Processing method for lithium ion battery scrap

Patent metadata

Field	Value
Publication number	US-2019084839-A1
Application number	US-201716085337-A
Country	US
Kind code	A1
Filing date	Mar 15, 2017
Priority date	Mar 16, 2016
Publication date	Mar 21, 2019
Grant date	—

Abstract

A method for processing lithium ion battery scrap according to this invention includes a leaching step of leaching lithium ion battery scrap to obtain a leached solution; an aluminum removal step of neutralizing the leached solution to a pH range of from 4.0 to 6.0, then performing solid-liquid separation and removing aluminum in the leached solution to obtain a first separated solution; and an iron removal step of adding an oxidizing agent to the first separated solution and adjusting the pH in a range of from 3.0 to 5.0, then performing solid-liquid separation and removing iron in the first separated solution to obtain a second separated solution.

First claim

1 . A method for processing lithium ion battery scrap, the method comprising:
a leaching step of leaching lithium ion battery scrap to obtain a leached solution; an aluminum removal step of neutralizing the leached solution to a pH range of from 4.0 to 6.0, then performing solid-liquid separation and removing aluminum in the leached solution to obtain a first separated solution; and an iron removal step of adding an oxidizing agent to the first separated solution and adjusting the pH in a range of from 3.0 to 5.0, then performing solid-liquid separation and removing iron in the first separated solution to obtain a second separated solution.

2 . The method for processing the lithium ion battery scrap according to claim 1 , wherein the lithium ion battery scrap contains copper; and
wherein the copper contained in the lithium ion battery scrap is left as a solid in the leaching step, and the copper in the leached solution is removed together with aluminum by the solid-liquid separation in the aluminum removal step.

3 . The method for processing the lithium ion battery scrap according to claim 1 , wherein the oxidizing agent added to the first separated solution in the iron removal step comprises one or more selected from the group consisting of manganese dioxide, positive electrode active materials, and manganese-containing leached residues obtained by leaching the positive electrode active materials.

4 . The method for processing the lithium ion battery scrap according to claim 1 ,
wherein the second separated solution contains manganese, copper, iron and/or aluminum dissolved in the second separated solution; and wherein the method further comprises an extraction step of subjecting the second separated solution to solvent extraction to remove manganese, copper, iron and/or aluminum.

5 . The method for processing the lithium ion battery scrap according to claim 4 , wherein the extraction step comprises subjecting the second separated solution to solvent extraction using a mixed extracting agent containing a phosphate ester-based extracting agent and an oxime-based extracting agent.

6 . The method for processing the lithium ion battery scrap according to claim 4 , further comprising a cobalt/nickel recovery step of recovering cobalt and/or nickel from an extraction residual solution after the extraction step.

7 . The method for processing the lithium ion battery scrap according to claim 6 , further comprising a lithium recovery step of recovering lithium after the cobalt/nickel recovery step.

Assignees

• Jx Nippon Mining & Metals Corp

Inventors

• Ito Junichi
• Arakawa Junichi
• Yokota Takuya
• Higuchi Naoki

Classifications

• C22B7/007

  by acid leaching · CPC title

• C22B26/12

  Obtaining lithium · CPC title

• C22B23/0407

  Leaching processes · CPC title

• H01M10/54

  Reclaiming serviceable parts of waste accumulators · CPC title

• C22B3/44 Primary

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title