Limiting-current type gas sensor, fabrication method of the limiting-current type gas sensor and sensor network system
US-2015377823-A1 · Dec 31, 2015 · US
US2019094173A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2019094173-A1 |
| Application number | US-201716079195-A |
| Country | US |
| Kind code | A1 |
| Filing date | Feb 22, 2017 |
| Priority date | Feb 24, 2016 |
| Publication date | Mar 28, 2019 |
| Grant date | — |
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The present invention aims at providing an electrode having more sufficient electrode activity and electrical conductivity as a sensor electrode for various gas sensors than conventional sensor electrodes. The present invention relates to a gas sensor electrode including a platinum-containing layer having mixed and dispersed therein a conductive particle phase composed of Pt or a Pt alloy and a ceramic particle phase, and a ceramic layer containing a ceramic material, wherein the platinum-containing layer and the ceramic layer are porous, and the porosity of the ceramic layer as measured by image analysis of a cross-sectional SEM appearance is from 1 to 40% and the average pore size of the ceramic layer is from 0.1 to 5 μm.
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1 . A gas sensor electrode comprising: a platinum-containing layer having mixed and dispersed therein a conductive particle phase composed of Pt or a Pt alloy and a ceramic particle phase, and a ceramic layer containing a ceramic material, wherein the platinum-containing layer and the ceramic layer are porous, and a porosity of the ceramic layer as measured by image analysis of a cross-sectional SEM appearance is from 1 to 40% and an average pore size of the ceramic layer is from 0.1 to 5 μm. 2 . The gas sensor electrode according to claim 1 , wherein a porosity of the platinum-containing layer as measured by image analysis of a cross-sectional SEM appearance is from 1 to 40% and an average pore size of the platinum-containing layer is from 0.1 to 5 μm. 3 . The gas sensor electrode according to claim 1 , wherein a ratio of a film thickness of the ceramic layer to a film thickness of the platinum-containing layer is from 0.1 to 3. 4 . A method for producing the gas sensor electrode according to claim 1 , the production method of the gas sensor electrode comprising the following steps (1) to (3): (1) a step of coating a green sheet serving as a substrate with a ceramic paste obtained by dispersing a ceramic powder in a solvent, (2) a step of further coating the ceramic paste-coated green sheet surface with a metal paste obtained by dispersing a conductive particle composed of Pt or a Pt alloy and a ceramic powder in a solvent, and (3) a step of firing the green sheet coated with the ceramic paste and the metal paste at 1,300 to 1,600° C.
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