Waterborne coating for synthetic paper

Patent metadata

Field	Value
Publication number	US-2018346752-A1
Application number	US-201815990874-A
Country	US
Kind code	A1
Filing date	May 29, 2018
Priority date	May 31, 2017
Publication date	Dec 6, 2018
Grant date	—

Abstract

A waterborne coating consists in an ink-absorbing spheres emulsion containing acrylate micro-sphere formed with a hollow chamber, an inorganic ink-absorbing material worked with the ink-absorbing spheres emulsion together for use in absorbing ink, a waterborne acrylate emulsion containing a low-Tg acrylate monomer liquid to fix the inorganic ink-absorbing material, and a waterborne crosslinker having two or more reactive functional groups to bridge with carboxyl monomers; and particularly the waterborne coating is coated onto synthetic paper as a surface coating to endow the synthetic paper with good printability, coating adhesion, water resistance, scrape resistance and solvent resistance.

First claim

What is claimed is:

1 . A waterborne coating for synthetic paper, based on a total weight of the coating, composed of components below summing up 100 wt %:
(1) an ink-absorbing sphere emulsion taking up 2-7 wt %; (2) a waterborne acrylate emulsion taking up 26-70 wt %; (3) an inorganic ink-absorbing material taking up 26-70 wt %; (4) a waterborne crosslinker taking up 0.5-3 wt %; wherein the waterborne acrylate emulsion (2) is primarily emulsion-polymerized from the following monomers (a)-(d) summing up 100 wt %: (a) a low-Tg acrylate monomer taking up 45-70 wt %, being one or more selected from the group consisting of ethyl acrylate, n-propyl acrylate, n-butyl acrylate, isobutyl acrylate and isooctyl acrylate; (b) a hydrophobic alkyl methacrylate monomer taking up 0.1-10 wt %; (c) a hydrophobic styrene-based monomer taking up 10-45 wt %; (d) a carboxyl-containing vinyl monomer taking up 1-20 wt %.

2 . The waterborne coating for synthetic paper as defined in claim 1 , wherein the component (2) of ink-absorbing sphere emulsion is produced by the following steps:
A) taking a weight ratio of a methacrylic acid (MAA) monomer to a methyl methacrylate (MMA) monomer is 1:2, adding therein a butyl acrylate (BA) as an acrylate-acid monomer with a use amount equal to 6-8 times by weight of the methyl methacrylate monomer, adding therein sodium lauryl sulfate as an anionic emulsifier with a use amount not exceeding 0.005 time by weight of the BA monomer, and performing emulsion polymerization to obtain an Emulsion A; B) taking the Emulsion A, a MAA monomer with a use amount of 1-5 times by weight of the Emulsion A, and an acrylate-based monomer with a use amount of 1-4 times by weight of the Emulsion A, and adding ethylene glycol dimethacrylate in a use amount of 0.1-2 mol % of the total amount of the monomers, to perform an emulsion polymerization to obtain Emulsion B; wherein the acrylate-based monomer is one or more selected from the group consisting of methyl acrylate monomer, methyl methacrylate monomer, ethyl acrylate monomer, butyl acrylate monomer and 2-ethylhexyl acrylate monomer; and C) taking the Emulsion B and a styrene (SM) monomer with a use amount of 0.5-1.5 times of Emulsion B for emulsion polymerization, and adding ammonia, to obtain an ink-absorbing sphere emulsion containing the Emulsion B up to 8.0-9.8% of the total solids content thereof.

3 . The waterborne coating for synthetic paper as defined in claim 1 , wherein the component (2) of the ink-absorbing sphere emulsion is a kind of acrylate micro-sphere having a particle size of 500-1100 nm.

4 . The waterborne coating for synthetic paper as defined in claim 1 , wherein the component (3) of the inorganic ink-absorbing material has a particle size of 1.2-5 μm and is one or more selected from the group consisting of calcium carbonate, titanium dioxide, diatomaceous earth, white clay, calcium oxide, silicon dioxide and barium sulfate.

5 . The waterborne coating for synthetic paper as defined in claim 1 , wherein the component (4) of the waterborne crosslinker has two or more reactive functional groups to bridge with carboxyl monomers and is one or more selected from the group consisting of isocyanate-containing crosslinker, epoxy-containing crosslinker and aziridine-containing crosslinker.

6 . The waterborne coating for synthetic paper as defined in claim 1 , wherein the hydrophobic alkyl methacrylate monomer is one or more selected from the group consisting of methyl methacrylate (MMA), ethyl acrylate (EA), propyl acrylate (PA), butyl acrylate (BA), isobutyl acrylate (IBA), amyl (meth)acrylate, hexyl methacrylate, heptyl methacrylate, 2-ethylhexylacrylate (2-HEA), n-octyl methacrylate, iso-octyl methacrylate (IOA), nonyl methacrylate (NA), sunflower methacrylate, lauryl (meth)acrylate (LA), octadecyl methacrylate, methoxyethyl (meth)acrylate (MOEA), n-butyl methacrylate (n-BMA), 2-ethylhexyl acrylate (2-EHA) and ethoxymethyl (meth)acrylates (EOMAA).

7 . The waterborne coating for synthetic paper as defined in claim 1 , wherein the hydrophobic styrene-based monomer is one or more selected from the group consisting of styrene monomer (SM), methylstyrene monomer (MSM) and vinyl toluene monomer.

8 . The waterborne coating for synthetic paper as defined in claim 1 , wherein the carboxyl-containing vinyl monomer is one or more selected from the group consisting of acrylic acid (AA), methacrylic acid (MAA), maleic anhydride (MA), fumaric acid (FA), itaconic acid (IA), butenoic acid (BA) and maleic anhydride (MAH).

Assignees

• Nanya Plastics Corp

Inventors

• Liao Te-Chao
• Hsu Sen-Huang
• Huang Chih-Hao

Classifications

• C08F220/1804

  C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate · CPC title

• C09D133/02 Primary

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• C09D133/10 Primary

  Homopolymers or copolymers of methacrylic acid esters · CPC title

• C09D7/69

  Particle size larger than 1000 nm · CPC title

• D21H21/14

  characterised by function or properties in or on the paper (D21H19/66, D21H27/02 take precedence) · CPC title