Method of refining of scandium oxide from concentrates using solvent extraction

Patent metadata

Field	Value
Publication number	US-2018320249-A1
Application number	US-201816031798-A
Country	US
Kind code	A1
Filing date	Jul 10, 2018
Priority date	Feb 11, 2016
Publication date	Nov 8, 2018
Grant date	—

Abstract

A method of selectively removing impurities from a scandium-containing feed solution includes contacting an aqueous scandium-containing solution with an organic solvent stream containing an extractant, thereby forming a loaded organic solvent stream containing the impurity or impurities while leaving the scandium in the raffinate. The aqueous stream containing the scandium is washed, diluted and has inorganic salts added before being contacted with a second organic solvent stream to extract the scandium selectively, and followed by stripping the scandium from the scandium-containing loaded organic extractant stream by adding oxalic acid to the loaded organic extractant stream to form scandium oxalate.

First claim

1 . A method of selectively removing scandium from an aqueous scandium-containing feed solution, comprising:
selectively removing zirconium from the aqueous scandium-containing solution by contacting the aqueous scandium-containing solution with a first organic solvent stream comprising a first extractant, the first extractant comprising an amine compound; and selectively removing scandium from the aqueous scandium-containing solution after the step of selectively removing zirconium by contacting the aqueous scandium-containing solution with a second organic solvent stream comprising a second extractant to form a scandium-containing loaded organic solvent stream, the second extractant comprising an organo-phosphorous compound; and stripping the scandium from the scandium-containing loaded organic extractant stream by forming scandium oxalate.

2 . The method of claim 1 , wherein the first organic solvent stream comprises at least one of a first modifier and a first diluent and the second organic solvent stream comprises at least one of a second modifier and a second diluent.

3 . The method of claim 2 , wherein the first modifier comprises an alcohol comprising a C8-C15 carbon chain, the first and second diluent comprises kerosene or a dearomatized hydrocarbon fluid.

4 . The method of claim 3 , wherein the first modifier comprises a tridecyl alcohol and the second modifier comprises tributyl phosphate.

5 . The method of claim 1 , wherein stripping the scandium comprises adding oxalic acid to the scandium containing loaded organic extractant stream to form scandium oxalate.

6 . The method of claim 5 , further comprising washing and filtering the scandium oxalate and calcining the scandium oxalate to form scandium oxide.

7 . The method of claim 1 , further comprising stripping the zirconium from the first organic solvent with an aqueous HCl solution.

8 . The method of claim 7 , further comprising reactivating the amine compound by treating the amine compound with an alkaline solution.

9 . The method of claim 1 , further comprising selectively removing titanium from the scandium-containing loaded organic extractant stream after stripping the scandium.

10 . The method of claim 1 , further comprising diluting the aqueous scandium-containing solution prior to selectively removing the scandium.

11 . The method of claim 5 , wherein the second extractant comprises bis(2,4,4-trimethylpentyl) phosphinic acid.

12 . The method of claim 11 , wherein the first extractant comprises a straight chain ternary amine with C8-C10 in an alkyl group.

13 . A method of selectively removing a metal from an aqueous feed solution, comprising:
selectively removing zirconium from the aqueous feed solution using a first organic solvent; and stripping the zirconium from the first organic solvent with an aqueous HCl solution.

14 . The method of claim 13 , wherein selectively removing zirconium from the aqueous feed solution comprises contacting the aqueous feed solution with a first organic solvent stream comprising a first extractant, the first extractant comprising an amine compound.

15 . The method of claim 14 , further comprising after selectively removing zirconium:
selectively removing scandium and titanium from the aqueous feed solution by reacting the aqueous feed solution with a second organic solvent stream comprising a second extractant to form a scandium and titanium-containing loaded organic solvent stream; and stripping the scandium from the scandium and titanium-containing loaded organic extractant stream by forming scandium oxalate.

16 . The method of claim 15 , further comprising prior to selectively removing zirconium, removing titanium from the aqueous feed solution using cross current extraction.

Assignees

• Bloom Energy Corp

Inventors

• Liao Lunzhi
• Hartley Christopher Jeffrey
• Mcallister Justin
• Sarmiento Andrew

Classifications

• C22B34/14

  Obtaining zirconium or hafnium {(treatment or purification of solutions by liquid-liquid extraction, by ion exchange or by adsorption C22B3/00, C01G25/003, C01G27/003)} · CPC title

• C07C51/412

  by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part · CPC title

• C07C55/07

  Salts thereof · CPC title

• C22B59/00 Primary

  Obtaining rare earth metals · CPC title

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title