Electrical steel sheet and method for manufacturing same
US-12163066-B2 · Dec 10, 2024 · US
US2018304583A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2018304583-A1 |
| Application number | US-201615769917-A |
| Country | US |
| Kind code | A1 |
| Filing date | Oct 31, 2016 |
| Priority date | Oct 30, 2015 |
| Publication date | Oct 25, 2018 |
| Grant date | — |
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A component made of metallic composite material having high corrosion resistance and scale resistance. The metallic composite material contains as a core material an uncoated hardenable steel on which surface a corrosion resistance and scaling resistance layer is provided using heat resistant stainless steel, and has a yield strength Rp 0,2 of at least 1000 MPa and a tensile strength R m of at least 1500 MPa for the core material and a critical scaling resistance temperature in air for the layer material is at least 850° C.
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1 . A component made of a metallic composite material having high corrosion resistance and scale resistance, wherein the metallic composite material comprises as a core material an uncoated hardenable steel on which surface a corrosion resistance and scaling resistance layer is provided using heat resistant stainless steel, and has a yield strength Rp 0,2 of at least 1000 MPa and a tensile strength R m of at least 1500 MPa for the core material and a critical scaling resistance temperature in air for the layer material is at least 850° C. 2 . The component according to claim 1 , wherein the chemical composition of the core material is by mass % up to 0.48% C, up to 0.4% N, up to 18% Cr, preferably 10.5-18% Cr, up to 8% Ni, up to 18% Mn, up to 3.0% Mo, up to 1.0% Si, up to 0.65% Cu, up to 0.005 B, the remainder being Fe and inevitable impurities. 3 . The component according to claim 1 , wherein the layer material is austenitic heat resistant stainless steel comprising by mass % 18-25% Cr, 10-19% Ni, Mn≥0.5% and Si≥0.4 %. 4. The component according to the claim 1 , wherein the layer material is ferritic heat resistant stainless steel comprising by mass % 13-18% Cr, Mn≥0.5%, Si≥1.0% and C≤0.1%. 5 . The component according to claim 1 , wherein the layer material is in the shape of a hot rolled strip or a hot rolled plate having a thickness at most 55 mm on a slab with a thickness of 220 mm, and the mutual thickness ratio between the layer material and the core material is at most 50% of the total thickness. 6 . The component according to claim 1 , wherein the layer material is in the shape of a cold rolled strip or a hot rolled plate having a thickness at most 2.5 mm, and the mutual thickness ratio between the layer material and the core material is at most 3.2%. 7 . The component according to claim 1 , wherein the mutual ratio of the thermal conductivity between the layer material and the core material is at most 2. 8 . A method for the manufacture of a component made of a metallic composite material having high corrosion resistance and scale resistance, comprising: welding a core material of uncovered hardenable steel and a layer material of heat resistant stainless steel together in order to produce a metallic composite material, wherein the layer material covers outer surfaces of the core material, heat treating the composite material at the austenization temperature for at most 5 minutes, hot forming the heat treated composite material in a hot forming tool to have a desired shape of the component and cooling the hot formed component to the room temperature. 9 . The method according to claim 8 , wherein welding is carried out by laser welding. 10 . The method according to claim 8 , wherein welding is carried out by keyhole welding. 11 . The method according to claim 8 , wherein hot forming is carried out in an atmosphere comprising at least one shielding gas. 12 . The method according to claim 11 , wherein nitrogen is used as the shielding gas and a top part of the component has a nitride hardened surface with high wear resistance. 13 . The method according to claim 8 , wherein the core material for the composite material of the component is made of steel having a chemical composition comprising by mass % up to 0.48% C, up to 0.4% N, up to 18% Cr, preferably 10.5-18% Cr, up to 8% Ni, up to 18% Mn, up to 3.0% Mo, up to 1.0% Si, up to 0.65% Cu, the remainder being Fe and inevitable impurities. 14 . The method according to claim 8 , wherein the layer material for the composite material of the component is made of austenitic heat resistant stainless steel comprising by mass % 18-25% Cr, 10-19% Ni, Mn≥0.5% and Si≥0.4%. 15 . The method according to claim 8 , wherein the layer material for the composite material of the component is made of ferritic heat resistant stainless steel comprising by mass % 13-18% Cr, Mn≥0.5%, Si≥1.0% and C≤0.1%. 16 . The method according to claim 8 , wherein a heating rate during the hot forming process of the composite material is at least 50 K/s. 17 . The method according to claim 8 , wherein the composite material is removed from the hot forming tool during the cool-down process when the martensitic start temperature (M s ) of the layer material is reached. 18 . The method according to claim 8 , wherein the connection of the layer material to the core material is achieved by preconditioning by electrobrightening with an electrolytic solution comprising a 96% sulfuric acid and 85% orthophosphoric acid.
with copper · CPC title
Inert, i.e. inert to chemical degradation, corrosion · CPC title
with more than 1.5% by weight of manganese · CPC title
containing chromium · CPC title
all layers being formed of iron alloys or steels · CPC title
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