Curable compositions and their use as coatings and footwear components

Patent metadata

Field	Value
Publication number	US-2018127617-A1
Application number	US-201615346853-A
Country	US
Kind code	A1
Filing date	Nov 9, 2016
Priority date	Nov 9, 2016
Publication date	May 10, 2018
Grant date	—

Abstract

Curable compositions are provided comprising:
(a) an isocyanate-functional prepolymer having a weight average molecular weight of 4000 to 15,000;
(b) a curing agent comprising a mixture of polyamines, wherein at least one polyamine has an amine equivalent weight of 125 to 250; and
(c) an abrasion resistant additive comprising organic and inorganic particles. The isocyanate-functional prepolymer is (i) a reaction product of a polyisocyanate and a polyamine having primary and/or secondary amino groups; and/or (ii) a reaction product of a polyisocyanate and a polyol. Upon application of the composition to a substrate as a coating and after curing to form a coated substrate, the coated substrate demonstrates a coating loss of less than 0.33 cm 3 after being subjected to 1000 cycles of a TABER Abrasion Test using S-42 sandpaper strips and two 1000 gram weights. Coated substrates and footwear components prepared from the compositions are also disclosed.

First claim

What is claimed is:

1 . A curable composition comprising:
(a) an isocyanate-functional prepolymer having a weight average molecular weight of 4000 to 15,000, wherein the isocyanate-functional prepolymer comprises (i) a reaction product of a polyisocyanate and a polyamine having primary and/or secondary amino groups; and/or (ii) a reaction product of a polyisocyanate and a polyol; (b) a curing agent comprising a mixture of polyamines, wherein at least one polyamine in the curing agent has an amine equivalent weight of 125 to 250; and (c) an abrasion resistant additive comprising organic and inorganic particles, wherein the organic particles demonstrate a volume average particle size of at least 5 microns, and the inorganic particles demonstrate a volume average particle size of at least 90 microns.

2 . The curable composition according to claim 1 wherein the polyisocyanate used to prepare the isocyanate-functional prepolymer is aliphatic.

3 . The curable composition according to claim 1 wherein isocyanate-functional prepolymer has an isocyanate equivalent weight greater than 300.

4 . The composition according to claim 1 , wherein the isocyanate-functional prepolymer comprises a reaction product of a polyisocyanate and a polyether having primary amino groups.

5 . The composition according to claim 1 , wherein the curing agent comprises 5 to 50 percent by weight of an aliphatic polyamine having an amine equivalent weight of 125 to 250, and 50 to 95 percent by weight of an aliphatic polyamine having an amine equivalent weight of 900 to 2500.

6 . The composition according to claim 1 , wherein the organic and inorganic particles of the abrasion resistant additive comprise chemically inert, untreated and uncoated particles.

7 . The composition according to claim 1 , wherein the abrasion resistant additive is present in the composition in an amount of at least 10 percent by weight, based on the total weight of solids in the composition.

8 . The composition according to claim 1 , wherein the inorganic particles comprise untreated alumina, and the organic particles comprise polyethylene, polypropylene, and/or saturated, linear primary alcohols with an average carbon chain length of C 20 to C 50 .

9 . The composition according to claim 8 , wherein the organic particles of the abrasion resistant additive demonstrate a volume average particle size of 5 to 7.5 microns.

10 . A coated substrate comprising:
A) a substrate having at least one coatable surface, and B) a coating layer formed from a film-forming composition applied to at least one surface of the substrate and cured thereon, wherein the film-forming composition is prepared from the curable composition of claim 1 .

11 . The coated substrate according to claim 9 , wherein the substrate comprises wood, metal, glass, fabric, leather, a composite, or a polymeric material.

12 . The coated substrate according to claim 11 , wherein the substrate comprises a plasma-treated surface adjacent to the coating layer formed from the curable composition.

13 . The coated substrate according to claim 11 , further comprising an adhesive layer disposed between the substrate (A) and the coating layer (B), wherein the adhesive layer comprises an adhesion promoter.

14 . A footwear component wherein the component is prepared from a curable composition comprising:
(a) an isocyanate-functional prepolymer having a weight average molecular weight of 4000 to 15,000, wherein the isocyanate-functional prepolymer comprises (i) a reaction product of a polyisocyanate and a polyamine having primary and/or secondary amino groups; and/or (ii) a reaction product of a polyisocyanate and a polyol; (b) a curing agent comprising a mixture of polyamines, wherein at least one polyamine in the curing agent has an amine equivalent weight of 125 to 250; and (c) an abrasion resistant additive comprising organic and inorganic particles, wherein the organic particles demonstrate a volume average particle size of at least 5 microns, and the inorganic particles demonstrate a volume average particle size of at least 90 microns.

15 . The footwear component according to claim 14 wherein the abrasion resistant additive is present in the composition in an amount of at least 10 percent by weight, based on the total weight of solids in the composition.

16 . The footwear component according to claim 14 wherein the inorganic particles comprise untreated alumina, and the organic particles comprise polyethylene, polypropylene, and/or saturated, linear primary alcohols with an average carbon chain length of C 20 to C 50 .

17 . The footwear component according to claim 16 wherein the organic particles of the abrasion resistant additive demonstrate a volume average particle size of 5 to 7.5 microns.

18 . The footwear component according to claim 14 wherein said footwear component demonstrates a dry film thickness of 508 to 25400 microns and the weight ratio of organic to inorganic particles in the abrasion resistant additive is less than 10:40.

19 . The footwear component according to claim 14 wherein said footwear component demonstrates a dry film thickness of 25.4 to 254 microns and the weight ratio of organic to inorganic particles in the abrasion resistant additive is at least 40:10.

20 . The footwear component according to claim 14 wherein the curable composition further comprises an adhesion promoter.

21 . Footwear comprising the footwear component according to claim 14 .

Assignees

• Ppg Ind Ohio Inc

Inventors

• Kabagambe Benjamin
• Kutchko Cynthia
• Winters Christina
• Millero Jr Edward Richard
• Breon Jonathan
• Donaldson Susan Fundy

Classifications

• C08G18/755

  and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate · CPC title

• C08K2201/005

  Additives being defined by their particle size in general · CPC title

• C08G18/5021

  having nitrogen · CPC title

• C09D175/08 Primary

  from polyethers · CPC title

• A43B13/20

  Pneumatic soles {filled with a compressible fluid, e.g. air, gas (inflatable linings for skiboots A43B5/0407)} · CPC title