Process of making multicomponent fibers

Patent metadata

Field	Value
Publication number	US-2019309447-A1
Application number	US-201916373070-A
Country	US
Kind code	A1
Filing date	Apr 2, 2019
Priority date	Apr 9, 2018
Publication date	Oct 10, 2019
Grant date	—

Abstract

A process for making a multicomponent fiber is disclosed. The process comprises extruding at least one water dispersible polymer to create a first polymer flow, extruding at least one water non-dispersible synthetic polymer to create a second polymer flow path, directing the resulting multiple polymer flows into a spinneret having a shaped cross section with a plurality of distribution flow paths, and combining the flow paths together to form a multicomponent fiber having a shaped cross section, wherein the multicomponent fiber comprises: (A) at least one water dispersible polymer; and (B) a plurality of domains comprising one or more water non-dispersible polymers, wherein the domains are substantially isolated from each other by the water dispersible polymer intervening between the domains; and wherein the water dispersible polymer is present at the perimeter of the outside cross-section of the multicomponent fiber in a proportion of no greater than 55% water dispersible polymer.

First claim

What is claimed is:

1 . A process for making a multicomponent fiber comprising:
extruding at least one water dispersible polymer to create a first polymer flow, extruding at least one water non-dispersible synthetic polymer to create a second polymer flow path, directing the resulting multiple polymer flows into a spinneret having a shaped cross section with a plurality of distribution flow paths, and combining the flow paths together to form a multicomponent fiber having a shaped cross section, wherein the multicomponent fiber comprises:
(A) at least one water dispersible polymer; and
(B) a plurality of domains comprising one or more water non--dispersible polymers, wherein the domains are substantially isolated from each other by the water dispersible polymer intervening between the domains; and
wherein the water dispersible polymer is present at the perimeter of the outside cross-section of the multicomponent fiber in a proportion of no greater than 55% water dispersible polymer.

2 . The process of claim 1 , wherein the water dispersible polymer is a water dispersible sulfopolyester.

3 . The process of claim 1 , wherein the water dispersible polymer is present at the perimeter of the outside cross-section of the multicomponent fiber in a proportion selected from no greater than 50% water dispersible polymer, no greater than 45%, no greater than 40%, no greater than 35%, and no greater than 30%.

4 . The process of claim 1 , further comprising drawing the multicomponent fiber, texturing the multicomponent fiber or a combination of drawing and texturing the multicomponent fiber.

5 . The process of claim 4 , wherein the texturing is selected from the group consisting of friction disk texturing, air jet texturing, stuffer box texturing, knife edge texturing and a combination thereof.

6 . The process of claim 1 , further comprising quenching the multicomponent fiber thereby solidifying the multicomponent fiber.

7 . The process according to claim 1 , further comprising applying at least one finish to the multicomponent fiber.

8 . A process for making a multicomponent fiber comprising:
melt spinning at least one water dispersible polymer and at least one water non-dispersible polymer through a shaped cross section to form a multicomponent fiber having a shaped cross section, wherein the multicomponent fiber comprises a plurality of domains comprising the at least one water non-dispersible polymer that are substantially isolated from each other by the water dispersible polymer intervening between the domains; and wherein the water dispersible polymer is present at the perimeter of the outside cross-section of the multicomponent fiber in a proportion of not greater than 55% water dispersible polymer.

9 . The process of claim 8 , wherein the water dispersible polymer is present at the perimeter of the outside cross-section of the multicomponent fiber in a proportion selected from no greater than 50% water dispersible polymer, no greater than 45%, no greater than 40%, no greater than 35%, and no greater than 30%.

10 . The process of claim 8 further comprising drawing the multicomponent fiber, texturing the multicomponent fiber or a combination of drawing and texturing the multicomponent fiber.

11 . The process of claim 10 , wherein the texturing is selected from the group consisting of friction disk texturing, air jet texturing, stuffer box texturing, knife edge texturing and a combination thereof.

12 . The process of claim 8 , further comprising quenching the multicomponent fiber thereby solidifying the multicomponent fiber.

13 . The process according to claim 8 , further comprising applying at least one finish to the multicomponent fiber.

14 . A process for producing at least one multicomponent fiber having a shaped cross section comprising:
spinning at least one water dispersible sulfopolyester having a glass transition temperature (Tg) of at least 25° C. and at least one water non-dispersible polymer into said multicomponent fiber, said water dispersible polymer comprising:
(i) about 50 to about 96 mole percent of one or more residues of isophthalic acid and/or terephthalic acid, based on the total acid residues;
(ii) about 4 to about 30 mole percent, based on the total acid residues, of a residue of sodiosulfoisophthalic acid;
(iii) one or more diol residues, wherein at least 25 mole percent, based on the total diol residues, is a poly(ethylene glycol) having a structure H—(OCH 2 —CH 2 ) n —OH wherein n is an integer in the range of 2 to about 500; and
(iv) 0 to about 20 mole percent, based on the total repeating units, of residues of a branching monomer having 3 or more functional groups wherein the functional groups are hydroxyl, carboxyl, or a combination thereof;
wherein said multicomponent fiber has a plurality of segments comprising said water non-dispersible polymer and said segments are substantially isolated from each other by said sulfopolyester intervening between said segments, wherein the water dispersible polymer is present at the perimeter of the outside cross-section of the multicomponent fiber in a proportion of no greater than 55% water dispersible polymer and optionally, wherein said multicomponent fiber contains less than 10 weight percent of at least one pigment or filler, based on the total weight of said multicomponent fiber.

15 . The process of claim 14 , wherein the water dispersible polymer is present at the perimeter of the outside cross-section of the multicomponent fiber in a proportion selected from no greater than 50% water dispersible polymer; no greater than 45%, no greater than 40%, no greater than 35%, and no greater than 30%.

16 . The process of claim 14 , further comprising drawing the multicomponent fiber, texturing the multicomponent fiber or a combination of drawing and texturing the multicomponent fiber.

17 . The process of claim 16 wherein the texturing is selected from the group consisting of friction disk texturing, air jet texturing, stuffer box texturing, knife edge texturing and a combination thereof.

18 . The process of claim 14 , further comprising quenching the multicomponent fiber thereby solidifying the multicomponent fiber.

19 . The process according to claim 14 , further comprising applying at least one finish to the multicomponent fiber

20 . The process of claim 14 , wherein said multicomponent fiber has an as-spun denier of less than about 15 denier per filament.

Assignees

• Eastman Chem Co

Inventors

• Rudisill Edgar N
• Holbert Jr Richard Moore
• Holbrook Jr Loady Palmer
• Smith Johnathan Wayne
• Urman Kevin Leonard

Classifications

• D01F8/14 Primary

  with at least one polyester as constituent · CPC title

• D02G1/16

  using jets or streams of turbulent gases, e.g. air, steam {(interlacing filaments D02J1/08)} · CPC title

• D01D5/36

  Matrix structure; Spinnerette packs therefor · CPC title

• D01D5/30

  Conjugate filaments; Spinnerette packs therefor · CPC title

• D02J1/08

  Interlacing constituent filaments without breakage thereof, e.g. by use of turbulent air streams · CPC title