Ureido-functionalized aqueous polymeric dispersion
US-9212292-B2 · Dec 15, 2015 · US
US2018200708A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2018200708-A1 |
| Application number | US-201615744340-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jul 1, 2016 |
| Priority date | Jul 14, 2015 |
| Publication date | Jul 19, 2018 |
| Grant date | — |
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A composite ion exchange membrane comprising a cationically-charged membrane and an oppositely charged compound covalently bound thereto, the composite ion exchange membrane having: (i) a zeta-potential lower than −8 mV; and (ii) an effective charge lower than 20 μmol/m 2 .
Opening claim text (preview).
1 . A composite ion exchange membrane comprising a cationically-charged membrane and an oppositely charged compound covalently bound thereto, the composite ion exchange membrane having: (i) a zeta-potential lower than −8 mV; and (ii) an effective charge lower than 20 μmol/m 2 . 2 . (canceled) 3 . The composite membrane according to claim 1 wherein the oppositely charged compound comprises a sulpho group. 4 . The composite membrane according to claim 1 wherein the cationically-charged membrane further comprises a porous support. 5 . The composite membrane according to claim 1 having an effective charge of less than 10 mol/m 2 . 6 . The composite membrane according to claim 1 having: (i) a zeta-potential lower than −10 mV; and (ii) an effective charge lower than 10 μmol/m 2 . 7 . The composite membrane according to claim 1 wherein only one side of the cationically-charged membrane has an oppositely charged compound covalently bound thereto. 8 . The composite membrane according to claim 1 wherein both sides of the cationically-charged membrane have an oppositely charged compound covalently bound thereto. 9 . A membrane stack comprising two or more composite membranes according to claim 1 . 10 . (canceled) 11 . The composite membrane according to claim 1 wherein the cationically-charged membrane has been obtained by a process comprising the polymerisation of a composition comprising a crosslinking agent and a monofunctional ethylenically unsaturated monomer having a cationic charge. 12 . The composite membrane according to claim 1 wherein the zeta-potential is lower than −10 mV and the effective charge is lower than 5 μmol/m 2 . 13 . The composite membrane according to claim 1 wherein the zeta-potential is measured using an Anton Paar SurPASS Electrokinetic Analyzer using 1 mM KCl solution at pH 5 in milli-Q ultrapure water as electrolyte. 14 . The composite membrane according to claim 1 wherein the effective charge constitutes the amount of sodium ions washed from the composite membrane surface by 0.5M KCl after an overnight washing with 0.5M NaCl. 15 . A membrane stack comprising two or more composite membranes according to claim 3 .
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