Electrolyte solution for redox flow battery containing organic active material and redox flow battery using the same

Patent metadata

Field	Value
Publication number	US-2018277876-A1
Application number	US-201615546454-A
Country	US
Kind code	A1
Filing date	Sep 6, 2016
Priority date	Aug 31, 2016
Publication date	Sep 27, 2018
Grant date	—

Abstract

This invention relates to an electrolyte solution for a redox flow battery containing an organic active material, in which an organic compound useful as a single active material for a cathode and an anode is dissolved in a water-soluble solvent, and to a redox flow battery using the same. The electrolyte solution of the invention is an aqueous electrolyte solution obtained by dissolving an active material in an aqueous solvent, and is thus very stable due to the low risk of fire or explosion. Furthermore, the organic compound is applied as a single active material to the cathode and the anode, and thus, when the capacity of the battery is decreased due to the permeation of the active material through the separator, the battery capacity can be restored through rebalancing.

First claim

1 . An electrolyte solution for a redox flow battery, comprising:
a supporting electrolyte, an aqueous solvent, and an organic active material, wherein the organic active material includes at least one selected from the group consisting of alkyl viologen dihalide, 4,4-bipyridine, pyrazine, and quinoxaline.

2 . The electrolyte solution of claim 1 , wherein the organic active material is used as a single active material for a cathode and an anode.

3 . The electrolyte solution of claim 1 , wherein the alkyl viologen dihalide has an alkyl group selected from the group consisting of ethyl, methyl, propyl, butyl, heptyl, and diheptyl.

4 . The electrolyte solution of claim 1 , wherein the alkyl viologen dihalide is alkyl viologen diiodide or alkyl viologen diperchlorate.

5 . The electrolyte solution of claim 1 , wherein the alkyl viologen dihalide is ethyl viologen diiodide or ethyl viologen diperchlorate.

6 . The electrolyte solution of claim 1 , wherein the organic active material is present in a concentration of 0.005 M to 0.3 M in the electrolyte solution.

7 . The electrolyte solution of claim 1 , wherein the supporting electrolyte is selected from the group consisting of H 2 SO 4 , Li 2 SO 4 , Na 2 SO 4 , K 2 SO 4 and LiCl.

8 . The electrolyte solution of claim 1 , wherein the supporting electrolyte is present in a concentration of 0.5 M to 3 M in the electrolyte solution.

9 . A redox flow battery, comprising:
a cathode cell comprising a cathode and a cathode electrolyte solution; an anode cell comprising an anode and an anode electrolyte solution; and a separator disposed between the cathode cell and the anode cell, wherein the cathode electrolyte solution and the anode electrolyte solution comprise a supporting electrolyte, an aqueous solvent and an organic active material, and the organic active material is selected from the group consisting of alkyl viologen dihalide, 4,4-bipyridine, pyrazine, and quinoxaline.

10 . The redox flow battery of claim 9 , wherein the separator is an anion exchange membrane or a porous membrane.

Assignees

• Korea Inst Energy Res

Inventors

• Jin Chang-Soo
• Yeon Sun-Hwa
• Jeon Myung-Seok
• Shiin Kyoung-Hee
• Lee Bum-Suk
• Park Se-Kook
• Park Cheon Beom
• So Jaeyoung

Classifications

• H01M8/188 Primary

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M8/08

  Fuel cells with aqueous electrolytes · CPC title

• H01M8/0239

  Organic resins; Organic polymers · CPC title

• H01M2300/0091

  in the form of mixtures · CPC title

• H01M8/023

  Porous and characterised by the material · CPC title