Molded Object And Method For Manufacturing the Same

Patent metadata

Field	Value
Publication number	US-2019105853-A1
Application number	US-201816214586-A
Country	US
Kind code	A1
Filing date	Dec 10, 2018
Priority date	Jun 10, 2016
Publication date	Apr 11, 2019
Grant date	—

Abstract

The present invention relates to a molded object and a method for manufacturing the same. The molded object according to the present invention has high density and enhanced properties such as flexural strength or tensile strength, has a small weight change caused by moisture absorption even when used for a long period of time, and has small changes in flexural strength, tensile strength and the like, and therefore, is suited to be used as household materials, industrial materials or the like.

First claim

1 . A molded object having a non-woven fiber structure, the molded object comprising:
a polyester-based fiber; and a binder, wherein the binder is a non-hygroscopic copolymer resin, all or a part of the polyester-based fiber is fused by the binder, wherein natural pores are included inside the molded object, and the molded object has apparent density of 0.5 g/cm 3 to 0.8 g/cm 3 .

2 . The molded object of claim 1 , which has flexural strength of 20 MPa or greater and tensile strength of 50 MPa to 80 MPa.

3 . The molded object of claim 1 , which has flexural modulus in a range of 1.0 GPa to 1.5 GPa, tension stiffness in a range of 1.0 GPa to 1.8 GPa, tensile elongation in a range of 10% to 30%, and peel-off strength in a range of 150 N to 200 N.

4 . The molded object of claim 1 , which has a weight change rate of less than 0.1% after keeping a constant temperature/constant humidity for 100 hours at a temperature of 85° C. and relative humidity of 85%.

5 . The molded object of claim 1 , which has a weight change rate of less than 0.08% after keeping a constant temperature/constant humidity for 100 hours at a temperature of 85° C. and relative humidity of 85%.

6 . The molded object of claim 1 , which has a flexural strength change rate of less than 10% after keeping a constant temperature/constant humidity for 100 hours at a temperature of 85° C. and relative humidity of 85%.

7 . The molded object of claim 1 , which has a flexural strength change rate of less than 5% after keeping a constant temperature/constant humidity for 100 hours at a temperature of 85° C. and relative humidity of 85%.

8 . The molded object of claim 1 , wherein the difference in the density of the 15% outermost portion of the molded object in the thickness direction and the density of the ±15% portion in the center of the molded object in the thickness direction is less than 3%, and the difference between the bonded fiber ratio of the 15% outermost portion of the molded object in the thickness direction and the bonded fiber ratio of the ±15% portion in the center of the molded object in the thickness direction is less than 10%.

9 . The molded object of claim 1 , wherein the difference in the density of the 15% outermost portion of the molded object in the thickness direction and the density of the ±15% portion in the center of the molded object in the thickness direction is less than 1%, and the difference between the bonded fiber ratio of the 15% outermost portion of the molded object in the thickness direction and the bonded fiber ratio of the ±15% portion in the center of the molded object in the thickness direction is less than 5%.

10 . The molded object of claim 1 , wherein the difference in the interfiber bonding ratio of the 15% outermost portion of the molded object in the thickness direction and the interfiber bonding ratio of the ±15% portion in the center of the molded object in the thickness direction is less than 10%.

11 . The molded object of claim 1 ,wherein the difference in the interfiber bonding ratio of the 15% outermost portion of the molded object in the thickness direction and the interfiber bonding ratio of the ±15% portion in the center of the molded object in the thickness direction is less than 5%.

12 . The molded object of claim 1 , which has a thermal conductivity (TC, W/m·K) and an apparent density (AD, g/cm 3 ) that satisfy equation 1 below.
AD/TC≥8   [Equation 1]

13 . The molded object of claim 12 , wherein the molded object has the thermal conductivity of 0.03 to 0.075 W/m·K.

14 . The molded object of claim 1 , which has a ratio between major axis and minor axis of polyester-based fiber (L/D: Aspect Ratio) is a range of 1000 to 3000.

15 . The molded object of claim 1 , which has a ratio between major axis and minor axis of polyester-based fiber (L/D: Aspect Ratio) is a range of 1500 to 2500.

16 . The molded object of claim 1 , wherein the polyester-based fiber is any one or more selected from the group consisting of polyethylene terephthalate (PET), polytrimethylene terephthalate, polybutylene terephthalate and polyethylene naphthalate.

17 . The molded object of claim 1 , wherein the binder has a melting point of 160° C. or higher.

18 . The molded object of claim 1 , further comprising a sheath-core type bicomponent fiber including a core part of a polyester-based fiber; and a sheath part which is a non-hygroscopic copolymer resin surrounding the core part.

19 . The molded object of claim 18 , wherein the polyester-based fiber is any one or more selected from the group consisting of polyethylene terephthalate (PET), polytrimethylene terephthalate, polybutylene terephthalate and polyethylene naphthalate.

20 . A method for manufacturing a molded object comprising:
a) preparing a non-woven fabric by mixing (A) a polyester-based fiber and (B) a sheath-core type bicomponent fiber including a core part of a polyester-based fiber and a sheath part that is a non-hygroscopic copolymer resin surrounding the core part, and then heating and pressurizing the result; b) installing the prepared non-woven fabric on a plurality of unwinding devices, and then moving to a heating press; and c) manufacturing a molded object by heating and pressurizing a plurality of the non-woven fabrics moved to the heating press under a temperature condition of 170° C. to 210° C. and a pressure condition of 1 MPa to 10 MPa.

21 . The method for manufacturing a molded object of claim 20 , further comprising, between b) and c), d) preheating for minutes to 10 minutes under a temperature condition of 160° C. to 210° C.

22 . The method for manufacturing a molded object of claim 20 , wherein, in a), (A) the polyester-based fiber and (B) the sheath-core type bicomponent fiber, including a core part of a polyester-based fiber and a sheath part that is a non-hygroscopic copolymer resin surrounding the core part, are mixed in a weight ratio of 1:99 to 70:30.

23 . The method for manufacturing a molded object of claim 20 , wherein the number of a plurality of the non-woven fabrics is from 2 to 10.

24 . The method for manufacturing a molded object of claim 20 , which is manufactured to a thickness of 5 mm to 7 mm.

25 . A device comprising the molded object of claim 1 , wherein the device is a structural member for a home appliance; an interior or exterior board for construction;
an automotive interior or exterior material; an interior or exterior material for a train, ship, or airplane; a partition board; or an elevator structural member.

26 . A sandwich panel comprising the molded object of claim 1 .

Assignees

• Lg Hausys Ltd

Inventors

• Kim Won
• Lee Myung
• Yu Dayoung
• Lim Jiwon
• Rho Sang Hyun
• Song Dongmin

Classifications

• D04H1/558

  in combination with mechanical or physical treatments other than embossing · CPC title

• B29C70/10 Primary

  characterised by the structure of fibrous reinforcements {, e.g. hollow fibres} · CPC title

• E04C2/16

  of fibres, chips, vegetable stems, or the like · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• B29K2267/00

  Use of polyesters {or derivatives thereof} as reinforcement · CPC title