Method and arrangement for determining at least one pore-related parameter of a porous structure

Patent metadata

Field	Value
Publication number	US-2019041313-A1
Application number	US-201716074854-A
Country	US
Kind code	A1
Filing date	Jan 26, 2017
Priority date	Feb 4, 2016
Publication date	Feb 7, 2019
Grant date	—

Abstract

In various embodiments, a method for determining at least one pore-related parameter of a porous structure is provided. The method includes supplying a volatile liquid into a chamber. The method also includes coating a first surface of the porous structure with an evaporation preventing substance. The method further includes placing the coated porous structure within the chamber. The method additionally includes determining an effective mass of the chamber over a period of time. The method also includes determining the at least one pore-related parameter of an uncoated second surface of the coated porous structure based on the effective mass determined. The second surface of the porous structure is opposite the first surface of the porous structure.

First claim

1 . A method for determining at least one pore-related parameter of a porous structure, the method comprising:
supplying a volatile liquid into a chamber; coating a first surface of the porous structure with an evaporation preventing substance; placing the coated porous structure within the chamber; determining an effective mass of the chamber over a period of time; and determining the at least one pore-related parameter of an uncoated second surface of the coated porous structure based on the effective mass determined; wherein the second surface of the coated porous structure is opposite the first surface of the porous structure.

2 . The method according to claim 1 , wherein the porous structure is a tubular porous structure.

3 . The method according to claim 2 , wherein the first surface is an outer surface of the tubular porous structure; and wherein the second surface is an inner surface of the tubular porous structure.

4 . (canceled)

5 . The method according to claim 1 , wherein coating the first surface of the porous structure comprises embedding the porous structure in the evaporation preventing substance so that a substrate comprising the evaporation preventing substance and the porous structure embedded in the evaporation preventing substance is formed.

6 - 8 . (canceled)

9 . The method according to claim 1 , further comprising:
determining an evaporation rate from the effective mass determined; and relating the evaporation rate to a vapour pressure of the volatile liquid at an interface between the volatile liquid in the porous structure and an ambient gas phase within the chamber; wherein determining the at least one pore-related parameter of the porous structure comprises determining the at least one pore-related parameter based on the vapour pressure determined.

10 . The method according to claim 1 , further comprising:
determining an evaporation rate from the effective mass determined; and relating the evaporation rate to a mole fraction of the volatile liquid at an interface between the volatile liquid in the porous structure and an ambient gas phase within the chamber; wherein determining the at least one pore-related parameter of the porous structure comprises determining the at least one pore-related parameter based on the mole fraction determined.

11 . The method according to claim 1 , wherein determining an effective mass of the chamber comprises determining the effective mass of the chamber at a series of time intervals to generate a plurality of instantaneous masses.

12 . The method according to claim 11 , wherein the at least one pore-related parameter is a pore-size distribution; and wherein determining the at least one pore-related parameter of the second surface of the porous structure comprises:
associating a respective instantaneous mass of the generated plurality of instantaneous masses to a respective pore diameter of the porous structure; and determining the pore-size distribution based on the plurality of instantaneous masses generated and the associated pore diameters.

13 . The method according to claim 1 , further comprising saturating the porous structure with the volatile liquid prior to placing the porous structure in the chamber.

14 . The method according to claim 1 , further comprising saturating the porous structure within the chamber with the volatile liquid.

15 . The method according to claim 1 , wherein the volatile liquid is supplied to a base of the chamber so that the chamber comprises a depth of volatile liquid; and wherein the coated porous structure is placed within the chamber such that the porous structure is over the depth of volatile liquid.

16 . The method according to claim 1 , further comprising controlling evaporation of the volatile liquid in the chamber.

17 - 19 . (canceled)

20 . An arrangement for determining at least one pore-related parameter of a porous structure, the arrangement comprising:
a chamber comprising:
a volatile liquid;
a porous structure comprising a first surface and a second surface opposite the first surface, wherein the porous structure comprises an evaporation preventing substance on the first surface of the porous structure, and wherein the second surface of the porous structure is uncoated; and
a mass determination device configured to determine an effective mass of the chamber over a period of time so that the at least one pore-related parameter of the second surface of the porous structure is determined based on the effective mass determined.

21 . The arrangement according to claim 20 , wherein the porous structure is a tubular porous structure.

22 . The arrangement according to claim 21 , wherein the first surface is an outer surface of the tubular porous structure; and wherein the second surface is an inner surface of the tubular porous structure.

23 . The arrangement according to claim 22 , wherein the chamber comprises a disc comprising a substrate, the substrate comprising:
the evaporation preventing substance; and the tubular porous structure embedded in the evaporation preventing substance with the outer surface of the tubular porous structure in contact with the evaporation preventing substance and the inner surface of the tubular porous structure uncoated.

24 - 26 . (canceled)

27 . The arrangement according to claim 20 , wherein the chamber comprises a diffusion resistance element.

28 . (canceled)

29 . The arrangement according to claim 20 , further comprising an absorbent material configured to control a vapour concentration of the volatile liquid.

30 . (canceled)

31 . The arrangement according to claim 20 , further comprising an environmental chamber or incubator configured to maintain a temperature of the chamber.

32 . The arrangement according to claim 20 , further comprising an anti-vibration platform configured to support the mass determination device.

33 . (canceled)

Assignees

• Univ Nanyang Tech

Inventors

• Zamani Farhad
• Akhondi Ebrahim
• Chew Jia Wei
• Krantz William Bernard
• Fane Anthony Gordon

Classifications

• G01N5/02

  by absorbing or adsorbing components of a material and determining change of weight of the adsorbent, e.g. determining moisture content {(absorption bulbs B01D53/00)} · CPC title

• G01N5/04

  by removing a component, e.g. by evaporation, and weighing the remainder · CPC title

• G01N15/0893 Primary

  by measuring weight or volume of sorbed fluid, e.g. B.E.T. method · CPC title

• G01N2015/086

  of films, membranes or pellicules · CPC title