Metal-resin composite structure, metal member, and manufacturing method of metal member

Patent metadata

Field	Value
Publication number	US-2019299503-A1
Application number	US-201716305835-A
Country	US
Kind code	A1
Filing date	May 26, 2017
Priority date	May 31, 2016
Publication date	Oct 3, 2019
Grant date	—

Abstract

A metal-resin composite structure ( 106 ) is formed by bonding a metal member ( 103 ) and a resin member ( 105 ) formed of a resin composition. A surface roughness measured regarding six linear portions in total including three arbitrary linear portions parallel with each other and another three arbitrary linear portions perpendicular to the former three linear portions on a surface ( 110 ) of the metal member ( 103 ), based on JIS B0601 (corresponding international standard: ISO4287) satisfies both Requirements (1) and (2).
(1) An average value of ten point average roughnesses (Rz) at an evaluated length of 4 mm is smaller than 20 μm. (2) An average value of mean width of the profile elements (RSm) at an evaluated length of 4 mm is equal to or greater than 20 μm and smaller than 77 μm.

First claim

1 . A metal-resin composite structure which is formed by bonding a metal member and a resin member formed of a resin composition,
wherein a surface roughness measured regarding six linear portions in total including three arbitrary linear portions parallel with each other and another three arbitrary linear portions perpendicular to the former three linear portions on a surface of the metal member, based on JIS B0601 (corresponding international standard: ISO4287) satisfies both Requirements (1) and (2): (1) an average value of ten point average roughnesses (Rz) at an evaluated length of 4 mm is smaller than 20 μm, and (2) an average value of mean width of the profile elements (RSm) at an evaluated length of 4 mm is equal to or greater than 20 μm and smaller than 77 μm.

2 . The metal-resin composite structure according to claim 1 ,
wherein the surface roughness measured regarding six linear portions in total including three arbitrary linear portions parallel with each other and another three arbitrary linear portions perpendicular to the former three linear portions on a surface of the metal member, based on JIS B0601 (corresponding international standard: ISO4287) further satisfies Requirement (3): (3) an average value of arithmetic average roughnesses (Ra) at an evaluated length of 4 mm is smaller than 5 μm.

3 . The metal-resin composite structure according to claim 1 ,
wherein the surface roughness measured regarding six linear portions in total including three arbitrary linear portions parallel with each other and another three arbitrary linear portions perpendicular to the former three linear portions on a surface of the metal member, based on JIS B0601 (corresponding international standard: ISO4287) further satisfies Requirement (1A): (1A) an average value of ten point average roughnesses (Rz) at an evaluated length of 4 mm is equal to or greater than 1 μm and equal to or smaller than 15 μm.

4 . The metal-resin composite structure according to claim 1 ,
wherein the surface roughness measured regarding six linear portions in total including three arbitrary linear portions parallel with each other and another three arbitrary linear portions perpendicular to the former three linear portions on a surface of the metal member, based on JIS B0601 (corresponding international standard: ISO4287) further satisfies Requirement (3A): (3A) an average value of arithmetic average roughnesses (Ra) at an evaluated length of 4 mm is smaller than 3 μm.

5 . The metal-resin composite structure according to claim 1 ,
wherein the metal member is formed of metal materials containing one kind or two or more kinds of metals selected from iron, a steel material, stainless steel, aluminum, an aluminum alloy, magnesium, a magnesium alloy, copper, a copper alloy, zinc, a zinc alloy, tin, a tin alloy, titanium, and a titanium alloy.

6 . The metal-resin composite structure according to claim 1 ,
wherein the resin composition contains one kind or two or more kinds of thermoplastic resins selected from a polyolefin-based resin, a polyester-based resin, a polyphenylene-based resin, and a polyamide-based resin.

7 . The metal-resin composite structure according to claim 1 ,
wherein the resin composition contains one kind or two or more kinds of thermoplastic resins, having a glass transition temperature equal to or higher than 140° C., selected from a polyether ether ketone resin, a polyether ketone resin, a polyimide resin, a polyphenylsulfone resin, and a polyether sulfone resin.

8 . The metal-resin composite structure according to claim 1 ,
wherein the resin composition contains one kind or two or more kinds of amorphous thermoplastic resins selected from a polystyrene resin, a polyacrylonitrile resin, a styrene-acrylonitrile copolymer resin, an acrylonitrile-butadiene-styrene copolymer resin, a polymethyl methacrylate resin, and a polycarbonate resin.

9 . The metal-resin composite structure according to claim 1 ,
wherein the resin composition contains one kind or two or more kinds of thermoplastic elastomers selected from a polyolefin-based elastomer, a polyurethane-based elastomer, a polystyrene-based elastomer, and a polyester-based elastomer.

10 . The metal-resin composite structure according to claim 1 ,
wherein the resin composition contains a thermosetting resin.

11 . The metal-resin composite structure according to claim 10 ,
wherein the resin composition containing the thermosetting resin contains at least one kind selected from a long fiber reinforced composite structure and a continuous fiber reinforced composite structure.

12 . A metal member used for bonding with a resin member formed of a resin composition,
wherein a surface roughness measured regarding six linear portions in total including three arbitrary linear portions parallel with each other and another three arbitrary linear portions perpendicular to the former three linear portions on a surface of the metal member, based on JIS B0601 (corresponding international standard: ISO4287) satisfies both Requirements (1) and (2): (1) an average value of ten point average roughnesses (Rz) at an evaluated length of 4 mm is smaller than 20 μm, and (2) an average value of mean width of the profile elements (RSm) at an evaluated length of 4 mm is equal to or greater than 20 μm and smaller than 77 μm.

13 . The metal member according to claim 12 ,
wherein the surface roughness measured regarding six linear portions in total including three arbitrary linear portions parallel with each other and another three arbitrary linear portions perpendicular to the former three linear portions on a surface of the metal member, based on JIS B0601 (corresponding international standard: ISO4287) further satisfies Requirement (3): (3) an average value of arithmetic average roughnesses (Ra) at an evaluated length of 4 mm is smaller than 5 μm.

14 . A manufacturing method of a metal member for manufacturing the metal member according to claim 12 , the method comprising:
a step of roughening a surface of the metal member by an electroless treatment.

15 . The manufacturing method of a metal member according to claim 14 ,
wherein, in the step of roughening the surface of the metal member, the surface of the metal member is subjected to a roughening treatment by an acid etching agent, and the acid etching agent contains an aqueous solution or a water dispersion, containing a metal salt (Q) represented by Formula (1):
MX  (1)

(In Formula (1), M represents a metal element in IA group, IIA group, IIIB group, or IVA group in the periodic table, and X represents fluorine atom, chlorine atom, bromine atom, or iodine atom).

16 . The manufacturing method of a metal member according to claim 15 ,
wherein the acid etching agent contains at least one of a ferric ion and a cupric ion, and the aqueous solution or the water dispersion, containing the metal salt (Q) represented by Formula (1).

17 . The manufacturing method of a metal member according to claim 15 ,
wherein the metal element (M) of Formula (1) is one or more kinds selected from Li, Na, K, Mg, Ca, Ba, and Al.

Assignees

• Mitsui Chemicals Inc

Inventors

• Kimura Kazuki
• Sugita Haruka
• Tomita Yoshihiko

Classifications

• C25D11/08

  containing inorganic acids · CPC title

• C25D11/16

  Pretreatment {, e.g. desmutting} · CPC title

• C23F1/20

  for etching aluminium or alloys thereof · CPC title

• C23F1/36

  for etching aluminium or alloys thereof · CPC title

• B29K2995/0072

  Roughness, e.g. anti-slip · CPC title