Process of preparing a chemically pre-formed (cpf) iron negative electrode with water

Patent metadata

Field	Value
Publication number	US-2018371602-A1
Application number	US-201816117430-A
Country	US
Kind code	A1
Filing date	Aug 30, 2018
Priority date	Sep 5, 2013
Publication date	Dec 27, 2018
Grant date	—

Abstract

Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the surface of the electrode with water to thereby create an oxidized surface. The resulting iron electrode is preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

First claim

What is claimed is:

1 . An electrode which has not been subject to a charge-discharge cycle, comprising an iron active material, which electrode is prepared by a process comprising:
i) fabricating an electrode comprising an iron active material, and ii) treating the surface of the electrode with water to thereby create an oxidized surface prior to any charge-discharge cycle.

2 . The electrode of claim 1 , wherein the water comprises deionized water.

3 . The electrode of claim 1 , wherein the iron electrode has been treated with water prior to any charge-discharge cycle to have the accessible surface of the iron material in the same oxidation state as discharged iron negative electrode active material.

4 . The electrode of claim 3 , wherein the oxidation state of the oxidized iron active material is +2, +2/+3, +3 or +4.

5 . The electrode of claim 1 , wherein the electrode further comprises a polyvinyl alcohol binder.

6 . The electrode of claim 5 , wherein the electrode further comprises sulfur.

7 . The electrode of claim 1 , wherein the electrode further comprises a conductive additive.

8 . The electrode s of claim 7 , wherein the conductive additive comprises nickel, or copper or carbon black.

9 . The electrode of claim 1 , wherein the electrode comprises about:
50-90 wt % iron powder 5-30 wt % nickel powder 0.5-5.0 w % binder, and 0.25-20 w % sulfur.

10 . The electrode of claim 1 , wherein the electrode comprise a single layer of conductive substrate coated on at least one side with a coating comprising the iron active material.

11 . The electrode of claim 10 , wherein the substrate is comprised of nickel plated steel.

12 . The electrode of claim 1 , wherein the porosity of the electrode is in the range of about 15-50%.

13 . The electrode of claim 1 , wherein the treatment of the surface of the electrode comprises coating, dipping, spraying or brushing the water on the electrode.

14 . The electrode of claim 13 , wherein the water is brushed on the surface of the electrode.

15 . The electrode of claim 13 , wherein the water is sprayed on the surface of the electrode.

16 . The electrode of claim 13 , wherein the electrode is dipped in water.

Assignees

• Encell Technology Inc

Inventors

• Ogg Randy Gene
• Roders Michael
• Meese Michael

Classifications

• H01M4/661

  Metal or alloys, e.g. alloy coatings (H01M4/669 take precedence) · CPC title

• H01M4/248

  Iron electrodes · CPC title

• C23C8/18 Primary

  Oxidising of ferrous surfaces · CPC title

• H01M4/0492

  Chemical attack of the support material · CPC title

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title