Method for modifying clay soils with gypsum

Patent metadata

Field	Value
Publication number	US-2018209112-A1
Application number	US-201815933060-A
Country	US
Kind code	A1
Filing date	Mar 22, 2018
Priority date	Dec 23, 2015
Publication date	Jul 26, 2018
Grant date	—

Abstract

A method of reducing the swell potential of an expansive clay mineral. The method includes (a) carrying out a forcefield-modified molecular level simulation to determine an amount of a swelling reduction agent to be incorporated into the expansive clay mineral to form a swelling reduction agent incorporated expansive clay mineral with a reduced swell potential S i(ECM) that is no greater than a pre-set level T, wherein the swelling reduction agent comprises at least one cementation material of calcite, gypsum, and potassium chloride and/or at least one exchangeable cation of K + , Ca 2+ , and Mg 2+ , and wherein the forcefield-modified molecular level simulation comprises molecular mechanics, molecular dynamics, and Monte Carlo simulation techniques configured to simulate the reduced swell potential S i(ECM) , and (b) incorporating the amount of the swelling reduction agent into the expansive clay mineral to form the swelling reduction agent incorporated expansive clay mineral.

First claim

1 - 16 . (canceled)

17 : A method of reducing the swell potential of an expansive clayey soil comprising at least one expansive clay mineral, the proportion of the weight of the at least one expansive clay mineral relative to the total weight of the expansive clayey soil being P ECM , the expansive clayey soil having a water content and a cation exchange capacity (CEC), the method comprising:
(a) carrying out a forcefield-modified molecular level simulation to determine an amount of a swelling reduction agent to be incorporated into the expansive clayey soil to form a swelling reduction agent incorporated expansive clayey soil with a reduced swell potential S i(soil) that is no greater than a pre-set level T*, wherein the swelling reduction agent incorporated expansive clayey soil comprises a swelling reduction agent incorporated at least one expansive clay mineral having a swell potential represented by S i(ECM) and S i(soil) equals S i(ECM) ×P ECM , wherein the swelling reduction agent comprises gypsum at a first weight percent of the amount of the swelling reduction agent, and at least one exchangeable cation selected from the group consisting of Ca 2+ and Mg 2+ at a second weight percent of the amount of the swelling reduction agent, wherein the sum of the first weight percent and the second weight percent is no greater than 100%, wherein the forcefield-modified molecular level simulation comprises molecular mechanics, molecular dynamics, and Monte Carlo simulation techniques configured to simulate the swell potential of the swelling reduction agent incorporated at least one expansive clay mineral S i(ECM) based on the water content as an initial water content and CEC of the expansive clayey soil, the gypsum at the first weight percent of the amount of the swelling reduction agent, and/or the at least one exchangeable cation at the second weight percent of the amount of the swelling reduction agent, and (b) incorporating the amount of the swelling reduction agent into the expansive clayey soil to form the swelling reduction agent incorporated expansive clayey soil.

18 : The method of claim 17 , wherein the swelling reduction agent comprises the gypsum at the first weight percent of the amount of the swelling reduction agent, and wherein the forcefield-modified molecular level simulation comprises the steps of
(i) a molecular level simulation of water sorption onto a crystallite of the at least one expansive clay mineral to form a water sorbed crystallite of the at least one expansive clay mineral with the water content of the expansive clayey soil as the initial water content, (ii) a molecular level simulation of sorption of gypsum in an amount proportional to P ECM × the first weight percent onto the water sorbed crystallite of the at least one expansive clay mineral, (iii) a molecular level simulation of assembling a plurality of the water sorbed crystallites of the at least one expansive clay mineral comprising the swelling reduction agent to form a loose cubic unit cell and at least one of a compacted unit cell at a first confining pressure and a stress relaxed unit cell at a second confining pressure less than the first confining pressure, wherein the loose cubic unit cell, the compacted unit cell, and the stress relaxed unit cell each comprise N water sorbed crystallites of the at least one expansive clay mineral comprising the swelling reduction agent and N is 2-8, and (iv) a molecular level simulation of water sorption onto and swelling of the compacted unit cell at the first confining pressure or the stress relaxed unit cell at the second confining pressure to form a swollen compacted unit cell or a swollen stress relaxed unit cell comprising the N water sorbed crystallites of the at least one expansive clay mineral comprising the swelling reduction agent until a swell cutoff point is reached, wherein the extent of the swelling of the swollen compacted unit cell or the swollen stress relaxed unit cell comprising the N water sorbed crystallites of the at least one expansive clay mineral comprising the swelling reduction agent at the swell cutoff point corresponds to the swell potential of the swelling reduction agent incorporated at least one expansive clay mineral S i(ECM) .

19 : The method of claim 17 , wherein the expansive clayey soil further comprises sand and the method further comprises removing all or a portion of the sand from the expansive clayey soil prior to the incorporating the amount of the swelling reduction agent into the expansive clayey soil to form the swelling reduction agent incorporated expansive clayey soil.

20 : The method of claim 17 , wherein the expansive clayey soil further comprises sand and the method further comprises replacing all or a portion of the sand in the expansive clayey soil with at least one non-expansive clay mineral prior to the incorporating the amount of the swelling reduction agent into the expansive clayey soil to form the swelling reduction agent incorporated expansive clayey soil.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Ahmed Habib Ur-Rehman
• Abduljauwad Sahel Nishat
• Dogan Ahmet Umran

Classifications

• C04B33/1315

  Non-ceramic binders · CPC title

• C04B33/131

  Inorganic additives · CPC title

• B09C2101/00

  In situ · CPC title

• E02D3/12 Primary

  Consolidating by placing solidifying or pore-filling substances in the soil (making piles E02D5/46; soil-conditioning or soil-stabilising materials C09K17/00; consolidation of ground around boreholes or wells E21B43/025) · CPC title

• A01G25/06

  Watering arrangements making use of perforated pipe-lines located in the soil · CPC title