Device for producing poly(meth)acrylate in powder form

Patent metadata

Field	Value
Publication number	US-2018326392-A1
Application number	US-201615774620-A
Country	US
Kind code	A1
Filing date	Nov 16, 2016
Priority date	Nov 17, 2015
Publication date	Nov 15, 2018
Grant date	—

Abstract

The invention relates to an apparatus for producing pulverulent poly(meth)acrylate, comprising a reactor for droplet polymerization having an apparatus for dropletization of a monomer solution for the preparation of the poly(meth)acrylate having holes through which the monomer solution is introduced, an addition point for a gas above the apparatus for dropletization, at least one gas withdrawal point on the circumference of the reactor and a fluidized bed, the reactor comprising a reactor shell between the apparatus for dropletization and the gas withdrawal point and having, above the fluidized bed, a region having decreasing hydraulic diameter toward the fluidized bed and having a maximum hydraulic diameter greater than the mean hydraulic diameter of the reactor shell, and the reactor shell projecting into the region having decreasing hydraulic diameter, so as to form an annular duct between the outer wall of the reactor shell and the wall by which the region having decreasing hydraulic diameter is bounded, and the at least one gas withdrawal point being disposed in the annular duct, wherein the ratio of the horizontal area of the annular duct to the horizontal area enclosed by the reactor shell is in the range from 0.3 to 5.

First claim

1 .- 10 . (canceled)

11 . An apparatus for producing pulverulent poly(meth)acrylate, comprising a reactor ( 1 ) for droplet polymerization having an apparatus ( 5 ) for dropletization of a monomer solution for the preparation of the poly(meth)acrylate having holes through which the monomer solution is introduced, an addition point ( 13 ) for a gas above the apparatus ( 5 ) for dropletization, at least one gas withdrawal point ( 19 ) on the circumference of the reactor ( 1 ) and a fluidized bed ( 11 ), the reactor ( 1 ) comprising a reactor shell ( 35 ) between the apparatus for dropletization ( 5 ) and the gas withdrawal point ( 19 ) and having, above the fluidized bed ( 11 ), a region ( 9 ) having decreasing hydraulic diameter toward the fluidized bed and having a maximum hydraulic diameter greater than the mean hydraulic diameter of the reactor shell ( 35 ), and the reactor shell ( 35 ) projecting into the region ( 9 ) having decreasing hydraulic diameter, so as to form an annular duct ( 21 ) between the outer wall of the reactor shell ( 35 ) and the wall by which the region ( 9 ) having decreasing hydraulic diameter is bounded, and the at least one gas withdrawal point ( 19 ) being disposed in the annular duct ( 21 ), wherein the ratio of the horizontal area ( 39 ) of the annular duct ( 21 ) to the horizontal area ( 41 ) enclosed by the reactor shell ( 35 ) is in the range from 0.3 to 5.

12 . The apparatus according to claim 11 , wherein the ratio of the distance ( 43 ) between the outer wall of the reactor shell ( 35 ) and the wall of the region ( 9 ) having decreasing hydraulic diameter at the inlet into the annular duct ( 21 ) and the height ( 45 ) of the annular duct ( 21 ) between the inlet into the annular duct ( 21 ) and the lower edge of the gas withdrawal point ( 19 ) is in the range from 0.05 to 50.

13 . The apparatus according to claim 11 , wherein each gas withdrawal point ( 19 ) is connected to an apparatus for removal of solids ( 27 ).

14 . The apparatus according to claim 13 , wherein the apparatus for removal of solids ( 27 ) is a cyclone.

15 . The apparatus according to claim 11 , wherein at least two gas withdrawal points ( 19 ) are connected to one apparatus for removal of solids ( 27 ).

16 . The apparatus according to claim 15 , wherein the apparatus for removal of solids ( 27 ) is a cyclone.

17 . The apparatus according to claim 11 , wherein at least two gas withdrawal points ( 19 ) are provided and the gas withdrawal points ( 19 ) are arranged uniformly over the circumference of the annular duct ( 21 ).

18 . The apparatus according to claim 11 , wherein the ratio of the horizontal cross-sectional area ( 39 ) of the annular duct ( 21 ) to the total cross-sectional area of all gas withdrawal points ( 19 ) is in the range from 1.5 to 150.

19 . The apparatus according to claim 11 , wherein the lower end of the reactor shell ( 35 ) has a region having an increase in diameter, the region having the increase in diameter being completely within the region which forms the annular duct ( 21 ).

20 . The apparatus according to claim 19 , wherein the increase in diameter at the lower end of the reactor shell ( 35 ) is conical and has an opening angle in the range from 0 to 10°.

21 . The apparatus according to claim 11 , wherein the top of the region ( 9 ) having decreasing hydraulic diameter is connected to a region having constant hydraulic diameter ( 37 ) such that the outer wall of the annular duct ( 21 ) has a constant hydraulic diameter.

Assignees

• Basf Se

Inventors

• Krüger Marco
• Possemiers Karl
• Schliwa Rudolf
• Bayer Robert

Classifications

• C08F120/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• B01J2208/00761

  Discharging · CPC title

• B01J8/0055

  using cyclones · CPC title

• B01J19/245 Primary

  placed in series · CPC title

• B01J2219/185

  vertical · CPC title