High-strength and high-conductivity copper alloy and applications of alloy as material of contact line of high-speed railway allowing speed higher than 400 kilometers per hour

Patent metadata

Field	Value
Publication number	US-2018355458-A1
Application number	US-201715777328-A
Country	US
Kind code	A1
Filing date	May 15, 2017
Priority date	May 16, 2016
Publication date	Dec 13, 2018
Grant date	—

Abstract

A high-strength and high-conductivity copper alloy and applications of the alloy as a material of a contact line of a high-speed railway allowing a speed higher than 400 kilometers per hour. The copper alloy has the following characteristics: (1) constituents of the copper alloy are in the form of CuXY, X is one or more selected from Ag, Nb and Ta, and Y is one of more selected from Cr, Zr and Si; (2) at a room temperature, the element X in the copper alloy exists in the form of a pure phase and solid solution atoms, the element Y exists in the form of a pure phase and solid solution atoms or a CuY compound and solid solution atoms, the content of the element X existing in the form of the solid solution atoms is lower than 0.5%, and the content of the element Y existing in the form of the solid solution atoms is lower than 0.1%; and (3) the copper alloy exists in the form of long strip rods or lines, the element X in the form of the pure phase is embedded in the copper alloy in the form of fibers disposed in parallel approximately, and the axial direction of the fibers is approximately in parallel with the axial direction of the copper alloy rods or lines; and the element Y existing in the copper alloy in the form of the pure phase or the CuY compound is embedded in the copper alloy in the form of particles. The copper alloy is suitable for being used as a material of a contact line of a high-speed railway allowing a speed higher than 400 kilometers per hour.

First claim

What is claimed is:

1 . A copper alloy, having the following features:
(1) The copper alloy composition conforms to the form: CuXY, of which X is selected from at least one of Ag, Nb and Ta, Y is from at least one of Cr, Zr and Si; in the copper alloy, the total content of X element shall be greater than 0.01% and no higher than 20%, the total content of Y element shall be greater than 0.01% and no higher than 2%, moreover, the Cr content ranges from 0.01% to 1.5%, Zr content ranges from 0.01% to 0.5%, and Si content ranges from 0.01% to 0.3%; (2) At room temperature, X element in the copper alloy exists in the forms of pure phase and solid solution atom, of which the X content in the latter form is less than 0.5%; Y element exists in the forms of pure phase and solid solution atom or CuY compound and solid solution atom, of which the Y content in the form of solid solution atom is less than 0.1%; (3) The copper alloy exists in the form of long bar or wire, of which X element in the form of pure phase is embedded in the copper alloy in the form of approximately parallel arranged fibers, the axial direction of the fiber is roughly parallel to that of the copper alloy bar or wire, and the diameter of the fiber is less than 100 nm, its length is greater than 1000 nm and the distance between fibers is less than 1000 nm, the phase interface between fiber and Cu matrix is a semi-coherent interface, on which periodically arranged misfit dislocation is distributed; Y element in the form of pure phase or compound is embedded in the copper alloy in the form of particles, and over 30% particles are distributed on the phase interface between X fiber and Cu matrix, the diameter of particles is less than 30 nm, the distance between particles is less than 200 nm, and the phase interface between particle and Cu matrix and between particle and X fiber is semi-coherent interface or incoherent interface.

2 . The copper alloy according to claim 1 , wherein the total content of X element in the copper alloy is 3%˜12%.

3 . The copper alloy according to claim 1 , wherein the total content of Y element in the copper alloy is 0.1%˜1.5%.

4 . The copper alloy according to claim 1 , wherein the copper alloy is one of the following: Cu-12% Ag-0.3% Cr-0.1% Zr-0.05% Si, Cu-12% Ag-12% Nb-1.3% Cr-0.4% Zr-0.3% Si, Cu-0.1% Ag-0.1% Cr-0.1% Zr, Cu-12% Nb-1% Cr-0.4% Zr-0.1% Si, Cu-6% Ag-6% Ta-0.1% Cr, Cu-3% Ag-0.8% Cr-0.5% Zr-0.3% Si.

5 . The copper alloy according to claim 1 , wherein the strength of the copper alloy reaches over 690 MPa, its conductivity reaches over 79% and the strength reduction rate <10% after annealing at 400° C. for 2 h.

6 . The copper alloy according to claim 1 , wherein the copper alloy is prepared through the following method: put the simple substance and/or intermediate alloy raw materials into the vacuum melting furnace according to the designed alloy composition proportion, increase the temperature, melt and cast in the mould to obtain ingot casting, transform the ingot casting into long bar or wire after multi-pass drawing at room temperature, to make the cross section shrinking ratio of the sample reach over 80%, then anneal the long bar or wire at a temperature without spheroidizing fracture of fibers of X elementary composition and with making Y element form nano-sized precipitated phase, and the annealing time shall be selected without spheroidizing fracture of fibers of X elementary composition and with making Y element greater than 50% form nano-sized precipitated phase, and draw the obtained alloy again, during which the cross section shrinking ratio of the sample is less than 50%, then freeze the obtained alloy with liquid nitrogen, so that the residual X or Y solid solution atom in the copper matrix continue to separate out, then slowly increase the temperature to room temperature to obtain copper alloy.

7 . The copper alloy according to claim 6 , wherein the duration for liquid nitrogen freezing treatment is 1˜100 hour(s).

8 . The copper alloy according to claim 6 , wherein the temperature is increased to room temperature at a rate of 2˜10° C./min after liquid nitrogen freezing treatment of the alloy.

9 . Applications of copper alloy as the contact wire materials of high speed railways according to claim 1 .

10 . The applications according to claim 9 , wherein the speed of the high speed railways is over 400 km per hour.

11 . The copper alloy according to claim 7 , wherein the temperature is increased to room temperature at a rate of 2˜10° C./min after liquid nitrogen freezing treatment of the alloy.

Assignees

• Univ Zhejiang

Inventors

• Liu Jiabin
• Xu Yuqing
• Wang Hongtao
• Fang Youtong
• Meng Liang
• Wang Litian
• Tian Yu

Classifications

• C22C9/00 Primary

  Alloys based on copper · CPC title

• C22F1/08

  of copper or alloys based thereon · CPC title

• C22C1/03

  using master alloys · CPC title

• H01B1/026

  Alloys based on copper · CPC title

• C22C1/02

  by melting {(C22C1/1036 takes precedence)} · CPC title