Process for the preparation of glycols

Patent metadata

Field	Value
Publication number	US-2018362425-A1
Application number	US-201616060262-A
Country	US
Kind code	A1
Filing date	Dec 7, 2016
Priority date	Dec 9, 2015
Publication date	Dec 20, 2018
Grant date	—

Abstract

The invention provides a continuous process for the preparation of ethylene glycol and 1,2-propylene glycol from starting material comprising one or more saccharides, said process comprising providing a feedstock comprising said one or more saccharides in a solvent to a reactor, said reactor having supported therein a heterogeneous hydrogenation catalytic composition and contacting the feedstock therein directly with said heterogeneous hydrogenation catalytic composition and concurrently with a retro-aldol catalyst composition in the presence of hydrogen, wherein said reactor operates in an essentially plug flow manner.

First claim

1 . A continuous process for the preparation of ethylene glycol and 1,2-propylene glycol from starting material comprising one or more saccharides, said process comprising providing a feedstock comprising said one or more saccharides in a solvent to a reactor, said reactor having supported therein a heterogeneous hydrogenation catalytic composition and contacting the feedstock therein directly with said heterogeneous hydrogenation catalytic composition and concurrently with a retro-aldol catalyst composition in the presence of hydrogen, wherein said reactor operates in an essentially plug flow manner.

2 . The process as claimed in claim 1 , wherein the starting material supplied to the first reactor comprises starch and/or hydrolysed starch.

3 . The process as claimed in claim 1 , wherein the solvent is water or a C 1 to C 6 alcohol or polyalcohol including sugar alcohols or mixtures thereof.

4 . The process as claimed in claim 1 , wherein the heterogeneous hydrogenation catalytic composition comprises one or more materials selected from transition metals from groups 8, 9 or 10 or compounds thereof, with catalytic hydrogenation capabilities.

5 . The process as claimed in claim 1 , wherein the retro-aldol catalyst composition comprises one or more compound, complex or elemental material comprising tungsten, molybdenum, vanadium, niobium, chromium, titanium or zirconium.

6 . The process as claimed in claim 1 , wherein the retro-aldol catalyst composition is homogeneous with respect to the reaction mixture.

7 . The process as claimed in claim 1 , wherein the weight ratio of the retro-aldol catalyst composition, based on the amount of metal in said composition, to sugar feed is suitably in the range of from 1:1 to 1:1000.

8 . The process as claimed in claim 1 , wherein the weight ratio of the hydrogenation catalyst composition, based on the amount of metal in said composition, to sugar feed is suitably in the range of from 10:1 to 1:100.

9 . The process as claimed in claim 1 , wherein the first reactor is selected from the group consisting of tubular reactors, pipe reactors, falling film reactors, staged reactors, packed bed reactors, trickle bed reactors and shell and tube type heat exchangers.

10 . The process as claimed in claim 1 , wherein the temperature in the reactor is at least 170° C. and at most 250° C. and the pressure in the reactor is suitably at least 1 MPa and at most 8 MPa.

Assignees

• Shell Oil Co

Inventors

• Van Der Heide Evert
• Nisbet Timothy Michael
• Chewter Leslie Andrew
• Huizenga Pieter

Classifications

• B01J21/063

  Titanium; Oxides or hydroxides thereof · CPC title

• C07C29/132 Primary

  by reduction of an oxygen containing functional group · CPC title

• C07C31/205

  1,3-Propanediol; 1,2-Propanediol · CPC title

• B01J23/26

  Chromium · CPC title

• B01J2219/00033

  Continuous processes · CPC title