less than 0.5 g/l at 25° C., and a polymer (a) that is prepared from the mixture (A) possesses a glass transition temperature of 10 to 65° C., the monomer mixture (B) comprises at least one polyunsaturated monomer, and a polymer (b) that is prepared from the mixture (B) possesses a glass transition temperature of −35 to 15° C., and a polymer (c) that is prepared from the monomer mixture (C) possesses a glass transition temperature of −50 to 15° C., and wherein i. first the monomer mixture (A) is polymerized, ii. then the monomer mixture (B) is polymerized in the presence of the polymer prepared under i., and iii. thereafter the monomer mixture (C) is polymerized in the presence of the polymer prepared under ii.

2 . The mixer system as claimed in claim 1 , wherein at least one of the components, (1), (2), or (3), comprises both the aqueous dispersion comprising at least one polymer SCS and the aliphatic monoalcohol having 5 carbon atoms and/or at least one aliphatic monoalcohol having 6 carbon atoms.

3 . The mixer system as claimed in claim 1 , wherein at least one of the monomer mixtures, (A), (B), or (C), comprises at least one polyurethane (P).

4 . The mixer system as claimed in claim 1 , wherein the at least one aliphatic monoalcohol having 5 carbon atoms is n-pentanol, and the at least one aliphatic monoalcohol having 6 carbon atoms is n-hexanol.

5 . The mixer system as claimed in claim 1 , wherein the weight-percentage fraction of the sum of all aliphatic monoalcohols having 5 carbon atoms and 6 carbon atoms in the respective component (1), (2), or (3) is less than 5 wt %, based on the respective component (1), (2), or (3), and at least one of the components, (1), (2), or (3), has a weight-percentage fraction of the sum of all aliphatic monoalcohols having 5 carbon atoms and 6 carbon atoms of at least 1.0 wt %, based on the total weight of the respective component (1), (2), or (3).

6 . The mixer system as claimed in claim 1 , wherein the fraction of the monomer mixture (A) is from 0.1 to 10 wt %, the fraction of the monomer mixture (B) is from 60 to 80 wt %, and the fraction of the monomer mixture (C) is from 10 to 30 wt %, based in each case on the sum of the individual amounts of the mixtures (A), (B), and (C).

7 . The mixer system as claimed in claim 1 , wherein the monomer mixture (A) comprises at least one monounsaturated ester of (meth)acrylic acid with an alkyl radical, and at least one vinyl group-containing, monoolefinically unsaturated monomer with a radical arranged on the vinyl group that is aromatic or that is mixed saturated aliphatic-aromatic, in which case wherein the aliphatic fractions of the radical are alkyl groups.

8 . The mixer system as claimed in claim 1 , wherein the monomer mixture (B) further comprises at least one monounsaturated ester of (meth)acrylic acid with an alkyl radical, and at least one vinyl group-containing, monoolefinically unsaturated monomer with a radical arranged on the vinyl group that is aromatic or that is mixed saturated aliphatic-aromatic, wherein the aliphatic fractions of the radical are alkyl groups.

9 . The mixer system as claimed in claim 1 , wherein the monomer mixture (C) comprises at least one alpha-beta-unsaturated carboxylic acid, at least one monounsaturated ester of (meth)acrylic acid with an alkyl radical substituted by a hydroxyl group, and at least one monounsaturated ester of (meth)acrylic acid with an alkyl radical.

10 . An aqueous refinish composition produced by mixing components (1), (2), and (3) of the mixer system as claimed in claim 1 , with the further admixing of a crosslinker if component (1) and/or (2) comprises an externally crosslinking polyurethane.

11 . The aqueous refinish composition as claimed in claim 10 , wherein the weight-percentage fraction of the at least one polymer SCS in the aqueous dispersion, based on the total weight of the aqueous refinish composition, is 1.0 to 24.0 wt %.

12 . The aqueous refinish composition as claimed in claim 10 , wherein the weight-percentage fraction of the sum of all aliphatic monoalcohols having 5 carbon atoms and 6 carbon atoms, based on the total weight of the refinish composition, is from 0.2 to 3.0 wt %.

13 . The aqueous refinish composition as claimed in claim 10 , wherein the aqueous refinish composition has a VOC content of less than 250 g/l.

14 . A method for producing refinish compositions comprising using the mixer system as claimed in claim 1 .

15 . A method of using the mixer system as claimed in claim 1 , the method comprising using the mixer system for producing refinish compositions for automotive refinishing.

Assignees

• Basf Coatings Gmbh

Inventors

• Corten Cathrin
• Eierhoff Dirk
• Schnieders Britta
• Freitag Nicole
• Rademacher Josef
• Grabbe Michael

Classifications

• C08F220/1804

  C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate · CPC title

• C08F220/1806

  C6-(meth)acrylate, e.g. (cyclo)hexyl (meth)acrylate or phenyl (meth)acrylate · CPC title

• C08G18/758

  containing two or more cycloaliphatic rings · CPC title

• C08G18/3271

  Hydroxyamines · CPC title

• C08F257/02

  on to polymers of styrene or alkyl-substituted styrenes · CPC title