Decontaminating rock samples by thermovaporization

Patent metadata

Field	Value
Publication number	US-2019317070-A1
Application number	US-201916451731-A
Country	US
Kind code	A1
Filing date	Jun 25, 2019
Priority date	Aug 17, 2017
Publication date	Oct 17, 2019
Grant date	—

Abstract

A rock sample includes multiple rock samples that are each obtained from the borehole. The rock samples have been exposed to contamination during a drilling operation to drill the borehole. The rock sample is split into a first sample portion and a second sample portion. The first sample portion is decontaminated with a solvent. The second sample portion is decontaminated by thermovaporization for an initial duration of time at an initial thermovaporization temperature below that of a cracking temperature of an organic matter carried within the rock sample. A difference between a first pyrolysis Tmax value of the first sample portion decontaminated by the solvent and a second pyrolysis Tmax value of the second sample portion decontaminated by the thermovaporization is determined to satisfy a decontamination level threshold. The remainder of rock samples are decontaminated by the thermovaporization in response to determining that the difference satisfies the decontamination level threshold.

First claim

What is claimed is:

1 . A method of decontaminating a rock sample obtained from a borehole, the method comprising:
thermovaporizing the rock sample to a thermovaporization temperature below that of a cracking temperature of organic matter carried within the rock sample, the thermovaporization temperature sufficient to at least partially decontaminate the rock sample; and ceasing to thermovaporize the rock sample at the thermovaporization temperature.

2 . The method of claim 1 , wherein the thermovaporization comprises heating up the rock sample while passing an inert carrier gas over the rock sample to at least partially decontaminate the rock sample.

3 . The method of claim 1 , wherein decontaminating the rock sample comprises elevating an initial thermovaporization temperature to greater than 350° C. for an initial duration of time.

4 . The method of claim 3 , wherein the initial duration of time is substantially 60 minutes.

5 . The method of claim 1 , wherein an initial thermovaporization temperature is elevated to substantially 375° C. and an initial duration of time is substantially 30 minutes.

6 . The method of claim 1 , wherein the rock sample comprises a plurality of rock samples, wherein decontaminating the plurality of rock samples by the thermovaporization comprises simultaneously thermovaporizing the plurality of rock samples within a single thermovaporization chamber.

7 . The method of claim 6 , wherein the plurality of rock samples comprises seventy samples.

8 . The method of claim 1 , wherein a portion of the rock sample is separated from the rock sample prior to vaporization, the method further comprising:
decontaminating the portion with a solvent, wherein decontaminating at least partially removes an organic contaminant from the portion; determining that a difference between a first pyrolysis Tmax value of the portion decontaminated by the solvent and a second pyrolysis Tmax value of the portion of the decontaminated by the thermovaporization satisfies a decontamination level threshold; and decontaminating additional rock samples by the thermovaporization in response to determining that the difference satisfies the decontamination level threshold.

9 . The method of claim 8 , wherein determining the difference between a first decontamination level portion of the rock sample decontaminated by the solvent and a second decontamination level of the rock sample by the thermovaporization comprises determining that a difference between the maximum temperature of the portion of the rock sample decontaminated by the solvent and the maximum temperature of the rock sample decontaminated by the thermovaporization is less than 2° C.

10 . The method of claim 8 , further comprising:
adjusting an initial temperature of the thermovaporization or an initial duration of a thermovaporization process of a second rock sample, based on determining that the difference does not satisfy the decontamination level threshold.

11 . The method of claim 10 , wherein adjusting the duration of the thermovaporization process comprises shortening a duration to be less than the initial duration by an amount of time sufficient to prevent the organic matter within the rock sample from cracking.

Assignees

• Saudi Arabian Oil Co

Inventors

• Inan Sedat

Classifications

• B09C1/06

  thermally · CPC title

• G01N1/44

  Sample treatment involving radiation, e.g. heat · CPC title

• B09C1/005

  Extraction of vapours or gases using vacuum or venting · CPC title

• B09C1/065

  by pyrolysis · CPC title

• G01N33/241 Primary

  for hydrocarbon content · CPC title