Non-aqueous compositions of polymers derived from monomers having acryloyl moiety and lactam moiety and applications thereof

Patent metadata

Field	Value
Publication number	US-2018333345-A1
Application number	US-201615777785-A
Country	US
Kind code	A1
Filing date	Nov 17, 2016
Priority date	Nov 20, 2015
Publication date	Nov 22, 2018
Grant date	—

Abstract

The invention provides non-aqueous compositions comprising film forming polymers comprising repeating units derived from: (a) at least one monomer comprising at least one functionalized or unfunctionalized acryloyl moiety and at least one lactam moiety; (b) at least one monomer selected from the group consisting of functionalized and unfunctionalized C 1 -C 7 alkyl (alk)acrylates, C 1 -C 7 alkyl (alk)acrylamides, and combinations thereof; and (c) at least one monomer selected from the group consisting of functionalized and unfunctionalized C 8 -C 60 alkyl (alk)acrylates, C 8 -C 60 (alk)alkyl acrylamides, and combinations thereof. The invention further provides applications of these compositions in various industrial arts, particularly in personal care. The invention furthermore provides water-resistant non-aqueous personal care compositions. Variables a, b and c are described herein. (Formula (I))

First claim

What is claimed is:

1 . A non-aqueous composition comprising a film forming polymer comprising repeating units derived from:
(a) at least one monomer comprising at least one functionalized or unfunctionalized acryloyl moiety and at least one lactam moiety; (b) at least one monomer selected from the group consisting of functionalized and unfunctionalized C 1 -C 7 alkyl (alk)acrylates, C 1 -C 7 alkyl (alk)acrylamides, and combinations thereof; and (c) at least one monomer selected from the group consisting of functionalized and unfunctionalized C 8 -C 60 alkyl (alk)acrylates, C 8 -C 60 alkyl (alk)acrylamides, and combinations thereof.

2 . The non-aqueous composition according to claim 1 wherein said monomer having at least one functionalized or unfunctionalized acryloyl moiety and at least one lactam moiety has the structure:

wherein each R 1 R 2 and R 3 is independently selected from the group consisting of hydrogen, halogens, functionalized and unfunctionalized C 1 -C 4 alkyl, and

each X is independently selected from the group consisting of OR 4 , OM, halogen, N(R 5 )(R 6 ),

and combinations thereof;
each Y is independently oxygen, NR 7 or sulfur;
each R 4 , R 5 , R 6 and R 7 is independently selected from the group consisting of hydrogen and functionalized and unfunctionalized alkyl;
each M is independently selected from the group consisting of metal ions, ammonium ions, organic ammonium cations, and combinations thereof; and
each Q 1 , Q 2 , Q 3 , and Q 4 is independently selected from the group consisting of functionalized and unfunctionalized alkylene.

3 . The non-aqueous composition according to claim 2 wherein each said Q 1 , Q 2 , Q 3 , and Q 4 is independently selected from the group consisting of functionalized and unfunctionalized C 1 -C 12 alkylene.

4 . The non-aqueous composition according to claim 2 wherein each said R 1 , R 2 and R 3 is independently selected from the group consisting of hydrogen, methyl and combinations thereof.

5 . The non-aqueous composition according to claim 2 wherein each said R 1 and R 3 is independently hydrogen or methyl; said R 2 is

X is selected from the group consisting of OR 4 , OM, halogens, and N(R 5 )(R 6 ); each R 4 , R 5 , and R 6 is independently selected from the group consisting of hydrogen and functionalized and unfunctionalized alkyl; and each M is independently selected from the group consisting of metal ions, ammonium ions, organic ammonium cations, and combinations thereof.

6 . The non-aqueous composition according to claim 2 wherein said monomer having at least one functionalized or unfunctionalized acryloyl moiety and at least one lactam moiety has a structure selected from the group consisting of:

7 . The non-aqueous composition according to claim 1 wherein said C 1 -C 7 alkyl (alk)acrylate is selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, iso-butyl acrylate, sec-butyl acrylate, tert-butyl acrylate, n-pentyl acrylate, iso-amyl acrylate, n-hexyl acrylate, n-heptyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, iso-butyl methacrylate, sec-butyl methacrylate, tert-butyl methacrylate, n-pentyl methacrylate, iso-amyl methacrylate, n-hexyl methacrylate, n-heptyl methacrylate, and combinations thereof.

8 . The non-aqueous composition according to claim 1 wherein said C 1 -C 7 alkyl (alk)acrylamide is selected from the group consisting of methyl acrylamide, ethyl acrylamide, propyl acrylamide, iso-butyl acrylamide, sec-butyl acrylamide, tert-butyl acrylamide, n-pentyl acrylamide, iso-amyl acrylamide, n-hexyl acrylamide, n-heptyl acrylamide, methyl methacrylamide, ethyl methacrylamide, propyl methacrylamide, iso-butyl methacrylamide, sec-butyl methacrylamide, tert-butyl methacrylamide, n-pentyl methacrylamide, iso-amyl methacrylamide, n-hexyl methacrylamide, n-heptyl methacrylamide, and combinations thereof.

9 . The non-aqueous composition according to claim 1 wherein said C 8 -C 60 alkyl (alk)acrylate is an (alk)acrylate comprising a branched C 8 -C 30 alkyl moiety.

10 . The non-aqueous composition according to claim 9 wherein said (alk)acrylate comprising a branched C 8 -C 30 alkyl moiety is selected from the group consisting of 2-ethylhexyl acrylate, 1,1,3,3-tetramethylbutyl acrylate, 1,1-dimethylhexyl acrylate, 6-methylheptyl acrylate, 7-methyloctyl acrylate, 2-propylheptyl acrylate, 8-methylnonyl acrylate, 9-methyldecyl acrylate, 10-methylundecyl acrylate, 11-methyldodecyl acrylate, 12-methyltridecyl acrylate, 13-methyltetradecyl acrylate, 14-methylpentadecyl acrylate, 15-methylhexadecyl acrylate, 16-methylheptadecyl acrylate, 17-methyloctadecyl acrylate, 2-ethylhexyl methacrylate, 1,1,3,3-tetramethylbutyl methacrylate, 1,1-dimethylhexyl methacrylate, 6-methylheptyl methacrylate, 7-methyloctyl methacrylate, 2-propylheptyl methacrylate, 8-methylnonyl methacrylate, 9-methyldecyl methacrylate, 10-methylundecyl methacrylate, 11-methyldodecyl methacrylate, 12-methyltridecyl methacrylate, 13-methyltetradecyl methacrylate, 14-methylpentadecyl methacrylate, 15-methylhexadecyl methacrylate, 16-methylheptadecyl methacrylate, 17-methyloctadecyl methacrylate, and combinations thereof.

11 . The non-aqueous composition according to claim 1 wherein said C 8 -C 60 alkyl (alk)acrylamide is an (alk)acrylamide comprising a branched C 8 -C 30 alkyl moiety.

12 . The non-aqueous composition according to claim 11 wherein said (alk)acrylamide comprising a branched C 8 -C 30 alkyl moiety is selected from the group consisting of N-2-ethylhexyl acrylamide, N-1,1,3,3-tetramethylbutyl acrylamide, N-1,1-dimethylhexyl acrylamide, N-6-methylheptyl acrylamide, N-7-methyloctyl acrylamide, N-2-propylheptyl acrylamide, N-8-methylnonyl acrylamide, N-9-methyldecyl acrylamide, N-10-methylundecyl acrylamide, N-11-methyldodecyl acrylamide, N-12-methyltridecyl acrylamide, N-13-methyltetradecyl acrylamide, N-14-methylpentadecyl acrylamide, N-15-methylhexadecyl acrylamide, N-16-methylheptadecyl acrylamide, N-17-methyloctadecyl acrylamide, N-2-ethylhexyl methacrylamide, N-1,1,3,3-tetramethylbutyl methacrylamide, N-1,1-dimethylhexyl methacrylamide, N-6-methylheptyl methacrylamide, N-7-methyloctyl methacrylamide, N-2-propylheptyl methacrylamide, N-8-methylnonyl methacrylamide, N-9-methyldecyl methacrylamide, N-10-methylundecyl methacrylamide, N-11-methyldodecyl methacrylamide, N-12-methyltridecyl methacrylamide, N-13-methyltetradecyl methacrylamide, N-14-methylpentadecyl methacrylamide, N-15-methylhexadecyl methacrylamide, N-16-methylheptadecyl methacrylamide, N-17-methyloctadecyl methacrylamide

Assignees

• Isp Investments Llc

Inventors

• Tallon Michael A
• Prettypaul Donald I
• Patel Drupesh
• Ghosh Mousumi
• Musa Osama M

Classifications

• A61K8/8182

  Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers · CPC title

• A61K2800/31

  Anhydrous · CPC title

• A61Q17/04

  Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations · CPC title

• C08F222/38

  Amides · CPC title

• C08F222/22

  Esters containing nitrogen · CPC title