Hfo-1234ze, hfo-1225zc and hfo-1234yf containing compositions and processes for producing and using the compositions
US-2024352296-A1 · Oct 24, 2024 · US
US2018354875A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2018354875-A1 |
| Application number | US-201816102320-A |
| Country | US |
| Kind code | A1 |
| Filing date | Aug 13, 2018 |
| Priority date | Mar 20, 2013 |
| Publication date | Dec 13, 2018 |
| Grant date | — |
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An azeotropic or quasi-azeotropic composition including hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene and optionally one or more (hydro)halogen-carbon compounds including between 1 and 3 carbon atoms. Also, a preferred azeotropic or quasi-azeotropic composition including hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene, and optionally one or more compounds selected from among 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro,1,1,1,2-tetrafluoropropane.
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1 - 14 . (canceled) 15 . An azeotropic or quasi-azeotropic composition consisting essentially of hydrogen fluoride and E-3,3,3-trifluoro-1-chloropropene. 16 . The composition as claimed in claim 15 , wherein the composition is azeotropic. 17 . The composition as claimed in claim 15 , wherein the composition is quasi-azeotropic, wherein the pressure difference between the pressure at the dew point and the pressure at the bubble formation point is less than or equal to 5%, on the basis of the pressure at the bubble formation point. 18 . The composition as claimed in claim 15 , wherein the composition has from 5% to 70% by weight of hydrogen fluoride and from 95% to 30% by weight of E-3,3,3-trifluoro-1-chloropropene, the boiling point of this composition is between 0 and 40° C. at a pressure of between 0.9 and 4 bar absolute. 19 . The composition as claimed in claim 15 , wherein the composition has from 10% to 65% by weight of hydrogen fluoride and from 90% to 35% by weight of E-3,3,3-trifluoro-1-chloropropene, the boiling point of this composition is between 0 and 40° C. at a pressure of between 0.9 and 4 bar absolute. 20 . The composition as claimed in claim 15 , wherein the composition consists of hydrogen fluoride and E-3,3,3-trifluoro-1-chloropropene. 21 . The composition as claimed in claim 20 , wherein the composition is azeotropic. 22 . The composition as claimed in claim 20 , wherein the composition is quasi-azeotropic, wherein the pressure difference between the pressure at the dew point and the pressure at the bubble formation point is less than or equal to 5%, on the basis of the pressure at the bubble formation point. 23 . The composition as claimed in claim 20 , wherein the composition has from 5% to 70% by weight of hydrogen fluoride and from 95% to 30% by weight of E-3,3,3-trifluoro-1-chloropropene, the boiling point of this composition is between 0 and 40° C. at a pressure of between 0.9 and 4 bar absolute. 24 . The composition as claimed in claim 20 , wherein the composition has from 10% to 65% by weight of hydrogen fluoride and from 90% to 35% by weight of E-3,3,3-trifluoro-1-chloropropene, the boiling point of this composition is between 0 and 40° C. at a pressure of between 0.9 and 4 bar absolute.
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