Non-aqueous electrolytic solution and non-aqueous electrolyte secondary battery using the same
US-2016294008-A1 · Oct 6, 2016 · US
US2018287201A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2018287201-A1 |
| Application number | US-201815934408-A |
| Country | US |
| Kind code | A1 |
| Filing date | Mar 23, 2018 |
| Priority date | Apr 3, 2017 |
| Publication date | Oct 4, 2018 |
| Grant date | — |
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A lithium ion secondary battery at least includes a positive electrode, a negative electrode, and an electrolyte solution. The positive electrode at least includes a positive electrode active material and a binder. The positive electrode active material includes more than or equal to 0.08 mass % of a lithium carbonate and a remainder of a lithium complex oxide. The binder is at least one selected from a group consisting of polytetrafluoroethylene, polyethylene oxide, and carboxymethylcellulose. The electrolyte solution at least includes a solvent and a lithium salt. The solvent is at least one of N,N-dimethylformamide and dimethylacetamide. A concentration of the lithium salt in the electrolyte solution is more than or equal to 1.9 mol/l and less than or equal to 2.3 mol/l.
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What is claimed is: 1 . A lithium ion secondary battery at least comprising a positive electrode, a negative electrode, and an electrolyte solution, the positive electrode at least including a positive electrode active material and a binder, the positive electrode active material including more than or equal to 0.08 mass % of a lithium carbonate and a remainder of a lithium complex oxide, the binder being at least one selected from a group consisting of polytetrafluoroethylene, polyethylene oxide, and carboxymethylcellulose, the electrolyte solution at least including a solvent and a lithium salt, the solvent being at least one of N,N-dimethylformamide and dimethylacetamide, a concentration of the lithium salt in the electrolyte solution being more than or equal to 1.9 mol/l and less than or equal to 2.3 mol/l. 2 . The lithium ion secondary battery according to claim 1 , wherein the positive electrode active material includes more than or equal to 0.10 mass % of the lithium carbonate and a remainder of the lithium complex oxide. 3 . The lithium ion secondary battery according to claim 1 , wherein the lithium complex oxide has a lamellar rock salt type structure. 4 . The lithium ion secondary battery according to claim 1 , wherein the electrolyte solution has an electric conductivity of more than or equal to 9.73 mS/cm and less than or equal to 19.84 mS/cm. 5 . A method of manufacturing a lithium ion secondary battery, the method comprising: preparing a positive electrode active material by exposing a lithium complex oxide to carbon dioxide; preparing a positive electrode paste by at least mixing the positive electrode active material, a binder, and water; manufacturing a positive electrode by drying the positive electrode paste; manufacturing a negative electrode; preparing an electrolyte solution at least including a solvent and a lithium salt; and manufacturing a lithium ion secondary battery at least including the positive electrode, the negative electrode, and the electrolyte solution, the positive electrode active material being prepared to include more than or equal to 0.08 mass % of a lithium carbonate and a remainder of the lithium complex oxide, the binder being at least one selected from a group consisting of polytetrafluoroethylene, polyethylene oxide, and carboxymethylcellulose, the electrolyte solution being prepared such that the solvent is at least one of N,N-dimethylformamide and dimethylacetamide and a concentration of the lithium salt is more than or equal to 1.9 mol/l and less than or equal to 2.3 mol/l.
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