Non-aqueous electrolyte additive, non-aqueous electrolyte comprising the same, and lithium secondary battery including non-aqueous electrolyte

Patent metadata

Field	Value
Publication number	US-2018191031-A1
Application number	US-201615735741-A
Country	US
Kind code	A1
Filing date	Oct 26, 2016
Priority date	Oct 29, 2015
Publication date	Jul 5, 2018
Grant date	—

Abstract

The present invention relates to: a non-aqueous electrolyte additive comprising, as a substituent, at least one cyano group and/or at least one fluorine element; a non-aqueous electrolyte for a lithium secondary battery, comprising the same; and a lithium secondary battery including the non-aqueous electrolyte.

First claim

1 . A non-aqueous electrolyte additive comprising a compound represented by Formula 1 below:

In Formula 1, R is a C1 to C3 alkyl group substituted or unsubstituted with at least one fluorine element, and A is a C1 to C4 alkyl group substituted with at least one fluorine element and/or at least one cyano group (—CN).

2 . The non-aqueous electrolyte additive of claim 1 , wherein the non-aqueous electrolyte additive comprises at least one compound selected from the group consisting of compounds represented by Formulas 1a to 1i below:

3 . A non-aqueous electrolyte for a lithium secondary battery, comprising an ionizable lithium salt; an organic solvent; and a non-aqueous electrolyte additive,
wherein the non-aqueous electrolyte additive includes a compound represented by Formula 1 below:

In Formula 1, R is a C1 to C3 alkyl group substituted or unsubstituted with at least one fluorine element, and A is a C1 to C4 alkyl group substituted with at least one fluorine element and/or at least one cyano group (—CN).

4 . The non-aqueous electrolyte of claim 3 , wherein the non-aqueous electrolyte additive is included at 0.5 to 5 wt % based on a total weight of the non-aqueous electrolyte.

5 . The non-aqueous electrolyte of claim 4 , wherein the non-aqueous electrolyte additive is included at 1 to 5 wt % based on a total weight of the non-aqueous electrolyte.

6 . The non-aqueous electrolyte of claim 3 , wherein the lithium salt includes Li + as a cation and any one selected from the group consisting of F − , Cl − , Br − , I − , NO 3 − , N(CN) 2 − , BF 4 − , ClO 4 − , AlO 4 − , AlCl 4 − , PF 6 − , SbF 6 − , AsF 6 − , BF 2 C 2 O 4 − , BC 4 O 8 − , (CF 3 ) 2 PF 4 − , (CF 3 ) 3 PF 3 − , (CF 3 ) 4 PF 2 − , (CF 3 ) 5 PF − , (CF 3 ) 6 P − , CF 3 SO 3 − , C 4 F 9 SO 3 − , CF 3 CF 2 SO 3 − , (CF 3 SO 2 ) 2 N − , (FSO 2 ) 2 N − , CF 3 CF 2 (CF 3 ) 2 CO − , (CF 3 SO 2 ) 2 CH − , (SF 5 ) 3 C − , (CF 3 SO 2 ) 3 C − , CF 3 (CF 2 ) 7 SO 3 − , CF 3 CO 2 − , CH 3 CO 2 − , SCN − , and (CF 3 CF 2 SO 2 ) 2 N − as an anion.

7 . The non-aqueous electrolyte of claim 3 , wherein the organic solvent includes any one or a mixture of two or more selected from the group consisting of an ether, an ester, an amide, a linear carbonate, and a cyclic carbonate.

8 . A lithium secondary battery comprising a negative electrode, a positive electrode, a separator interposed between the negative electrode and the positive electrode, and a non-aqueous electrolyte,
wherein the non-aqueous electrolyte is the non-aqueous electrolyte for a lithium secondary battery according to claim 3 .

Assignees

• Lg Chemical Ltd

Inventors

• Yu Sung Hoon
• Kang Yoo Sun
• Lee Kyung Mi

Classifications

• H01M2300/0037

  Mixture of solvents · CPC title

• H01M10/0568

  characterised by the solutes · CPC title

• H01M10/0567 Primary

  characterised by the additives · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M10/0569

  characterised by the solvents · CPC title