Polymer compound

Patent metadata

Field	Value
Publication number	US-2019218324-A1
Application number	US-201916366343-A
Country	US
Kind code	A1
Filing date	Mar 27, 2019
Priority date	Sep 30, 2016
Publication date	Jul 18, 2019
Grant date	—

Abstract

An object of the present invention is to provide a polymer compound capable of improving adhesiveness between a hydrophobic member and a hydrophilic member. The polymer compound of the present invention is a polymer compound having a repeating unit represented by Formula (I) and a repeating unit represented by Formula (II).

First claim

What is claimed is:

1 . A polymer compound comprising:
a repeating unit represented by Formula (I); and a repeating unit represented by Formula (II),

in Formula (I), R 1 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; X 1 represents a single bond or a divalent linking group selected from the group consisting of —O—, —S—, —COO—, —OCO—, —CONR 2 —, —NR 2 COO—, —CR 2 N—, a substituted or unsubstituted divalent aliphatic group, a substituted or unsubstituted divalent aromatic group, and a combination thereof; R 2 represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, or —X 1 —P 1 ; and P 1 represents a polymerizable group, and
in Formula (II), R 10 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R 11 and R 12 each independently represent a hydrogen atom, a substituted or unsubstituted aliphatic hydrocarbon group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group; R 11 and R 12 may be linked to each other through an alkylene linking group, an arylene linking group, or a linking group of a combination thereof; X 10 represents a single bond or a divalent linking group selected from the group consisting of —O—, —S—, —COO—, —OCO—, —CONR 13 —, —NR 13 COO—, —CR 13 N—, a substituted or unsubstituted divalent aliphatic group, a substituted or unsubstituted divalent aromatic group, and a combination thereof; and R 13 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms.

2 . The polymer compound according to claim 1 ,
wherein the polymerizable group represented by P 1 in Formula (I) is any polymerizable group selected from the group consisting of groups represented by Formulae (P-1) to (P-7),

in Formulae (P-1) to (P-7), * represents a bonding position with X 1 ; R 3 represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms; and two R 3 's may be the same or different from each other and may be linked to each other to form a ring structure.

3 . The polymer compound according to claim 1 ,
wherein the polymerizable group represented by P 1 in Formula (I) is any polymerizable group selected from the group consisting of groups represented by Formulae (P-1) to (P-3),

in Formulae (P-1) to (P-3), * represents a bonding position with X 1 .

4 . The polymer compound according to claim 1 ,
wherein R 1 in Formula (I) is a hydrogen atom or a methyl group, and X 1 in Formula (I) is a divalent linking group selected from the group consisting of —O—, —COO—, —OCO—, a substituted or unsubstituted divalent aliphatic group, and a combination thereof.

5 . The polymer compound according to claim 2 ,
wherein R 1 in Formula (I) is a hydrogen atom or a methyl group, and X 1 in Formula (I) is a divalent linking group selected from the group consisting of —O—, —COO—, —OCO—, a substituted or unsubstituted divalent aliphatic group, and a combination thereof.

6 . The polymer compound according to claim 3 ,
wherein R 1 in Formula (I) is a hydrogen atom or a methyl group, and X 1 in Formula (I) is a divalent linking group selected from the group consisting of —O—, —COO—, —OCO—, a substituted or unsubstituted divalent aliphatic group, and a combination thereof.

7 . The polymer compound according to claim 1 , further comprising:
a repeating unit represented by Formula (III),

in Formula (II), R 20 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R 21 represents an alkyl group having 4 to 20 carbon atoms, an alkyl group having 1 to 20 carbon atoms in which at least one hydrogen atom is substituted with a fluorine atom, or a monovalent organic group including —Si(R a3 )(R a4 )O—; R a3 and R a4 each independently represent an alkyl group, a haloalkyl group, or an aryl group; and L 20 represents a divalent linking group selected from the group consisting of —O—, —COO—, —OCO—, a divalent aliphatic group, and a combination thereof.

8 . The polymer compound according to claim 2 , further comprising:
a repeating unit represented by Formula (III),

in Formula (III), R 20 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R 21 represents an alkyl group having 4 to 20 carbon atoms, an alkyl group having 1 to 20 carbon atoms in which at least one hydrogen atom is substituted with a fluorine atom, or a monovalent organic group including —Si(R a3 )(R a4 )O—; R a3 and R a4 each independently represent an alkyl group, a haloalkyl group, or an aryl group; and L 20 represents a divalent linking group selected from the group consisting of —O—, —COO—, —OCO—, a divalent aliphatic group, and a combination thereof.

9 . The polymer compound according to claim 3 , further comprising:
a repeating unit represented by Formula (III),

in Formula (III), R 20 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R 21 represents an alkyl group having 4 to 20 carbon atoms, an alkyl group having 1 to 20 carbon atoms in which at least one hydrogen atom is substituted with a fluorine atom, or a monovalent organic group including —Si(R a3 )(R a4 )O—; R a3 and R a4 each independently represent an alkyl group, a haloalkyl group, or an aryl group; and L 20 represents a divalent linking group selected from the group consisting of —O—, —COO—, —OCO—, a divalent aliphatic group, and a combination thereof.

10 . The polymer compound according to claim 4 , further comprising:
a repeating unit represented by Formula (III),

in Formula (III), R 20 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R 21 represents an alkyl group having 4 to 20 carbon atoms, an alkyl group having 1 to 20 carbon atoms in which at least one hydrogen atom is substituted with a fluorine atom, or a monovalent organic group including —Si(R a3 )(X a4 )O—; R a3 and R a4 each independently represent an alkyl group, a haloalkyl group, or an aryl group; and L 20 represents a divalent linking group selected from the group consisting of —O—, —COO—, —OCO—, a divalent aliphatic group, and a combination thereof.

11 . The polymer compound according to claim 5 , further comprising:
a repeating unit represented by Formula (III),

in Formula (III), R 20 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R 21 represents an alkyl group having 4 to 20 carbon atoms, an alkyl group having 1 to 20 carbon atoms in which at least one hydrogen atom is substituted with a fluorine atom, or a monovalent organic group including —Si(R a3 )(R a4 )O—; R a3 and R a4 each independently represent an alkyl group, a haloalkyl group, or an aryl group; and L 20 represents a divalent linking group selected from the group consisting of —O—, —COO—, —OCO—, a divalent aliphatic group, and a combination thereof.

12 .

Assignees

• Fujifilm Corp

Inventors

• Katoh Shunya
• Yoshikawa Masaru
• Suzuki Masaaki

Classifications

• C08F222/102

  of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate · CPC title

• C08F220/283

  and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate · CPC title

• C08F220/346

  and further oxygen · CPC title

• C08F222/225

  the ester chains containing seven or more carbon atoms · CPC title

• C08F220/281

  and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate · CPC title