Resin composition and molded body of same

Patent metadata

Field	Value
Publication number	US-2018312677-A1
Application number	US-201615772177-A
Country	US
Kind code	A1
Filing date	Oct 24, 2016
Priority date	Nov 6, 2015
Publication date	Nov 1, 2018
Grant date	—

Abstract

A resin composition containing (a) an olefinic polymer (A) having a melting endotherm (ΔH-D) of 0 J/g or more and 80 J/g or less and a molecular weight distribution (Mw/Mn) of less than 3.0, (b) an olefinic polymer (B) having a melting point (Tm-D) of 100° C. or higher, and (c) fibers (C) having an aspect ratio of 10 or more, and a mean fiber diameter of 0.01 μm or more and 1,000 μm or less.

First claim

1 : A resin composition, comprising:
(a) an olefinic polymer (A) having a melting endotherm (ΔH-D) of 0 J/g or more and 80 J/g or less, which is defined as the area of a peak observed on the highest temperature side in a melting endothermic curve obtained with a differential scanning calorimeter (DSC) by keeping a sample of the polymer in a nitrogen atmosphere at −10° C. for 5 minutes and then heating the sample at 10° C./min; and having a molecular weight distribution (Mw/Mn) of less than 3.0; (b) an olefinic polymer (B) having a melting point (Tm-D) of 100° C. or higher, which is defined as the peak top observed on the highest temperature side in a melting endothermic curve obtained with a differential scanning calorimeter (DSC) by keeping a sample of the polymer in a nitrogen atmosphere at −10° C. for 5 minutes and then heating the sample at 10° C./min and (c) fibers (C) having an aspect ratio of 10 or more and a mean fiber diameter of 0.01 μm or more and 1,000 μm or less.

2 : The resin composition according to claim 1 , wherein a content of the olefinic polymer (A) is 0.5% by mass or more and less than 50% by mass, relative to 100% by mass of a total content of the olefinic polymer (A) and the olefinic polymer (B).

3 : The resin composition according to claim 1 , wherein the olefinic polymer (A) is a propylenic polymer.

4 : The resin composition according to claim 1 , wherein the olefinic polymer (B) is a propylenic polymer.

5 : The resin composition according to claim 1 , wherein the olefinic polymer (A) is a propylenic polymer (a1) in which a propylene monomer accounts for 50 mol % or more of monomers constituting the polymer (a1).

6 : The resin composition according to claim 5 , wherein the propylenic polymer (a1) satisfies at least one of the following (i) and (ii):
(i) an ethylene structural unit is contained in an amount of more than 0 mol % and 20 mol % or less; and (ii) a 1-butene structural unit is contained in an amount of more than 0 mol % and 30 mol % or less.

7 : The resin composition according to claim 5 , wherein the propylenic polymer (a1) satisfies the following (1):
(1) the meso pentad fraction [mmmm] is 20 mol % or more and 60 mol % or less.

8 : The resin composition according to claim 5 , wherein the propylenic polymer (a1) satisfies the following (2):
(2) the melting point (Tm-D), which is defined as the peak top observed on the highest temperature side in a melting endothermic curve obtained with a differential scanning calorimeter (DSC) by keeping a sample of the polymer in a nitrogen atmosphere at −10° C. for 5 minutes and then heating the sample at 10° C./min, is 0° C. or higher and 120° C. or lower.

9 : The resin composition according to claim 7 , wherein the propylenic polymer (a1) satisfies the following (3):
(3) the value of [rrrr]/(1−[mmmm]) is 0.1 or less.

10 : The resin composition according to claim 7 , wherein the propylenic polymer (a1) satisfies the following (4) and (5):
(4) the racemic meso racemic meso pentad fraction [rmrm] is more than 2.5 mol %; and (5) the value of [mm]×[rr]/[mr] 2 is 2.0 or less.

11 : The resin composition according to claim 1 , wherein the fibers (C) are glass fibers.

12 : The resin composition according to claim 1 , wherein the fibers (C) are carbon fibers.

13 : The resin composition according to claim 1 , wherein the composition is adapted to function as a composition for injection molding.

14 : A molded article, which is formed of the resin composition of claim 1 .

15 : An injection-molded article, which is formed of the resin composition of claim 1 .

Assignees

• Idemitsu Kosan Co

Inventors

• Fujii Nozomu
• Kubo Masahiro

Classifications

• C08K2201/016

  Additives defined by their aspect ratio · CPC title

• C08J5/042

  with carbon fibres · CPC title

• C08F2800/10

  as molar percentages · CPC title

• C08J5/043

  with glass fibres · CPC title

• C08J2323/14

  Copolymers of propene (C08J2323/16 takes precedence) · CPC title