Fuel cell stack break-in procedures and break-in conditioning systems

Patent metadata

Field	Value
Publication number	US-2018261858-A1
Application number	US-201715451893-A
Country	US
Kind code	A1
Filing date	Mar 7, 2017
Priority date	Mar 7, 2017
Publication date	Sep 13, 2018
Grant date	—

Abstract

Disclosed are fuel cell stack break-in procedures, conditioning systems for performing break-in procedures, and motor vehicles with a fuel cell stack conditioned in accordance with disclosed break-in procedures. A break-in method is disclosed for conditioning a membrane assembly of a fuel cell stack. The method includes transmitting humidified hydrogen to the anode of the membrane assembly, and transmitting deionized water to the cathode of the membrane assembly. An electric current and voltage cycle are applied across the fuel cell stack while the fuel cell stack is operated in a hydrogen pumping mode until the fuel cell stack is determined to operate at a predetermined threshold for a fuel cell stack voltage output capability. During hydrogen pumping, the membrane assembly oxidizes the humidified hydrogen, transports protons from the anode to the cathode across the proton conducting membrane, and regenerates the protons in the cathode through a hydrogen evolution reaction.

First claim

What is claimed:

1 . A break-in method for conditioning a membrane assembly of a fuel cell stack, the membrane assembly including a proton conducting membrane, an anode with an anode fluid inlet, and a cathode with a cathode fluid inlet, the method comprising:
commanding transmission of humidified hydrogen to the anode fluid inlet; commanding transmission of deionized water to the cathode fluid inlet; commanding application of an electric current across the fuel cell stack; and commanding the fuel cell stack to operate in a hydrogen pumping mode whereby the membrane assembly oxidizes hydrogen at the anode to generate protons, transport the protons across the proton conducting membrane to the cathode, and regenerate the protons to form hydrogen until the fuel cell stack is determined to operate at a predetermined threshold for a fuel cell stack voltage output capability.

2 . The break-in method of claim 1 , further comprising commanding application of a voltage cycle to the fuel cell stack in a range between a predetermined low potential and a predetermined high potential.

3 . The break-in method of claim 2 , wherein the commanding application of the voltage cycle includes commanding application of a predetermined finite number of the voltage cycles.

4 . The break-in method of claim 3 , wherein the predetermined low potential is approximately 0.1V, the predetermined high potential is approximately 0.9V, and the predetermined finite number of the voltage cycles is approximately 10 to 50 cycles.

5 . The break-in method of claim 2 , wherein a total current of the electric current applied across the fuel cell stack is less than or equal to approximately 80 A, and wherein a total voltage of the voltage applied to the fuel cell stack is less than or equal to approximately 50V.

6 . The break-in method of claim 1 , wherein the commanding application of the electric current across the fuel cell stack includes imposing a positive current across each cell in the fuel cell stack in a range of approximately 0.05 to 1.5 A/cm 2 .

7 . The break-in method of claim 1 , wherein the fuel cell stack operating in the hydrogen pumping mode further includes hydrogen oxidized in the anode being regenerated in the cathode through a hydrogen evolution reaction.

8 . The break-in method of claim 7 , further comprising commanding transport of hydrogen and water from the cathode to a water separator where the hydrogen and water from the cathode are combined with depleted hydrogen exhausted from the anode.

9 . The break-in method of claim 8 , further comprising commanding the water separator to separate hydrogen from water and transmit the separated hydrogen to the anode fluid inlet.

10 . The break-in method of claim 1 , wherein the fuel cell stack is operated in the hydrogen pumping mode at a temperature of approximately 70-80° F.

11 . The break-in method of claim 1 , further comprising, prior to the transmission of humidified hydrogen and the transmission of deionized water, commanding transmission of humidified nitrogen to both the anode fluid inlet and the cathode fluid inlet.

12 . The break-in method of claim 1 , wherein the transmission of deionized water includes transmitting humidified nitrogen or humidified hydrogen to the cathode fluid inlet.

13 . The break-in method of claim 1 , wherein the humidified hydrogen is transmitted at approximately 30-700 standard litres per minute (slpm), and the deionized water is transmitted at approximately 5-20 mL/min.

14 . The break-in method of claim 1 , wherein the electric current is applied in the form of a constant value, a square wave, or a triangle wave, or any combination thereof.

15 . A fuel cell conditioning system for implementing break-in of a membrane assembly of a fuel cell stack, the membrane assembly including a proton conducting membrane, an anode with an anode fluid inlet and an anode fluid outlet, and a cathode with a cathode fluid inlet and a cathode fluid outlet, the fuel cell conditioning system comprising:
a first intake conduit configured to connect the anode fluid inlet to a hydrogen source; a second intake conduit configured to connect the cathode fluid inlet to a water source; an electrical connector configured to connect the fuel cell stack to an electric power source; and an electronic control unit programmed to:
command transmission of humidified hydrogen from the hydrogen source through the first intake conduit to the anode fluid inlet;
command transmission of deionized water from the water source through the second intake conduit to the cathode fluid inlet;
command application of an electric current through the electrical connector to the fuel cell stack; and
command the fuel cell stack to operate in a hydrogen pumping mode whereby the membrane assembly transports protons from the anode to the cathode across the proton conducting membrane until the fuel cell stack is determined to operate at a predetermined threshold for a fuel cell stack voltage output capability.

16 . The fuel cell conditioning system of claim 15 , wherein the electronic control unit is further programmed to command application of a predetermined finite number of voltage cycles to the fuel cell stack in a range between a predetermined low potential and a predetermined high potential, wherein the voltage cycles are applied contemporaneous with the fuel cell stack operating in the hydrogen pumping mode.

17 . The fuel cell conditioning system of claim 15 , wherein the fuel cell stack operating in the hydrogen pumping mode further includes hydrogen oxidized in the anode being regenerated in the cathode through a hydrogen evolution reaction.

18 . The fuel cell conditioning system of claim 15 , further comprising:
a water separator; a first exhaust conduit configured to connect the anode fluid outlet to the water separator; and a second exhaust conduit configured to connect the cathode fluid outlet to the water separator, wherein the electronic control unit is further programmed to command transport of hydrogen and water from the cathode to the water separator, and command transport of depleted hydrogen from the anode to the water separator.

19 . The fuel cell conditioning system of claim 18 , wherein the electronic control unit is further programmed to command the water separator to separate hydrogen from water and transmit the separated hydrogen to the anode fluid inlet.

20 . The fuel cell conditioning system of claim 15 , wherein the electronic control unit is further programmed to, prior to the transmission of humidified hydrogen to the anode and the transmission of deionized water to the cathode, command transmission of humidified nitrogen to both the anode fluid inlet and the cathode fluid inlet.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Zhang Jingxin
• Ramaswamy Nagappan
• Lakshmanan Balasubramanian
• Kumaraguru Swaminatha P

Classifications

• H01M8/04141 Primary

  by water containing exhaust gases · CPC title

• H01M8/04835

  of fuel cell reactants · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M8/04223

  during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells · CPC title