Improved conditioning hair treatment product with washout protection

Patent metadata

Field	Value
Publication number	US-2019216713-A1
Application number	US-201716337289-A
Country	US
Kind code	A1
Filing date	Jul 13, 2017
Priority date	Sep 30, 2016
Publication date	Jul 18, 2019
Grant date	—

Abstract

Hair treatment products comprising, in relation to its weight, from about 0.001 to about 20% by weight of at least one alpha-substituted aldehyde and from about 0.001 to about 50% by weight of at least one amino-functional silicon, which lead to improved structural reinforcement of keratin fibers and improved hair care, and which reduce or prevent color washout in dyed hair.

First claim

1 . A hair treatment agent comprising, based on its weight,
a) from about 0.001 to about 20 wt. % of at least one alpha-substituted aldehyde, b) from about 0.001 to about 50 wt. % of at least one amino-functional silicone.

2 . The hair treatment agent according to claim 1 , wherein it comprises, based on its weight, from about 0.01 to about 10 wt. %, of alpha-substituted aldehyde(s) of formula (I)
Y—CH(X)—CHO  (I),
in which X represents —OH, —Cl, —Br, —I, —O—(CH 2 ) n —CH 3 where n=1, 2, 3 or 4, or —O—(CH 2 ) m —OH where m=1, 2 or 3; Y represents —H, —CH 3 , H 3 C—(CH 2 ) k — where k=1, 2, 3, 4, 5, 6, 7 or 8, —OH, —(CH 2 ) p —OH where p=1, 2, 3 or 4, or —CHO.

3 . The hair treatment agent according to claim 1 , wherein it comprises, based on its weight, from about 0.01 to about 10 wt. %, of at least one alpha-substituted aldehyde from the group
2-hydroxypropanal (X=—OH, Y=—CH 3 ):

2-hydroxyhexanal (X=—OH, Y=H 3 C—(CH 2 ) k — where k=3):

2-hydroxyoctanal (X=—OH, Y=H 3 C—(CH 2 ) k — where k=5):

bromomalonaldehyde (X=Br, Y=—CH=):

2-(2-hydroxyethoxy)acetaldehyde (X=—O—(CH 2 ) p —OH where p=2, Y=—H):

glyceraldehyde (X=—OH, Y=—(CH 2 ) p —OH where p=1):

4 . The hair treatment agent according to claim 1 , wherein it comprises, based on its weight, from about 0.01 to about 20 wt. %, of amino-functional silicone(s).

5 . The hair treatment agent according to claim 1 , wherein it comprises, based on its weight, from about 0.001 to about 20 wt. %, of at least one 4-morpholinomethyl-substituted silicone of formula (Si-VI)

in which
R1 represents —CH 3 , —OH, —OCH 3 , —O—CH 2 CH 3 , —O—CH 2 CH 2 CH 3 , or —O—CH(CH 3 ) 2 ;
R2 represents —CH 3 , —OH, or —OCH 3 ;
B represents an —OH, —O—Si(CH 3 ) 3 , —O—Si(CH 3 ) 2 OH, or —O—Si(CH 3 ) 2 OCH 3 group;
D represents an —H, —Si(CH 3 ) 3 , —Si(CH 3 ) 2 OH, or —Si(CH 3 ) 2 OCH 3 group;
a, b and c represent, independently of one another, integers between 0 and 1,000, with the proviso that a+b+c>0;
m and n represent, independently of one another, integers between 1 and 1,000,
with the proviso that
at least one of the conditions B=—OH or D=—H is met,
the units a, b, c, m and n are distributed randomly or in blocks in the molecule.

6 . The hair treatment agent according to claim 1 , wherein it comprises, based on its weight, from about 0.3 to about 20 wt. %, of amphoteric surfactant(s).

7 . The hair treatment agent according to claim 1 , wherein it comprises, based on the weight of the agent, from about 0.01 to about 3 wt. %, of at least one polymer from the group of cationic cellulose polymers and/or cationic guar derivatives.

8 . The hair treatment agent according to claim 1 , wherein it comprises, based on the weight of the agent, from about 0.05 to about 20 wt. %, of behenyl trimethyl ammonium chloride.

9 . The hair treatment agent according to claim 1 , wherein it additionally comprises, based on the weight of the agent, from about 0.001 to about 10 wt. %, of at least one succinimidyl ester.

10 . The hair treatment agent according to claim 1 , wherein it additionally comprises, based on the weight of the agent, from about 0.01 to about 10 wt. %, of (a) succinimidyl ester(s) of formula (III)

in which
R1 represents —H or an ionic group;
R represents an optionally substituted saturated or unsaturated, linear, branched or cyclic, aliphatic or aromatic hydrocarbon functional group having at least 5 C atoms.

11 . The hair treatment agent according to claim 1 , wherein it comprises, based on its weight, from about 0.01 to about 10 wt. %, of at least one succinimidyl ester from the group

in which R represents -Ph or —(CH 2 )nCH3 where n=4, 5, 6, 7, 8, 9 or 10,

in which R represents -Ph or —(CH 2 )nCH3 where n=4, 5, 6, 7, 8, 9 or 10 and
X represents H, a monovalent cation or the n-th part of an n-valent cation,

12 . The hair treatment agent according to claim 1 , wherein it comprises, based on its weight, from about 0.001 to about 20 wt. % of complexing agents from the group tetrasodium-N,N-bis(carboxylatomethyl)-L-glutamate (tetrasodium glutamate diacetate, GLDA), pentasodium diethylenetriaminepentaacetate (DTPA), tetrasodium iminodisuccinate (IDS), tetrasodium ethylenediaminetetraacetate (EDTA), tetrasodium ethylenediamine disuccinic acid (EDDS), or trisodium hydroxyethyl ethylenediaminetriaccetic acid (HEDTA).

13 . The hair treatment agent according to claim 1 , wherein it comprises, based on its weight, from about 0.001 to about 20 wt. %, of complexing agents from the group
a. tetrasodium-N,N-bis(carboxylatomethyl)-L-glutamate (tetrasodium glutamate diacetate, GLDA)

b. pentasodium diethylenetriaminepentaacetate (DTPA)

c. tetrasodium iminodisuccinate (IDS)

14 . A method for treating hair, wherein an agent according to claim 1 is applied to dry or wet hair, is left there for a period of from about 10 to about 300 seconds, and is rinsed out thereafter.

15 . A method for treating hair, wherein an agent according to claim 1 is applied to dry or wet hair and is left there until the next time the hair is washed.

16 . (canceled)

17 . The hair treatment agent according to claim 1 , wherein it comprises, based on its weight, from about 0.15 to about 5 wt. %, of alpha-substituted aldehyde(s) of formula (I)
Y—CH(X)—CHO  (I),
in which X represents —OH, —Cl, —Br, —I, —O—(CH 2 ) n —CH 3 where n=1, 2, 3 or 4, or —O—(CH 2 ) m —OH where m=1, 2 or 3; Y represents —H, —CH 3 , H 3 C—(CH 2 ) k — where k=1, 2, 3, 4, 5, 6, 7 or 8, —OH, —(CH 2 ) p —OH where p=1, 2, 3 or 4, or —CHO.

18 . The hair treatment agent according to claim 1 , wherein it comprises, based on its weight, from about 0.15 to about 5 wt. %, of at least one alpha-substituted aldehyde from the group
2-hydroxypropanal (X=—OH, Y=—CH 3 ):

2-hydroxyhexanal (X=—OH, Y=H 3 C—(CH 2 ) k — where k=3):

Assignees

• Henkel Ag & Co Kgaa

Inventors

• Scheunemann Volker
• Schulze Zur Wiesche Erik
• Krohn Rene

Classifications

• A61K8/731

  Cellulose; Quaternized cellulose derivatives · CPC title

• A61Q5/02

  Preparations for cleaning the hair · CPC title

• A61Q5/004

  Preparations used to protect coloured hair · CPC title

• A61Q5/12

  Preparations containing hair conditioners · CPC title

• A61K8/44

  Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof · CPC title