Organoboron compounds and methods of making organoboron compounds

Patent metadata

Field	Value
Publication number	US-2018201627-A9
Application number	US-201615296456-A
Country	US
Kind code	A9
Filing date	Oct 18, 2016
Priority date	Jun 18, 2013
Publication date	Jul 19, 2018
Grant date	—

Abstract

Embodiments of the present disclosure provide for methods of making an organoboron compound, organoboron compounds, and the like.

First claim

We claim at least the following:

1 . A composition, comprising: a compound having a structure selected from the group consisting of:

wherein [B] is BX 2 (1 or 2) , where X 2 can independently selected from: catecholate, pinacolate, ethylene glycolate, 1,3-propanediolate, N-methyliminodiacetate, 2,2′-azanediyldiethanolate, fluoride, chloride, bromide, hydrogen, hydroxide, acetate, 9-Borabicyclo[3.3.1]nonane (9-BBN), diisopinocampheyl (Ipc), or 1,8-diaminonaphthalene, each of which can be substituted or unsubstituted;
wherein Y is selected from the group consisting of: CH 2 , CRH, CR 2 , NR, O, S, PR or SiR 2 , where R is selected from the group consisting of H, a carbonyl functional group (substituted or unsubstituted), a carboxy functional group (substituted or unsubstituted), a carbocycle group (substituted or unsubstituted), a heterocycle (substituted or unsubstituted), a halide, or an alkyl group (substituted or unsubstituted);
wherein each of R, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , and R 8 is independently selected from: H, a carbonyl functional group (substituted or unsubstituted), a carbocycle group (substituted or unsubstituted), a heterocycle (substituted or unsubstituted), a halide, an alkyl group (cyclic or acyclic; substituted or unsubstituted), an alkenyl group (cyclic or acyclic; substituted or unsubstituted), CF 3 , CN, NO 2 , an aryl group (substituted or unsubstituted), a heteroaryl group (substituted or unsubstituted), a sulfonyl group, a boryl group, an ether group, a thioether group, a silyl group, an ester group, an amide group, an alkoxy group, a thiol group, an alcohol group, or an amine group;
wherein a “curved line” between R groups represents a carbon chain or a hetero carbon chain;
wherein X is selected from the group consisting of: O, S, or —C(O)O—;
wherein Y is selected from the group consisting of: NR, O, S, or CR 7 R 8 ; and
wherein X 1 is selected from the group consisting of: O, NR, S, or CR 1 R 2 , where each of R, R 1 , R 2 for X 1 is independently selected from: H, a carbonyl functional group, a carboxy group, a carbocycle group, a heterocycle, a halide, or an alkyl group, each of which is optionally substituted or unsubstituted.

2 . A method of making an organoboron compound, comprising a reaction described by one of the following schemes:

Assignees

• Univ California

Inventors

• Blum Suzanne A
• Hirner Joshua J
• Faizi Darius J

Classifications

• C07F5/025

  Boronic and borinic acid compounds · CPC title

• C07F5/027

  Organoboranes and organoborohydrides · CPC title

• C07F7/1804

  Compounds having Si-O-C linkages (Si-O-acyl linkages C07F7/1896) · CPC title

• C07F1/12 Primary

  Gold compounds · CPC title

• C07F5/02 Primary

  Boron compounds · CPC title