Nitrogen-containing heterocycles as pesticides

Patent metadata

Field	Value
Publication number	US-2018201600-A1
Application number	US-201615742369-A
Country	US
Kind code	A1
Filing date	Jul 4, 2016
Priority date	Jul 6, 2015
Publication date	Jul 19, 2018
Grant date	—

Abstract

The present application relates to novel heterocyclic compounds, to processes and intermediates for the preparation thereof, and their use for controlling animal pests.

First claim

1 . Compound of formula (I)

in which the structural unit of the formula

represents a radical A from the group consisting of

where these radicals carry m substituents X,
X represents a radical from the group consisting of halogen, cyano (CN), nitro, alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, haloalkyl, haloalkoxy, haloalkylthio, haloalkylsulphonyl, alkoxycarbonyl, alkylcarbonyl and cycloalkylcarbonyl,
m represents a number from the group consisting of 0, 1 and 2,
R represents a radical B from the group consisting of

where these radicals carry n substituents Y and the dashed line represents the bond to the nitrogen atom in radical A,
Y represents a radical from the group consisting of halogen, cyano, nitro, amino, alkyl, alkenyl, alkynyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulphinyl, haloalkylsulphinyl, alkylsulphonyl, haloalkylsulphonyl, alkoxycarbonyl, alkylcarbonyl, cycloalkylcarbonyl, alkylamino, dialkylamino, alkylaminosulphonyl, dialkylaminosulphonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylcarbonylamino, alkoxyalkylcarbonylamino, haloalkylcarbonylamino and in each case optionally substituted aryl and hetaryl,
n represents a number from the group consisting of 0, 1 and 2,
W represents CH or N (nitrogen) and
R 1 represents a radical from the group consisting of nitro, cyano, CS—NH 2 and CO—CF 3 .

2 . Compound of formula (I) according to claim 1 in which the structural unit of the formula

represents a radical A from the group consisting of

where these radicals carry m substituents X,
X represents a radical from the group consisting of halogen, cyano, nitro, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -alkylthio, C 1 -C 4 -alkylsulphinyl, C 1 -C 4 -alkylsulphonyl, halo-C 1 -C 4 -alkyl, halo-C 1 -C 4 -alkoxy, halo-C 1 -C 4 -alkylthio, halo-C 1 -C 4 -alkylsulphonyl, C 1 -C 4 -alkoxycarbonyl, C 1 -C 4 -alkylcarbonyl and C 3 -C 6 -cycloalkylcarbonyl,
m represents a number from the group consisting of 0, 1 and 2,
R represents a radical B from the group consisting of

where these radicals carry n substituents Y and the dashed line represents the bond to the nitrogen atom in radical A,
Y represents a radical from the group consisting of halogen, cyano, nitro, amino, C 1 -C 4 -alkyl, C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl, halo-C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, halo-C 1 -C 4 -alkoxy, C 1 -C 4 -alkylthio, halo-C 1 -C 4 -alkyl thio, C 1 -C 4 -alkylsulphinyl, halo-C 1 -C 4 -alkylsulphinyl, C 1 -C 4 -alkylsulphonyl, halo-C 1 -C 4 -alkylsulphonyl, C 1 -C 4 -alkoxycarbonyl, C 1 -C 4 -alkylcarbonyl, C 3 -C 6 -cycloalkylcarbonyl, C 1 -C 4 -alkylamino, di-(C 1 -C 4 -alkyl)amino, C 1 -C 4 -alkylaminosulphonyl, di-(C 1 -C 4 -alkyl)aminosulphonyl, C 1 -C 4 -alkylaminocarbonyl, di-(C 1 -C 4 -alkyl)aminocarbonyl, C 1 -C 4 -alkylcarbonylamino, C 1 -C 4 -alkoxy-C 1 -C 4 -alkylcarbonylamino, halo-C 1 -C 4 -alkylcarbonylamino, in each case optionally substituted aryl and 5- or 6-membered hetaryl and in the case of aryl and hetaryl in particular in each case optionally halogen-, cyano-, C 1 -C 4 -alkyl-, halo-C 1 -C 4 -alkyl-, C 1 -C 4 -alkoxy-, halo-C 1 -C 4 -alkoxy-, C 1 -C 4 -alkylthio-, halo-C 1 -C 4 -alkylthio-, C 1 -C 4 -alkylsulphinyl-, halo-C 1 -C 4 -alkylsulphinyl-, C 1 -C 4 -alkylsulphonyl- or halo-C 1 -C 4 -alkylsulphonyl-substituted phenyl and 5- or 6-membered hetaryl, where hetaryl is preferably selected from the group consisting of N-pyrazolyl, N-imidazolyl and N-1,2,4-triazolyl,
n represents a number from the group consisting of 0, 1 and 2,
W represents CH or N (nitrogen) and
R 1 represents a radical from the group consisting of nitro, cyano, CS—NH 2 and CO—CF 3 .

3 . Compound of formula (I) according to claim 1 in which the structural unit of the formula

represents a radical A from the group consisting of

where these radicals carry m substituents X,
X represents a radical from the group consisting of hydrogen, halogen, cyano, C 1 -C 4 -alkyl, halo-C 1 -C 4 -alkyl,
m represents a number from the group consisting of 0, 1 and 2,
R represents a radical B from the group consisting of

where these radicals carry n substituents Y and the dashed line represents the bond to the nitrogen atom in radical A,
Y represents a radical from the group consisting of halogen, cyano, C 1 -C 4 -alkyl, C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl, halo-C 1 -C 4 -alkyl, halo-C 1 -C 4 -alkoxy, halo-C 1 -C 4 -alkylthio, C 1 -C 4 -alkylsulphinyl, halo-C 1 -C 4 -alkylsulphinyl, C 1 -C 4 -alkylsulphonyl, halo-C 1 -C 4 -alkylsulphonyl and 5-membered hetaryl which is optionally substituted by a substituent from the group consisting of halogen, cyano, C 1 -C 4 -alkyl, halo-C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, halo-C 1 -C 4 -alkoxy, C 1 -C 4 -alkylthio, halo-C 1 -C 4 -alkylthio, C 1 -C 4 -alkylsulphinyl, halo-C 1 -C 4 -alkylsulphinyl, C 1 -C 4 -alkylsulphonyl, halo-C 1 -C 4 -alkylsulphonyl, where hetaryl is, for example, N-pyrazolyl, N-imidazolyl or N-1,2,4-triazolyl,
n represents a number from the group consisting of 0, 1 and 2,
W represents N (nitrogen) and
R 1 represents cyano or CO—CF 3 .

4 . Compound of formula (I) according to claim 1 in which the structural unit of the formula

represents a radical A from the group consisting of

where these radicals carry m substituents X,
X represents a radical from the group consisting of fluorine, chlorine, bromine or iodine, cyano, methyl, ethyl, trifluoromethyl and difluoromethyl,
m represents a number from the group consisting of 0, 1 and 2,
R represents a radical from the group consisting of

where these radicals carry n substituents Y and t

Assignees

• Bayer Cropscience Ag

Inventors

• Jeschke Peter
• Gutbrod Oliver
• Fischer Reiner
• Hellwege Elke
• Loesel Peter
• Malsam Olga
• Eilmus Sascha
• Ilg Kerstin
• Portz Daniela
• Goergens Ulrich
• Lishchynskyi Anton

Classifications

• C07D213/74

  Amino or imino radicals substituted by hydrocarbon or substituted hydrocarbon radicals · CPC title

• C07D401/14

  containing three or more hetero rings · CPC title

• A01N43/58

  1,2-Diazines; Hydrogenated 1,2-diazines · CPC title

• C07D401/04 Primary

  directly linked by a ring-member-to-ring-member bond · CPC title

• A01N43/653

  1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles · CPC title