Electrochemical system for producing ammonia from nitrogen oxides and preparation method thereof

Patent metadata

Field	Value
Publication number	US-2020002180-A1
Application number	US-201916448692-A
Country	US
Kind code	A1
Filing date	Jun 21, 2019
Priority date	Jun 29, 2018
Publication date	Jan 2, 2020
Grant date	—

Abstract

It is an object of the present invention to provide an electrochemical system for producing ammonia from nitrogen oxides which can perform the reaction at room temperature under normal pressure with high ammonia selectivity, and a preparation method thereof.
To achieve the object above, the present invention provides an electrochemical system for producing ammonia from nitrogen oxides characteristically comprising a cathode electrode where the reduction reaction of a complex of nitrogen oxide and a metal complex compound occurs, an anode electrode, a reference electrode, an electrolyte including a metal complex compound, and a nitrogen oxide supply unit.
The present invention also provides a method for producing ammonia from nitrogen oxides, which characteristically comprises the steps of introducing nitrogen oxide in the electrochemical system; forming a complex from the introduced nitrogen oxide and the metal complex compound included in the electrolyte; and performing an electrical reduction reaction of the formed complex. According to the present invention, ammonia can be produced from nitrogen oxides via electrochemical method under normal atmospheric pressure and at room temperature with a high selectivity.

First claim

What is claimed is:

1 . An electrochemical system for producing ammonia from nitrogen oxides characteristically comprising a cathode electrode where the reduction reaction of a complex of nitrogen oxide and a metal complex compound occurs, an anode electrode, a reference electrode, an electrolyte including a metal complex compound, and a nitrogen oxide supply unit.

2 . The electrochemical system according to claim 1 , wherein the nitrogen oxide is nitrogen monoxide.

3 . The electrochemical system according to claim 1 , wherein the metal of the metal complex compound is iron or magnesium.

4 . The electrochemical system according to claim 1 , wherein the complex compound is a salt selected from the group consisting of ethylenediamine tetraacetic acid (EDTA), 1,2-cyclohexanediamine tetraacetic acid (CyDTA), and nitrilo disodium triacetate (NTA).

5 . The electrochemical system according to claim 1 , wherein the material forming the cathode electrode or the anode electrode is one or more substances selected from the group consisting of iron, glassy carbon (GC), aluminum, copper, silver, nickel, platinum, oxides thereof, and alloys thereof.

6 . The electrochemical system according to claim 1 , wherein when the material forming the cathode electrode is silver or copper, the applied potential difference is in the range of 0.2 to −0.4 Volt by the reference hydrogen electrode; when the material is glassy carbon, the applied potential difference is in the range of −0.3 to −0.4 Volt; and when the material is platinum, the applied potential difference is in the range of 0.4 to −0.4 Volt.

7 . The electrochemical system according to claim 1 , wherein the pH of the electrolyte is maintained in the range of 6˜8.

8 . A method for producing ammonia from nitrogen oxides comprising the following steps:
introducing nitrogen oxide in the electrochemical system; forming a complex from the introduced nitrogen oxide and the metal complex compound included in the electrolyte; and performing an electrical reduction reaction of the formed complex.

9 . The method for producing ammonia from nitrogen oxides according to claim 8 , wherein the nitrogen oxide is nitrogen monoxide.

10 . The method for producing ammonia from nitrogen oxides according to claim 8 , wherein the concentration of the metal complex compound is 10 mM-500 mM.

11 . The method for producing ammonia from nitrogen oxides according to claim 8 , wherein when the material forming the cathode electrode is silver or copper, the applied potential difference is in the range of 0.2 to −0.4 Volt by the reference hydrogen electrode; when the material is glassy carbon, the applied potential difference is in the range of −0.3 to −0.4 Volt; and when the material is platinum, the applied potential difference is in the range of 0.4 to −0.4 Volt.

12 . The method for producing ammonia from nitrogen oxides according to claim 8 , wherein the pH of the electrolyte included in the electrochemical system for the electrical reduction reaction is maintained in the range of 6˜8.

Assignees

• Korea Res Inst Chemical Tech

Inventors

• Kim Dong Yeon
• Kwon Young Kook
• Heo Iljeong
• Kim Beom Sik

Classifications

• C01C1/02

  Preparation, {purification} or separation of ammonia · CPC title

• C25B1/00 Primary

  Electrolytic production of inorganic compounds or non-metals · CPC title

• C25B11/04

  characterised by the material · CPC title

• C01C1/026 Primary

  Preparation of ammonia from inorganic compounds · CPC title

• C01C1/04

  Preparation of ammonia by synthesis (preparation or purification of gas mixtures for ammonia synthesis C01B3/025) · CPC title