Gas diffusion electrode and method for manufacturing same

Patent metadata

Field	Value
Publication number	US-2019006682-A1
Application number	US-201616064237-A
Country	US
Kind code	A1
Filing date	Dec 16, 2016
Priority date	Dec 24, 2015
Publication date	Jan 3, 2019
Grant date	—

Abstract

A gas diffusion electrode includes a porous carbon electrode substrate and a microporous layer(s) provided at least on one surface of the porous carbon electrode substrate. The porous carbon electrode substrate is composed of carbon short fibers bonded with a resin carbide. When the region of the porous carbon electrode substrate, extending from a plane that has a 50% filling rate and is closest to one surface of the substrate to a plane that has the 50% filling rate and is closest to the other surface thereof, is trisected in the through-plane direction to obtain three layers, a layer located closer to one surface has a layer filling rate different from the layer filling rate of the layer located closer to the other surface. The microporous layer has a thickness under an added pressure of 0.15 MPa of from 28 to 45 μm, and has a thickness under an added pressure of 2 MPa of from 25 to 35 μm.

First claim

1 . A gas diffusion electrode having a microporous layer on at least one surface of a porous carbon electrode substrate,
wherein the porous carbon electrode substrate is composed of carbon short fibers bonded with a resin carbide; wherein the porous carbon electrode substrate has a bulk density of from 0.20 to 0.40 g/cm 3 ; wherein the porous carbon electrode substrate has an areal weight ratio defined below of from 0.3 to 0.65; wherein, when the region of the porous carbon electrode substrate, extending from a plane that has a 50% filling rate defined below and is closest to one surface of the substrate to a plane that has the 50% filling rate and is closest to the other surface thereof, is trisected in the through-plane direction to obtain three layers, a layer located closer to one surface has a layer filling rate defined below different from the layer filling rate of the layer located closer to the other surface; wherein the microporous layer has a thickness under an added pressure of 0.15 MPa of from 28 to 45 μm, and has a thickness under an added pressure of 2 MPa of from 25 to 35 μm; wherein the areal weight ratio is defined as a value obtained by the equation: areal weight ratio=(A−B)/B: wherein A represents the areal weight (g/m 2 ) of the porous carbon electrode substrate, and B represents the areal weight (g/m 2 ) of the carbon short fibers in the porous carbon electrode substrate; wherein the 50% filling rate is defined as a value obtained by measuring the filling rate of a plane at every certain length in the direction from one surface toward the other surface of the porous carbon electrode substrate, then calculating the mean value of the measured filling rates of planes, and further obtaining a value corresponding to 50% of the calculated mean value as the 50% filling rate; and wherein the layer filling rate of a layer is defined as the mean value obtained from the filling rates of planes constituting the layer.

2 . The gas diffusion electrode according to claim 1 , wherein the gas diffusion electrode has a short circuit current density in the thickness direction, as measured in a state where a polymer electrolyte membrane having a thickness of 25 μm is laminated on the microporous layer and while applying a voltage of 2 V and an added pressure of 5 MPa thereto, of 11 mA/cm 2 or less at 90% or more of measurement points.

3 . The gas diffusion electrode according to claim 1 , wherein, of the three layers obtained by the trisection, when the layer located closer to one surface of the porous carbon electrode substrate and having the highest layer filling rate is defined as a layer X, the layer located closer to the other surface and having a layer filling rate lower than that of the layer X is defined as a layer Y, and the layer located between the layer X and the layer Y is defined as a layer Z, the layer filling rates of these layers decrease in the order of the layer X, the layer Y, and the layer Z.

4 . The gas diffusion electrode according to claim 1 , wherein the microporous layer comprises at least a first microporous layer which is in contact with the porous carbon electrode substrate, and a second microporous layer,
wherein the first microporous layer contains a carbon black having a structure index of 3.0 or more; and wherein the second microporous layer contains a carbon black having a structure index of less than 3.0.

5 . A method of producing the gas diffusion electrode according to claim 1 , the method comprising, in the order mentioned:
a compression step of subjecting a precursor fiber sheet to a pressure treatment; a carbonization step of subjecting the pressure treated precursor fiber sheet to a heat treatment to convert a resin into the resin carbide, to obtain the porous carbon electrode substrate; and a microporous layer forming step of forming a microporous layer on one surface of the porous carbon electrode substrate; wherein the precursor fiber sheet after being subjected to the pressure treatment in the compression step has a carbon short fiber density of from 0.14 to 0.2 g/cm 3 .

Assignees

• Toray Industries

Inventors

• Okano Yasutaka
• Urai Junichi
• Tanimura Yasuaki
• Utsunomiya Masamichi

Classifications

• H01M4/96 Primary

  Carbon-based electrodes · CPC title

• H01M4/8875

  Methods for shaping the electrode into free-standing bodies, like sheets, films or grids, e.g. moulding, hot-pressing, casting without support, extrusion without support · CPC title

• H01M4/8657

  layered · CPC title

• H01M4/8807

  Gas diffusion layers · CPC title

• H01M4/861 Primary

  with a gradient in the porosity · CPC title