Apparatus including a ceramic component, a metal component, and a glass sealing material and a process of forming the apparatus

Patent metadata

Field	Value
Publication number	US-2019002337-A1
Application number	US-201616064531-A
Country	US
Kind code	A1
Filing date	Dec 20, 2016
Priority date	Dec 21, 2015
Publication date	Jan 3, 2019
Grant date	—

Abstract

An apparatus can include a ceramic component, a metal component, and a glass sealing material that bonds the ceramic and metal components to each other. In an embodiment, the coefficients of thermal expansion of the components and glass sealing material can be within 4 ppm/° C. of one another. The metal component may be relatively oxidation resistant. The glass sealing material may have a relatively low amount of an amorphous phase as compared to one or more crystalline phases within the glass sealing material. The apparatuses can exhibit good bond strength even after long term exposure to high temperature, thermal cycling to a high temperature, or both. In an embodiment, the metal component may allow another metal component of a different composition to be used without a significant impact on the integrity of the bonded apparatus.

First claim

1 . An apparatus, comprising:
a ceramic component; a glass sealing material; and a metal component bonded to the ceramic component via the glass sealing material, wherein:
each of the ceramic component, the metal component, and the glass sealing material has a coefficient of thermal expansion that is within 4 ppm/° C. of one another, and
the metal component has a normalized weight gain less than 0.06 mg/(cm 2 *hr) or a normalized weight loss less than 0.01 mg/(cm 2 *hr), wherein the weight gain or the weight loss is calculated by formula ΔW n =|(W−W o )|/(500A s ), wherein W o is an original weight of the metal component, W is a weight after the metal component is exposed to 1000° C. in air at atmospheric pressure for 500 hours, and A s is an outer surface area of the metal component.

2 . An apparatus, comprising:
a ceramic component; a glass sealing material; and a metal component bonded to the ceramic component via the glass sealing material, wherein a loss in a bond strength of the apparatus is not greater than 50% after exposure of the apparatus to 1050° C. for 1000 hours or 5 cycles of a temperature change between 22° C. and 1000° C. at a ramp up rate of 5° C./min. and a ramp down rate of 5° C./min.

3 . A process of forming an apparatus, comprising:
providing a ceramic component and a metal component; placing a glass sealing material between the ceramic component and the metal component; and heating the glass sealing material to form a bond between the ceramic component and the metal component, wherein:
each of the ceramic component, the metal component, and the glass sealing material has a coefficient of thermal expansion that is within 4 ppm/° C. of one another, and
the metal component has a normalized weight gain less than 0.06 mg/cm 2 /hr or a normalized weight loss less than 0.01 mg/(cm 2 *hr), wherein the weight gain or the weight loss is calculated by formula ΔW n =(W−W o )/(500A s ), wherein W o is an original weight of the metal component, W is a weight after the metal component is exposed to 1000° C. in air at atmospheric pressure for 500 hours, and A s is an outer surface area of the metal component.

4 . The process of claim 3 further comprising forming an oxidized layer adjacent to the metal component, wherein said oxidized layer is formed prior to placing the glass sealing material.

5 . (canceled)

6 . The process of claim 4 wherein heating the glass sealing material comprises heating the glass sealing material at a first temperature and heating the glass sealing material at a second temperature that is different than the first temperature.

7 . The process of claim 6 , wherein the first temperature is in a range of 930° C. to 1360° C., or in a range of 1050° C. to 1310° C., or in a range of 1150° C. to 1280° C.

8 . The process of claim 7 , wherein the second temperature is in a range of 800° C. to 1050° C., or in a range of 825° C. to 1000° C., or in a range of 850° C. to 950° C.

9 . The process of claim 3 , wherein a loss in a bond strength of the apparatus is not greater than 50% after exposure of the apparatus to 1050° C. for 1000 hours or 5 cycles of a temperature change between 22° C. and 1000° C. at a ramp up rate of 5° C./min. and a ramp down rate of 5° C./min.

10 . The process of claim 3 , wherein the glass sealing material of the seal as initially formed comprises an amorphous phase that is not greater than 10 vol. %, not greater than 5 vol. %, not greater than 3 vol. %, not greater than 1 vol %.

11 . The process of claim 3 wherein the glass sealing material of the seal comprises a sanbornite phase, a hexacelsian phase, and a barium aluminum silicate phase.

12 . The process of claim 11 , wherein the glass sealing material further comprises SrO, TiO 2 , ZrO 2 , or any combination thereof.

13 . The process of claim 3 , wherein each of the ceramic component, the metal component, and the glass sealing material has a coefficient of thermal expansion that is within 3 ppm/° C. of one another, or within 2 ppm/° C., or within 1 ppm/° C., or within 0.5 ppm/° C.

14 . The process of claim 3 , wherein the apparatus comprises a solid oxide fuel cell system, an oxygen transport membrane system, a chemical processing system, or a combination thereof.

15 . An apparatus for forming a joint between a tubular ceramic component and a plurality metal component, said apparatus comprising:
a dense ceramic adapter; a first tubular metal connector comprising proximate and distal ends wherein at least a portion of said first metal connector is contained within the bore of said dense ceramic adapter, a second metal connector configured to receive or form a joint with said first tubular metal connector, and a glass-ceramic sealing material,
wherein said dense ceramic adapter comprises a first female end configured to receive said tubular ceramic component, and a second female end configured to receive the proximal end of said first tubular metal connector, and
wherein the distal end of said first tubular metal connector is configured to engage the corresponding proximal end of said second tubular metal connector,
wherein said glass-ceramic seal material is disposed between the adjacent surfaces of said tubular ceramic component, said dense ceramic adaptor, and said first tubular metal connector thus forming a joint between said adjacent surfaces.

16 . The apparatus of claim 15 wherein each of the ceramic components, the metal connectors, and the glass sealing material has a coefficient of thermal expansion that is within 4 ppm/° C. of one another.

17 . The apparatus of claim 16 where a second metal tubular connector has a larger diameter and is configured to receive at least a portion of said first tubular metal connector that is extending from the dense ceramic adaptor, wherein said first and second tubular metal connectors are joined with a weld or a braze material forming an joint between at least a portion of the contacting or overlapping surfaces of said first and second tubular metal connectors.

18 . The method of claim 17 wherein said second tubular metal connector is composed of a different material than said first tubular metal connector, wherein said material has higher strength or lower rate of creep-strain at temperatures of from about 750° C. to about 1025° C. than the material of said first tubular metal connector.

19 . The apparatus of claim 15 which additionally comprises a third tubular metal connector configured to engage the corresponding proximal end of said second tubular metal connector.

20 . The apparatus of claim 19 where the said second tubular metal connector is joined with the third tubular metal connector by a weld or a braze material forming an joint between the adjoining surfaces of said second and third tubular metal connectors.

Assignees

• Praxair Technology Inc

Inventors

• Kelly Sean M
• Robinson Charles
• Gonzalez Javier E
• Kosowski Lawrence W
• Rich David A
• Lacourse Brian C
• Reis Signo T

Classifications

• C04B2237/84

  Joining of a first substrate with a second substrate at least partially inside the first substrate, where the bonding area is at the inside of the first substrate, e.g. one tube inside another tube · CPC title

• B32B15/18

  comprising iron or steel {(B32B15/011, B32B15/012 and B32B15/013 take precedence)} · CPC title

• C22C38/18

  containing chromium · CPC title

• C04B2237/32

  Ceramic · CPC title

• C04B2237/54

  Oxidising the surface before joining · CPC title