Rapid Depressurization of a Reactor System

Patent metadata

Field	Value
Publication number	US-2018257055-A1
Application number	US-201615762377-A
Country	US
Kind code	A1
Filing date	Aug 10, 2016
Priority date	Sep 29, 2015
Publication date	Sep 13, 2018
Grant date	—

Abstract

Systems and processes for rapidly depressurizing a reactor system are disclosed. The systems and processes are particularly useful in the high pressure polymerization of ethylene.

First claim

1 . A reactor system comprising:
a. a compressor in fluid connection with a reactor, the reactor comprising at least one reaction zone and at least one cooling zone; b. a first pressure relief valve located downstream of the reactor; and c. a second pressure relief valve located along the reactor in the cooling zone.

2 . A reactor system comprising:
d. a compressor in fluid connection with a reactor, the reactor comprising at least one reaction zone and at least one cooling zone, wherein the total inner volume of the reactor is less than about 6 m 3 ; and e. a first pressure relief valve located downstream of the reactor.

3 . The system of claim 1 , wherein the reactor comprises at least three cooling zones, and a second pressure relief valve is located along the reactor in cooling zone three or a cooling zone further downstream.

4 . The system of claim 1 , wherein the reactor comprises at least four cooling zones, and a second pressure relief valve is located along the reactor in cooling zone four or a cooling zone further downstream.

5 . The system of claim 1 , further comprising a preheater upstream of the reactor, wherein the system does not have a pressure relief valve upstream of the preheater or between the preheater and the reactor.

6 . The system of claim 1 , further comprising a preheater upstream of the reactor, wherein the system is capable of reducing the operating pressure at the inlet of the preheater from above about 2000 bar to below about 1000 bar in less than 10 seconds.

7 . The system of claim 1 , wherein the reactor further comprises at least one rupture disk.

8 . The system of claim 1 , further comprising a stagnant zone within the reactor during a pressure dump event, wherein the stagnant zone is located entirely within a cooling zone.

9 . The system of claim 8 , wherein the location of the stagnant zone moves during a pressure dump event, but remains entirely within a cooling zone.

10 . The system of claim 1 , wherein the first pressure relief valve is located upstream of a high pressure let down valve.

11 . The system of claim 1 , wherein the compressor is adapted to compress olefin monomer to a pressure of at or above about 2000 bar.

12 . The system of claim 10 , wherein the olefin monomer comprises ethylene.

13 . A process for rapidly depressurizing a polymerization reactor, the process comprising opening a first pressure relief valve located downstream of the reactor.

14 . The process of claim 13 , wherein the reactor comprises at least one reaction zone and at least one cooling zone, and further comprising opening a second pressure relief valve located along the reactor in a cooling zone.

15 . The process of claim 13 , further comprising opening a high pressure let down valve located downstream of the first pressure relief valve.

16 . The process of claim 14 , further comprising opening the first pressure relief valve and the second pressure relief valve simultaneously.

17 . The process of claim 15 , further comprising opening the first pressure relief valve, the second pressure relief valve, and the high pressure let down valve simultaneously.

18 . The process of claim 15 , further comprising closing the high pressure let down valve partially or completely after confirming that at least one of the first pressure relief valve or the second pressure relief valve is open.

19 . The process of claim 13 , wherein the process is adapted to reduce the operating pressure at the inlet of a preheater upstream of the reactor from above about 2000 bar to below about 1000 bar in less than 10 seconds.

20 . The process of claim 13 , wherein a primary and a secondary compressor are located upstream of the reactor, and further comprising shutting down the secondary compressor.

21 . The process of claim 20 , wherein the secondary compressor comprises at least one suction valve, and the process comprises closing the at least one suction valve.

22 . The process of claim 13 , wherein the reactor comprises at least one feed valve, and the process further comprises closing the at least one feed valve.

23 . The process of claim 22 , further comprising closing the at least one feed valve when the pressure at any point within the reactor is at or below about 1500 bar.

24 . The process of claim 13 , further comprising initiating the process in response to a decomposition detected within the reactor.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Cornelissen Philip H
• Clymans Paul J
• Lammens Henri A

Classifications

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title

• B01J2219/0027

  Pressure relief · CPC title

• C08F10/02

  Ethene · CPC title

• B01J2219/00162

  controlling the pressure · CPC title

• B01J2219/00094

  Jackets · CPC title