Device for fractional condensation of arsenic lead vapor mixture and application method thereof

Patent metadata

Field	Value
Publication number	US-2019284658-A1
Application number	US-201916352199-A
Country	US
Kind code	A1
Filing date	Mar 13, 2019
Priority date	Mar 13, 2018
Publication date	Sep 19, 2019
Grant date	—

Abstract

A device is provided for fractional condensation of an arsenic-lead vapor mixture and an application method thereof. The device includes a vacuumizing device, a flange, temperature measuring devices, a graded vacuum furnace body, a quartz tube, a push rod, a control cabinet, a heating zone and recycled foil. The length of the quartz tube is 1.2-2 m; the length of the heating zone is 0.15-0.25 m; and the quartz tube is provided with one temperature measuring device every 2-3 cm. The device forms a certain temperature gradient in the quartz tube, so that a material condenses in the corresponding temperature range, thereby achieving the purpose of high-efficiency separation.

First claim

What is claimed is:

1 .- 6 . (canceled)

7 . A device for fractional condensation of an arsenic-lead vapor mixture, comprising:
a vacuumizing device, a flange, a plurality of temperature measuring devices, a graded vacuum furnace body, a quartz tube, a push rod, a control cabinet, a heating zone, and recycled foil, wherein one end of the quartz tube is connected with the vacuumizing device through the flange, and another end of the quartz tube is internally sealed and provided with the push rod that can move inside the quartz tube; the quartz tube is internally provided with a recycled foil layer, the quartz tube is provided in the middle thereof with the heating zone, and the quartz tube is externally provided with a furnace shell to form the graded vacuum furnace body; the plurality of temperature measuring devices are evenly inserted in the top of the graded vacuum furnace body, and each of the temperature measuring devices is in contact with the top of the quartz tube; a bottom of the graded vacuum furnace body is provided with the control cabinet, and a controller in the control cabinet is respectively electrically connected with a heating device of the heating zone, the plurality of temperature measuring devices and a mechanical pump of the vacuumizing device; and a length of the quartz tube is 1.2-2 m; a length of the heating zone is 0.15-0.25 m; and the quartz tube is provided with one of the temperature measuring devices every 2-3 cm.

8 . The device of claim 7 , wherein each of the temperature measuring devices is a K-type or Pt—Rh type thermocouple.

9 . The device of claim 7 , wherein the heating device of the heating zone carries out heating by resistance.

10 . The device of claim 7 , wherein the recycled foil is defined by graphite foil or metal foil, having a thickness of 0.2-0.4 mm.

11 . An application method of a device for fractional condensation of an arsenic-lead vapor mixture, comprising:
providing the device for fractional condensation of an arsenic-lead vapor mixture such that it includes a vacuumizing device, a flange, a plurality of temperature measuring devices, a graded vacuum furnace body, a quartz tube, a push rod, a control cabinet, a heating zone, and recycled foil, wherein one end of the quartz tube is connected with the vacuumizing device through the flange, and another end of the quartz tube is internally sealed and provided with the push rod that can move inside the quartz tube; the quartz tube is internally provided with a recycled foil layer, the quartz tube is provided in the middle thereof with the heating zone, and the quartz tube is externally provided with a furnace shell to form the graded vacuum furnace body; the plurality of temperature measuring devices are evenly inserted in the top of the graded vacuum furnace body, and each of the temperature measuring devices is in contact with the top of the quartz tube; a bottom of the graded vacuum furnace body is provided with the control cabinet, and a controller in the control cabinet is respectively electrically connected with a heating device of the heating zone, the plurality of temperature measuring devices and a mechanical pump of the vacuumizing device; and a length of the quartz tube is 1.2-2 m; a length of the heating zone is 0.15-0.25 m; and the quartz tube is provided with one of the temperature measuring devices every 2-3 cm; placing an arsenic-lead material in the quartz tube and pressing the arsenic-lead material with the push rod, and then sealing one side of the quartz tube provided with the push rod; controlling, by the controller, the vacuumizing device to vacuumize the inside of the quartz tube to 0.1-50 Pa, controlling the heating temperature of a heating device of the heating zone to be 800-1100° C., and then pushing the arsenic-lead material to the heating zone by the push rod; maintaining the heating temperature for 60-120 min for vacuum distillation to obtain arsenic vapor and lead vapor; with a temperature of an area of the quartz tube close to the heating zone being high, and temperatures of areas at both sides of the quartz tube being low, condensing the lead vapor obtained by vacuum distillation in a recycled foil area which is at a temperature of 480-700° C. and is close to the heating zone, and condensing the arsenic vapor obtained by vacuum distillation in a low-temperature recycled foil area at a temperature of 110-300° C.

12 . The application method of claim 11 , wherein the arsenic-lead material has an arsenic content of 1-50 wt %.

13 . The application method of claim 11 , wherein each of the temperature measuring devices is a K-type or Pt—Rh type thermocouple.

14 . The application method of claim 13 , wherein the arsenic-lead material has an arsenic content of 1-50 wt %.

15 . The application method of claim 11 , wherein the heating device of the heating zone carries out heating by resistance.

16 . The application method of claim 15 , wherein the arsenic-lead material has an arsenic content of 1-50 wt %.

17 . The application method of claim 11 , wherein the recycled foil is defined by graphite foil or metal foil, having a thickness of 0.2-0.4 mm.

18 . The application method of claim 17 , wherein the arsenic-lead material has an arsenic content of 1-50 wt %.

Assignees

• Univ Kunming Science & Technology

Inventors

• Li Yifu
• Pu Zhenghao
• Yang Bin
• Xu Baoqiang
• Liu Dachun
• Tian Yang
• Jiang Wenlong
• Xiong Neng
• Zhang Huan

Classifications

• C22B30/04

  Obtaining arsenic {(extraction of metal compounds by leaching in organic solutions C22B3/16; treatment or purification of solutions by adsorption on solids C22B3/24, by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42)} · CPC title

• C22B13/02

  by dry processes · CPC title

• C22B9/02 Primary

  Refining by liquating, filtering, centrifuging, distilling, or supersonic wave action {including acoustic waves; (C22B9/003, C22B9/006, C22B9/05, C22B9/22 take precedence)} · CPC title

• B01D3/10 Primary

  Vacuum distillation (B01D3/12 takes precedence) · CPC title

• B01D3/42

  Regulation; Control · CPC title