Ferrite powder for bonded magnets, method for producing the same and ferrite bonded magnet

Patent metadata

Field	Value
Publication number	US-2018244537-A1
Application number	US-201615553074-A
Country	US
Kind code	A1
Filing date	Feb 23, 2016
Priority date	Feb 23, 2015
Publication date	Aug 30, 2018
Grant date	—

Abstract

A ferrite powder for bonded magnets capable of producing a ferrite bonded magnet having a BH max value of 2.65 MGOe or more when molded in a magnetic field and a method for producing the same, and a ferrite bonded magnet using the same, wherein a compression density is 3.50 g/cm 3 or more, and an average value of a (long axis length/short axis length) ratio of ferrite particles having a long axis length of 1.0 μm or more is, 1.60 or less.

First claim

1 . A ferrite powder for bonded magnets, wherein a compression density is 3.50 g/cm 3 or more, and an average value of a (long axis length/short axis length) ratio of ferrite particles having a long axis length of 1.0 μm or more, is 1.60 or less.

2 . The ferrite power for bonded magnets according to claim 1 , wherein a standard deviation value of the (long axis length/short axis length) ratio of the ferrite particles having a long axis length of 1.0 μm or more, is 0.45 or less.

3 . The ferrite powder for bonded magnets according to claim 1 , wherein a molded material is prepared by performing operations of (1), (2), and (3) described below, and a value of a maximum energy product (inj−BH maX ) of the molded material measured by performing operation of (4) is 2.65 MGOe or more:
(1) 93.0 parts by weight of the ferrite powder for bonded magnets, 0.8 parts by weight of a silane coupling agent, 0.8 parts by weight of at least one lubricant selected from a fatty acid type and an alcohol type, 5.4 parts by weight of a polyamide resin (powdery) are mixed in a mixer to obtain a mixture;
(2) The obtained mixture is kneaded at 230° C. to obtain pellets with an average diameter of 2 mm;
(3) The pellets are injection-molded in a magnetic field orientation of 12.0 kOe at a temperature of 290° C., with a molding pressure set to 85 kgf/cm 2 , to obtain a columnar molded material having a diameter of 15 mm×a height of 8 mm (the orientation direction of the magnetic field is along a central axis of the column);
(4) Magnetic properties of the molded material are measured with a BH tracer.

4 . The ferrite powder for bonded magnets according to claim 1 , wherein ferrite powder is one or more kinds selected from strontium ferrite and barium ferrite.

5 . A ferrite bonded magnet containing the ferrite powder for bonded magnets of claim 1 and a binder.

6 . A method for producing a ferrite powder for bonded magnets, comprising:
granulating a plurality of ferrite raw materials including iron oxide, and obtaining a first granulated material; sintering the obtained first granulated material at a first temperature, and obtaining a ferrite powder (coarse powder); granulating a plurality of ferrite raw materials including iron oxide, and obtaining a second granulated material; sintering the obtained second granulated material at a second temperature lower than the first temperature, and obtaining a ferrite powder (fine powder); mixing the obtained ferrite powder (coarse powder) and the ferrite powder (fine powder), to obtain a mixed powder; and adding a mechanical pulverizing force to the obtained mixed powder to obtain a pulverized mixture, and applying annealing to the obtained pulverized mixture, wherein potassium chloride is contained in the first granulated material, the first temperature is set to 1230° C. or more and 1300° C. or less, an oxygen concentration in the atmosphere at the time of sintering the first granulated material is 0.1 volume % or more and 6 volume % or less, the second temperature is 900° C. or more and 1100° C. or less, and a mixing ratio of the ferrite powder (coarse powder) and the ferrite powder (fine powder) is 20 parts by weight or more and less than 50 parts by weight based on 100 parts by weight of the ferrite powder (coarse powder).

7 . The ferrite powder for bonded magnets according to claim 2 , wherein a molded material is prepared by performing operations of (1), (2), and (3) described below, and a value of a maximum energy product (inj−BH max ) of the molded material measured by performing operation of (4) is 2.65 MGOe or more:
(1) 93.0 parts by weight of the ferrite powder for bonded magnets, 0.8 parts by weight of a silane coupling agent, 0.8 parts by weight of at least one lubricant selected from a fatty acid type and an alcohol type, 5.4 parts by weight of a polyamide resin (powdery) are mixed in a mixer to obtain a mixture;
(2) The obtained mixture is kneaded at 230° C. to obtain pellets with an average diameter of 2 mm;
(3) The pellets are injection-molded in a magnetic field orientation of 12.0 kOe at a temperature of 290° C., with a molding pressure set to 85 kgf/cm 2 , to obtain a columnar molded material having a diameter of 15 mm× a height of 8 mm (the orientation direction of the magnetic field is along a central axis of the column);
(4) Magnetic properties of the molded material are measured with a BH tracer.

8 . The ferrite powder for bonded magnets according to claim 2 , wherein ferrite powder is one or more kinds selected from strontium ferrite and barium ferrite.

9 . The ferrite powder for bonded magnets according to claim 3 , wherein ferrite powder is one or more kinds selected from strontium ferrite and barium ferrite.

10 . The ferrite powder for bonded magnets according to claim 7 , wherein ferrite powder is one or more kinds selected from strontium ferrite and barium ferrite.

11 . A ferrite bonded magnet containing the ferrite powder for bonded magnets of claim 2 and a binder.

12 . A ferrite bonded magnet containing the ferrite powder for bonded magnets of claim 3 and a binder.

13 . A ferrite bonded magnet containing the ferrite powder for bonded magnets of claim 4 and a binder.

14 . A ferrite bonded magnet containing the ferrite powder for bonded magnets of claim 7 and a binder.

15 . A ferrite bonded magnet containing the ferrite powder for bonded magnets of claim 8 and a binder.

16 . A ferrite bonded magnet containing the ferrite powder for bonded magnets of claim 9 and a binder.

17 . A ferrite bonded magnet containing the ferrite powder for bonded magnets of claim 10 and a binder.

Assignees

• Dowa Electronics Materials Co Ltd
• Dowa F Tec Co Ltd

Inventors

• Yamada Tomoya
• Tsuboi Satoru
• Ayabe Keisuke
• Mishima Yasunobu
• Senda Masayasu

Classifications

• C01P2004/20

  extending in two dimensions, e.g. plate-like · CPC title

• C01P2006/11

  Powder tap density · CPC title

• C01P2006/12

  Surface area · CPC title

• C01G49/0036 Primary

  containing one alkaline earth metal, magnesium or lead · CPC title

• C01G49/06

  Ferric oxide [Fe2O3] · CPC title