A method of making a polycrystalline super hard constructions

Patent metadata

Field	Value
Publication number	US-2019344236-A1
Application number	US-201716474140-A
Country	US
Kind code	A1
Filing date	Dec 28, 2017
Priority date	Dec 31, 2016
Publication date	Nov 14, 2019
Grant date	—

Abstract

A method of forming polycrystalline diamond comprised placing a plurality of graphene nano-platelets into a capsule; and subjecting the platelets to a pressure of around 10 GPa to around 20 GPa and a temperature of around 1600 degrees Celsius to around 3000 degrees Celcius to convert the graphene platelets to nano-polycrystalline diamond. There is also disclosed a polycrystalline super hard construction comprising a polycrystalline diamond region comprising polycrystalline diamond material formed according to said method.

First claim

1 . A method of forming polycrystalline diamond, comprising:
placing a plurality of graphene nano-platelets into a capsule; and subjecting the platelets to a pressure of around 10 GPa to around 20 GPa and a temperature of around 1600 degrees Celsius to around 3000 degrees Celcius to convert the graphene platelets to nano-polycrystalline diamond.

2 . The method of claim 1 wherein the step of subjecting the platelets to said pressure and temperature comprises subjecting the platelets to a pressure of between around 10 GPa to around 15 GPa.

3 . The method of claim 1 , wherein the step of subjecting the platelets to said pressure and temperature comprises subjecting the platelets to said temperature and pressure for around 1 minute to around 60 minutes.

4 . The method of claim 1 , wherein the step of subjecting the platelets to said pressure and temperature comprises subjecting the platelets to a temperature of around 1600 degrees Celsius to around 2500 degrees Celsius.

5 . (canceled)

6 . The method of claim 1 , wherein the step of placing a plurality of graphene nano-platelets into a capsule comprises placing graphene platelets having a lateral size of between around 5 microns to around 25 microns into the capsule.

7 . The method of claim 1 , wherein size of nanodiamonds produced is between around 1 nm to around 999 nm.

8 . The method of claim 1 , further comprising treating the platelets to reduce the presence of oxygen terminated groups on the surfaces of the platelets to less than around 5000 ppm.

9 . The method of claim 1 , further comprising treating the platelets to reduce the presence of oxygen terminated groups on the surfaces of the platelets to less than around 1000 ppm.

10 . The method of claim 1 , further comprising treating the platelets to reduce the presence of oxygen terminated groups on the surfaces of the platelets to less than around 500 ppm.

11 . The method of claim 1 , further comprising treating the platelets to reduce the presence of oxygen terminated groups on the surfaces of the platelets to less than around 200 ppm.

12 . The method of claim 1 , wherein the step of placing a plurality of graphene nano-platelets into a capsule comprises placing graphene platelets having an average thickness of between around 0.1 nm to around 15 nm into the capsule.

13 . The method of claim 1 , wherein the step of placing a plurality of graphene nano-platelets into a capsule comprises placing graphene platelets having an average thickness in the Z dimension of between around 1 nm to around 15 nm into the capsule.

14 . The method of claim 1 , wherein the step of placing a plurality of graphene nano-platelets into a capsule comprises placing graphene platelets having an average thickness in the X-Y dimension of between around 20 nm to 25000 nm in the capsule.

15 . The method of claim 1 , wherein the step of placing a plurality of graphene nano-platelets into a capsule comprises placing graphene platelets having an average thickness in the X-Y dimension of between around 500 nm to around 15000 nm into the capsule.

16 . The method of claim 1 , wherein the step of placing a plurality of graphene nano-platelets into a capsule comprises placing graphene platelets having an aspect ratio of between around 200 to 25000, or around 500 to 20000, or from 1000 to 15000 into the capsule.

17 . The method of claim 1 , further comprising cleaning the graphene nano-platelets prior to placing into the capsule.

18 . The method of claim 17 , wherein the step of cleaning comprises cleaning the platelets with any one or more of ethanol, propanol, and distilled water to remove soluble substances.

19 . The method of claim 1 , further comprising mixing the graphene nano platelets with a second phase material and the step of placing the graphene nano platelets into the capsule comprises placing the second phase material mixed with the graphene nano platelets into the capsule.

20 . The method of claim 19 , wherein the second phase material comprises any one or more of nano cBN grains, nano polycrystalline cubic boron nitride, nano monocrystalline cubic boron nitride, or nano cubic silicon nitride.

21 . The method of claim 19 , wherein the formed nano polycrystalline diamond comprises around 0.1 vol % to 99.9 vol % of the material, and the nano second phase material comprises between around 99.9 vol % to 0.1 vol %.

22 . The method of claim 1 , wherein size of nanodiamonds produced is between around 50 nm to around 200 nm.

23 . The method of claim 1 , wherein the step of subjecting the platelets to a pressure of around 10 GPa to around 20 GPa and a temperature of around 1600 degrees Celsius to around 3000 degrees Celcius to convert the graphene platelets to nano-polycrystalline diamond further comprises converting the graphene platelets to nano-polycrystalline diamond comprising a twinned crystal structure when viewed along a plane.

24 . The method of claim 21 , wherein the formed nano polycrystalline diamond comprises a plurality of nano polycrystalline diamond crystals having a twinned crystal structure and the nano second phase material comprises a plurality of nano sized crystals of the second phase material having a twinned crystal structure.

25 . The method of claim 1 , wherein the step of subjecting the platelets to a pressure of around 10 GPa to around 20 GPa and a temperature of around 1600 degrees Celsius to around 3000 degrees Celcius to convert the graphene platelets to nano-polycrystalline diamond comprises forming a nano-polycrystalline diamond material having a laminar layered structure.

26 - 35 . (canceled)

Assignees

• Element Six Uk Ltd

Inventors

• Wang Dong
• Miranda-Fernandez Miriam

Classifications

• B01J2203/0645

  Boronitrides · CPC title

• C04B2235/386

  Boron nitrides · CPC title

• C04B2235/427

  Diamond · CPC title

• C04B35/528

  obtained from carbonaceous particles with or without other non-organic components · CPC title

• B01J2203/0615

  Fullerene · CPC title