Method and apparatus for the preparation of a polyolefin

Patent metadata

Field	Value
Publication number	US-2018086856-A1
Application number	US-201615566157-A
Country	US
Kind code	A1
Filing date	Apr 13, 2016
Priority date	Apr 14, 2015
Publication date	Mar 29, 2018
Grant date	—

Abstract

A method ( 100 ) is proposed for the preparation of a polyolefin from olefin monomers, wherein the olefin monomers are subjected to one or more polymerisation steps ( 13 ), in which a proportion of the olefin monomers are catalytically reacted to form the polyolefin, while the olefin monomers that are not reacted in the polymerisation step or steps (13) are at least partly transferred into one or more gaseous, monomer-containing purge streams (g, h), which additionally contain(s) one or more aluminium organic compounds, which comprise one or more co-catalysts used in the polymerisation step or steps ( 13 ) and/or one or more compounds formed from the co-catalyst(s). It is provided that, downstream of one or more olefin synthesis steps ( 21 ), the gaseous, monomer-containing purge stream or streams (g, h) are brought into contact with a crude gas mixture (p, r) formed using a product mixture from the olefin synthesis step or steps ( 21 ) and are subjected to a caustic wash ( 26 ) together with the crude gas mixture (p, r). The present invention also relates to a corresponding apparatus.

First claim

1 . Method ( 100 ) for producing a polyolefin from olefin monomers, wherein the olefin monomers are subjected to one or more polymerisation steps ( 13 ), in which a proportion of the olefin monomers are catalytically reacted to form the polyolefin, while the olefin monomers that are not reacted in the polymerisation step or steps ( 13 ) are at least partly transferred into one or more gaseous, monomer-containing purge streams (g, h), which additionally contain(s) one or more aluminium organic compounds, which comprise one or more co-catalysts used in the polymerisation step or steps ( 13 ) and/or one or more compounds formed from the co-catalyst(s), characterised in that, downstream of one or more olefin synthesis steps ( 21 ), the gaseous, monomer-containing purge stream or streams (g, h) are brought into contact with a crude gas mixture (p, r) formed using a product mixture from the olefin synthesis step or steps ( 21 ) and are subjected to a caustic wash ( 26 ) together with the crude gas mixture (p, r).

2 . Method ( 100 ) according to claim 1 , wherein the gaseous, monomer-containing purge stream or streams (g, h) is or are combined with the crude gas mixture (r), downstream of one or more working-up steps ( 22 , 23 ) to which the product mixture of the olefin synthesis step or steps ( 21 ) is or are subjected during the formation of the crude gas mixture (p, r).

3 . Method ( 100 ) according to claim 2 , wherein the working-up step or steps comprise a cooling ( 22 ) and/or a water wash ( 23 ).

4 . Method ( 100 ) according to one of the preceding claims, wherein one or more washing columns ( 261 ) are used in the caustic wash ( 26 ), and wherein the gaseous, monomer-containing purge stream or streams (g, h) are brought into contact with the crude gas mixture (p, r) in or upstream of the one or more washing columns ( 261 ).

5 . Method ( 100 ) according to claim 4 , wherein one or more washing columns ( 261 ) are used which comprise sections separated from one another by liquid barrier trays, the number of sections being two to five, more particularly two to three.

6 . Method ( 100 ) according to claim 4 or 5 , wherein a plurality of washing columns ( 261 ) are used which are connected in parallel and/or in series.

7 . Method ( 100 ) according to one of the preceding claims, wherein the gaseous, monomer-containing purge stream or streams (g, h) and the crude gas mixture (p, r) are brought into contact with an alkaline washing medium in the caustic wash ( 26 ), the alkaline washing medium containing sodium hydroxide in an amount of 0.5 to 20% by weight, particularly 1 to 10% by weight, particularly 1 to 6% by weight.

8 . Method ( 100 ) according to one of the preceding claims, wherein the one or more aluminium organic compounds are present in the gaseous, monomer-containing purge stream or streams (g, h) in an amount of up to 5% by weight, particularly up to 2.5% by weight, particularly up to 1.25% by weight, particularly up to 0.5% by weight, particularly up to 1000 ppm by weight, based on the aluminium present.

9 . Method ( 100 ) according to one of the preceding claims, wherein the gaseous, monomer-containing purge stream or streams (g, h) contain the one or more aluminium organic compounds in the form of at least one aluminium alkyl and/or in the form of at least one methylaluminoxane and/or in the form of at least one halogenated aluminium compound with the empirical formulae AIR1R2X1 and/or AIR1X1X2, wherein R1 and R2 denote branched or unbranched C1- to C12-alkyl chains and X1 and X2 denote a halogen atom, particularly triethylaluminium, and/or in the form of at least one compound formed from the above-mentioned compounds.

10 . Method ( 100 ) according to one of the preceding claims, wherein a hydrocarbon-containing purge washing stream (u) which is depleted in or free from the aluminium organic compound or compounds is obtained in the caustic wash ( 26 ), and wherein hydrocarbons contained in the purge washing stream (u) are fed into one or more separating steps ( 26 ), in which one or more olefin-rich fractions (x) are obtained.

11 . Method ( 100 ) according to claim 10 , wherein the olefin monomers which are subjected to the polymerisation step or steps ( 13 ) are prepared at least partially using the one or more olefin-rich fractions (x).

12 . Method ( 100 ) according to one of the preceding claims, wherein the olefin synthesis step or steps ( 21 ) encompass at least one thermal and/or catalytic cleavage step and/or at least one step for the dehydrogenation of alkanes and/or at least one step for the oxidative coupling of methane.

13 . Apparatus for the production of a polyolefin from olefin monomers having one or more polymerisation reactors which are set up so as to subject the olefin monomers to one or more polymerisation steps ( 13 ) and thereby react some of the olefin monomers catalytically to form the polyolefin, and having means which are designed to transfer the olefin monomers that are not reacted in the polymerisation step or steps ( 13 ) at least partly into one or more gaseous monomer-containing purge streams (g, h) which additionally contain one or more aluminium organic compounds, which consist of one or more co-catalysts used in the polymerisation step or steps ( 13 ), and/or one or more compounds formed from the co-catalyst or co-catalysts, characterised by means which are designed to bring the gaseous, monomer-containing purge stream or streams (g, h),downstream of one or more olefin synthesis steps ( 21 ), into contact with a crude gas mixture (p, r) formed using a product mixture from the olefin synthesis step or steps ( 21 ), and to subject it, together with the crude gas mixture (p, r), to a caustic wash ( 26 ).

Assignees

• Linde Ag

Inventors

• Meiswinkel Andreas
• Fritz Helmut
• Zander Hans-Jörg
• Kirzinger Anton
• Freisinger Josef
• Ulubay Can
• Hesch Walter
• Winkler Thomas
• Wöhl Anina

Classifications

• C08F2/34 Primary

  Polymerisation in gaseous state · CPC title

• C08F6/001 Primary

  Removal of residual monomers by physical means · CPC title

• C08F6/02

  Neutralisation of the polymerisation mass, e.g. killing the catalyst (short-stopping C08F2/42 ){also removal of catalyst residues} · CPC title

• C08F2/01

  characterised by special features of the polymerisation apparatus used · CPC title

• C08L23/00

  Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers · CPC title