SOEC System with Heating Ability

Patent metadata

Field	Value
Publication number	US-2019330751-A1
Application number	US-201716310254-A
Country	US
Kind code	A1
Filing date	Jun 8, 2017
Priority date	Jun 17, 2016
Publication date	Oct 31, 2019
Grant date	—

Abstract

A Solid Oxide Electrolysis System has electrolytes with increased Area Specific Resistance, ASR yet is thin as compared to known electrolytes in the field, to obtain heating of the endothermic reducing process performed in the electrolysis cells directly where it is needed without any extra heating appliances or integrated heating elements, a simple efficient solution which does not increase the volume of the stack.

First claim

1 . A solid oxide electrolysis system comprising a planar solid oxide electrolysis cell stack comprising a plurality of solid oxide electrolysis cells, each cell comprising layers of an oxidizing electrode, a reducing electrode and an electrolyte, comprising of a first electrolyte layer, a second electrolyte layer, and a layer formed by interdiffusion of the first electrolyte layer and the second electrolyte layer, wherein the area-specific resistance of the electrolyte, measured at 700° C., is higher than 0.2 Ω cm 2 and the total thickness of the electrolyte is less than 25 μm.

2 . A solid oxide electrolysis system according to claim 1 , wherein the total thickness of the electrolyte is between 5 μm and 25 μm.

3 . A solid oxide electrolysis system according to claim 1 , wherein the first electrolyte layer is composed primarily of stabilized zirconia, the second electrolyte layer is composed primarily of doped ceria, and a third layer between the above layers is formed by interdiffusion (interdiffusion layer).

4 . A solid oxide electrolysis system according to claim 3 , wherein the first electrolyte material is primarily (Y 2 O 3 ) x (ZrO 2 ) 1-x , where 0.02≤x≤0.10 or (Y 2 O 3 ) y (L 2 O 3 ) z (ZrO 2 ) 1-y-z or (Sc 2 O 3 ) y (L 2 O 3 ) z (ZrO 2 ) 1-y-z , where 0.0≤y≤0.12, 0≤z≤0.06, and L is Ce, Gd, Ga, Y, Al, Yb, Bi, or Mn.

5 . A solid oxide electrolysis systems according to claim 3 , wherein the second electrolyte materials is primarily (Ln 2 O 3 ) x (CeO 2 ) 1-x , where 0.02≤x≤0.30, and Ln is a lanthanide or mixture of two lanthanides.

6 . A solid oxide electrolysis system according to claim 1 , wherein the thickness of the interdiffusion layer is at least 300 nm.

7 . A solid oxide electrolysis system according to claim 1 , wherein at least 65% of the area-specific resistance of the electrolyte originates from the interdiffusion layer.

8 . A solid oxide electrolysis system according to claim 4 , wherein the interdiffusion layer is obtained by sintering the electrolyte layers at temperatures above 1250° C.

9 . A solid oxide electrolysis system according to claim 1 , wherein the in-plane electrical conductivity of the oxidizing electrode, measured at 700° C. in air, at is higher than 30 S/cm.

10 . A solid oxide electrolysis system according to claim 1 , wherein the oxidizing electrode comprises two or more layers.

11 . A solid oxide electrolysis system according to claim 10 , wherein the oxidizing electrode layer closest to the electrolyte is a composite of doped ceria and Ln 1-x-a Sr x MO 3±δ , where Ln is a lanthanide or mixture thereof, M is Mn, Co, Fe, Cr, Ni, Ti, Cu or mixture thereof, 0≤x≤0.95, 0≤a≤0.05, and 0≤δ≤0.25, and the oxidizing electrode layer farthest from the electrolyte is primarily Ln 1-x-a Sr x MO 3±δ , Ln 1-a Ni 1-y Co y O 3±δ , or Ln 1-a Ni 1-y Fe y O 3±δ , where 0≤y≤1, or mixtures thereof.

12 . A solid oxide electrolysis system according to claim 1 wherein the operating temperature is in the range of 650° C.-900° C.

13 . A solid oxide electrolysis system according to claim 1 where the reaction occurring in the reducing electrode comprises the electrochemical reduction of CO 2 to CO.

Assignees

• Haldor Topsoe As

Inventors

• Blennow Bengt Peter Gustav
• Heiredal-Clausen Thomas
• Holt Nørby Tobias
• Küngas Rainer
• Rass-Hansen Jeppe
• Skafte Theis Løye

Classifications

• H01M8/126

  the electrolyte containing cerium oxide · CPC title

• C25B1/00

  Electrolytic production of inorganic compounds or non-metals · CPC title

• C04B2237/348

  Zirconia, hafnia, zirconates or hafnates · CPC title

• C25B13/04 Primary

  characterised by the material · CPC title

• H01M2300/0077

  based on zirconium oxide · CPC title