Gas Diffusion Electrodes and Methods for Fabricating and Testing Same
US-2015376803-A1 · Dec 31, 2015 · US
US2019336956A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2019336956-A1 |
| Application number | US-201716094562-A |
| Country | US |
| Kind code | A1 |
| Filing date | Apr 6, 2017 |
| Priority date | Apr 19, 2016 |
| Publication date | Nov 7, 2019 |
| Grant date | — |
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Provided is a catalyst that can exhibit high activity. The catalyst is an electrode catalyst having catalytic metals supported on a catalyst support, in which the catalytic metals include platinum and a metal component other than platinum; the electrode catalyst has mesopores having a mode radius of pore distribution of mesopores having a radius of 1 nm or more, of 1 nm or more and less than 2.5 nm; alloy microparticles of platinum and the metal component other than platinum are supported inside the mesopores; and a molar content ratio of platinum with respect to the metal component other than platinum in the alloy microparticles supported inside the mesopores is 1.0 to 10.0.
Opening claim text (preview).
1 . An electrode catalyst in which catalytic metals are supported on a catalyst support, wherein the catalytic metals include platinum and a metal component other than platinum, the electrode catalyst has mesopores having a radius of 1 nm or more, with a mode radius of pore distribution of the mesopores being 1 nm or more and less than 2.5 nm, alloy microparticles of platinum and the metal component other than platinum are supported inside the mesopores, and a molar content ratio of platinum with respect to the metal component other than platinum in the alloy microparticles supported inside the mesopores is 1.0 to 10.0. 2 . The electrode catalyst according to claim 1 , wherein the electrode catalyst has a pore volume of the mesopores of 0.4 cc/g of the support or more. 3 . The electrode catalyst according to claim 1 , wherein the alloy microparticles supported inside the mesopores have an average diameter of 2.0 nm or more. 4 . The electrode catalyst according to claim 1 , wherein the alloy microparticles in the electrode catalyst have, as an internal structure, an intermetallic compound structure having platinum atoms and metal atoms other than platinum arranged with regularity. 5 . The electrode catalyst according to claim 4 , wherein the alloy microparticles in the electrode catalyst have an L1 2 structure, and the L1 2 structure has an extent of ordering of 30% to 100%. 6 . The electrode catalyst according to claim 1 , wherein the metal component other than platinum is cobalt (Co). 7 . A membrane electrode assembly comprising the electrode catalyst according to claim 1 and an electrolyte. 8 . A fuel cell comprising the membrane electrode assembly according to claim 7 .
characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence) · CPC title
Cobalt and noble metals · CPC title
Alloys or mixtures with metallic elements · CPC title
supported on carriers, e.g. powder carriers · CPC title
Coating with slurry or ink · CPC title
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