Decontaminating rock samples by thermovaporization

Patent metadata

Field	Value
Publication number	US-2019056375-A1
Application number	US-201816059646-A
Country	US
Kind code	A1
Filing date	Aug 9, 2018
Priority date	Aug 17, 2017
Publication date	Feb 21, 2019
Grant date	—

Abstract

A rock sample includes multiple rock samples that are each obtained from the borehole. The rock samples have been exposed to contamination during a drilling operation to drill the borehole. The rock sample is split into a first sample portion and a second sample portion. The first sample portion is decontaminated with a solvent. The second sample portion is decontaminated by thermovaporization for an initial duration of time at an initial thermovaporization temperature below that of a cracking temperature of an organic matter carried within the rock sample. A difference between a first pyrolysis Tmax value of the first sample portion decontaminated by the solvent and a second pyrolysis Tmax value of the second sample portion decontaminated by the thermovaporization is determined to satisfy a decontamination level threshold. The remainder of rock samples are decontaminated by the thermovaporization in response to determining that the difference satisfies the decontamination level threshold.

First claim

What is claimed is:

1 . A method comprising:
decontamination of a rock sample obtained from a borehole, the rock sample included in a plurality of rock samples, each obtained from the borehole, the plurality of rock samples exposed to contamination during a drilling operation to drill the borehole; splitting the rock sample into a first sample portion and a second sample portion; decontaminating the first sample portion with a solvent, wherein decontaminating at least partially removes an organic contaminant from the first sample portion; decontaminating the second sample portion by thermovaporization, for an initial duration of time, at an initial thermovaporization temperature below that of a cracking temperature of an organic matter carried within the rock sample; determining that a difference between a first pyrolysis Tmax value of the first sample portion decontaminated by the solvent and a second pyrolysis Tmax value of the second sample portion decontaminated by the thermovaporization satisfies a decontamination level threshold; and decontaminating a remainder of the plurality of rock samples by the thermovaporization in response to determining that the difference satisfies the decontamination level threshold.

2 . The method of claim 1 , wherein the thermovaporization comprises heating up the second sample portion while passing an inert carrier gas over the second sample portion to at least partially decontaminate the second sample portion.

3 . The method of claim 1 , wherein decontaminating the second sample portion comprises elevating the initial thermovaporization temperature to greater than 350° C. for the initial duration.

4 . The method of claim 3 , wherein the initial duration is substantially 60 minutes.

5 . The method of claim 3 , wherein the initial thermovaporization temperature is elevated to substantially 375° C. and the initial duration is substantially 30 minutes.

6 . The method of claim 1 , wherein determining the difference between a first decontamination level of the first sample portion by the solvent and a second decontamination level of the second sample portion by the thermovaporization comprises determining that a difference between the maximum temperature of the first sample portion by the solvent and the maximum temperature of the second sample portion by the thermovaporization is less than 2° C.

7 . The method of claim 1 , wherein decontaminating the remainder of the plurality of rock samples by the thermovaporization comprises simultaneously thermovaporizing the remainder of the plurality of rock samples within a single thermovaporization chamber.

8 . The method of claim 7 , wherein the plurality of rock samples comprises seventy samples.

9 . The method of claim 1 , wherein the rock sample is a first rock sample, wherein the plurality of rock samples comprises a second rock sample, wherein the method further comprises:
adjusting the thermovaporization initial temperature or the initial duration of a thermovaporization process, based on determining that the difference does not satisfy the decontamination level threshold.

10 . The method of claim 9 , wherein adjusting a duration of the thermovaporization process comprises shortening a duration to be less than the initial duration by an amount of time sufficient to prevent the organic matter within the rock sample from cracking.

11 . A method of decontaminating a rock sample obtained from a borehole, the method comprising:
thermovaporizing the rock sample to a thermovaporization temperature below that of a cracking temperature of organic matter carried within the rock sample, the thermovaporization temperature sufficient to at least partially decontaminate the rock sample; and ceasing to thermovaporize the rock sample at the thermovaporization temperature.

Assignees

• Saudi Arabian Oil Co

Inventors

• Inan Sedat

Classifications

• B09C1/06

  thermally · CPC title

• G01N1/44

  Sample treatment involving radiation, e.g. heat · CPC title

• B09C1/065

  by pyrolysis · CPC title

• B09C1/005

  Extraction of vapours or gases using vacuum or venting · CPC title

• G01N33/241 Primary

  for hydrocarbon content · CPC title