Method for producing a polymer film

Patent metadata

Field	Value
Publication number	US-2019224902-A1
Application number	US-201716333105-A
Country	US
Kind code	A1
Filing date	Sep 5, 2017
Priority date	Sep 14, 2016
Publication date	Jul 25, 2019
Grant date	—

Abstract

The present invention relates to a process for producing a polymer film (P) comprising at least one copolyamide by extrusion of the copolyamide through a ring die and subsequent stretching of the tube thus obtained by blowing in air. The present invention further relates to the polymer film (P) obtainable by the process of the invention and to a process for packing foods.

First claim

1 . A process for producing a polymer film (P) the process comprising:
i) polymerizing the following components to obtain at least one copolyamide: (A) 15% to 84% by weight of at least one lactam, (B) 16% to 85% by weight of a monomer mixture (M) comprising the following components:
(B1) at least one C 32 -C 40 dimer acid and
(B2) at least one C 4 -C 12 diamine,
where the percentages by weight of components (A) and (B) are each based on the sum total of the percentages by weight of components (A) and (B), in molten form in a first extruder; ii) extruding the at least one copolyamide i) in molten form from a first extruder through a ring die to obtain a tube comprising the at least one copolyamide in molten form; iii) cooling the tube ii) which comprises the at least one copolyamide in molten form in a water bath to a first temperature (T 1 ), and solidifying the at least one copolyamide to obtain a first tubular film comprising the at least one copolyamide; iv) heating the first tubular film iii) to a second temperature (T 2 ) to obtain a heated first tubular film comprising the at least one copolyamide; and v) blowing air into the heated first tubular film iv) to extend the width of the heated first tubular film, and cooling the heated first tubular film to a third temperature (T 3 ) to obtain the polymer film (P) comprising the at least one copolyamide.

2 . The process according to claim 1 , wherein lactam (A) is selected from the group consisting of 3-aminopropanolactam, 4-amino butanolactam, 5-aminopentanolactam, 6-aminohexanolactam, 7-aminoheptanolactam, 8-aminooctanolactam, 9-aminononanolactam, 10-aminodecanolactam, 11-amino undecanolactam and 12-aminododecanolactam.

3 . The process according to claim 1 , wherein the C 4 -C 12 diamine (B2) is selected from the group consisting of tetramethylenediamine, pentamethylenediamine, hexamethylenediamine, decamethylenediamine and dodecamethylenediamine.

4 . The process according to claim 1 , wherein the tube ii) has a thickness in the range from 10 μm to 1 mm.

5 . The process according to claim 1 , wherein the first temperature (T 1 ) in step iii) is in the range from 5 to 50° C.

6 . The process according to claim 1 , wherein:
the at least one copolyamide has a glass transition temperature (T G(C) ) and a melting temperature (T M(C) ); and the second temperature (T 2 ) in step iv) is above the glass transition temperature (T G(C) ) and below the melting temperature (T M(C) ) of the at least one copolyamide.

7 . The process according to claim 1 , wherein the tube comprising the at least one copolyamide is guided through a first roll system during the cooling in step iii) to extend the length of the tube.

8 . The process according to claim 1 , wherein the heated first tubular film comprising the at least one copolyamide is guided through a second roll system during the blowing-in of air in step v) to extend the length of the heated first tubular film.

9 . The process according to claim 1 , wherein the polymer film (P) has a thickness in the range from 0.1 μm to <1 mm.

10 . The process according to claim 1 , further comprising, after step v):
vi) guiding the polymer film (P) obtained in step v) through at least one third roll; vii) heating the polymer film (P) obtained in step v) to a fourth temperature (T 4 ) above the glass transition temperature (T G(C) ) of the at least one copolyamide to obtain a heated polymer film (P); and viii) guiding the heated polymer film (P) obtained in step vii) through at least one fourth roll to obtain the polymer film (P), where the heated polymer film (P), between step vii) and step viii), during step viii) and/or after step viii), is cooled to a fifth temperature (T 5 ) below the glass transition temperature (T G(C) ) of the at least one copolyamide.

11 . A polymer film (P) obtained by the process of claim 1 .

12 . A process for packing foods, the process comprising:
a) providing a food ensheathed by at least one polymer film (P) according to claim 11 , where the at least one polymer film (P) has a provision temperature (T B ); and b) heating the at least one polymer film (P) to a shrink temperature (T S ), which results in shrinkage of the at least one polymer film (P) to obtain the food ensheathed by the at least one shrunk polymer film (P).

13 . The process according to claim 12 , wherein the shrink temperature (T S ) in step b) is in the range from 50 to 200° C.

14 . The process according to claim 12 , wherein the shrink temperature (T S ) in step b) is above the glass transition temperature (T G(C) ) of the at least one copolyamide present in the at least one polymer film (P).

Assignees

• Basf Se

Inventors

• Goetz Walter
• Minkwitz Rolf
• Gruetzner Rolf-Egbert
• Richter Florian

Classifications

• C08G69/34 Primary

  using polymerised unsaturated fatty acids · CPC title

• B65B53/02

  by heat · CPC title

• B29C48/919

  using a bath, e.g. extruding into an open bath to coagulate or cool the material · CPC title

• B32B2307/21

  Anti-static · CPC title

• B65B25/001

  of foodstuffs, combined with their conservation (B65B25/041, B65B25/062, B65B25/067 take precedence) · CPC title